Effective Heat Treatment Temperature of Carbon Materials in High Temperature Furnaces: Determination by the Parameters of Raman Spectroscopy of Witness Samples

2021 ◽  
Vol 12 (5) ◽  
pp. 1416-1427
Author(s):  
V. M. Samoilov ◽  
A. V. Nakhodnova ◽  
M. A. Osmova ◽  
D. B. Verbets ◽  
A. N. Bubnenkov ◽  
...  
2021 ◽  
Vol 1 ◽  
pp. 67-84
Author(s):  
V. M. Samoilov ◽  
◽  
A. V. Nakhodnova ◽  
M. A. Osmova ◽  
D. B. Verbets ◽  
...  

The aim of this work is to evaluate the use of Raman spectroscopy of carbon fibre-based (CF) reference samples for establishing the heat treatment temperature (HTT) in high-temperature (1000 – 3000 °C) furnaces used in production of a series of carbon materials. Based on obtained correlational relationships between Raman spectroscopy parameters and HTT, the use of the ID/IG parameter is suggested for obtaining the most exact and reproducible results. An experimental basis for the use of polyacrylonitrile-based (PAN) CF as reference specimens is provided. It is shown that for PAN-based CF samples treated in the high temperature interval (1000 – 3000 °С) the ID/IG parameter correlates well with X-Ray diffraction analysis parameters. A series of Raman spectroscopy of reference specimens potential uses the in determination of effective HTT of carbon materials in technological processes of production of carbon-carbon based composite materials, artificial graphites and PAN-based CF’s and in the determination of temperature fields of laboratory and industrial equipment for high-temperature treatment of carbon materials in the temperature interval 1000 – 3000 °C, specifically Tamman, vacuum electric resistance and Acheson furnaces, are examined.


2015 ◽  
Vol 658 ◽  
pp. 14-18
Author(s):  
Tanaporn Rojhirunsakool ◽  
Duangkwan Thongpian ◽  
Nutthita Chuankrerkkul ◽  
Panyawat Wangyao

Nickel-base superalloys have been used as high temperature materials in land-base gas turbine application. When subjected to long term, high temperature service, large crack propagation was observed. Typical refurbishment method of these turbines is carried out by using TIG welding followed by post-weld standard heat treatment. However, new crack initiation is found in the heat-affected zone after TIG welding. Pre-weld heat treatment has been discovered to improves final γ + γ’ microstructure. This study focuses on the effect of pre-weld heat treatment temperature on final γ + γ’ microstructure. Seven different conditions of pre-weld heat treatment temperature were investigated. Scanning electron microscopy studies were carried out after pre-weld and post-weld heat treatments to compare the γ + γ’ microstructure and capture microcracks. The best pre-weld heat treatment temperature produces uniform distribution of finely dispersed γ’ precipitates in the γ matrix without post-weld crack.


Processes ◽  
2020 ◽  
Vol 8 (8) ◽  
pp. 933 ◽  
Author(s):  
Gerrit Ralf Surup ◽  
Tommy Andre Pedersen ◽  
Annah Chaldien ◽  
Johan Paul Beukes ◽  
Merete Tangstad

This study reports the effect of high-temperature treatment on the electrical properties of charcoal, coal, and coke. The electrical resistivity of industrial charcoal samples used as a reducing agent in electric arc furnaces was investigated as a renewable carbon source. A set-up to measure the electrical resistivity of bulk material at heat treatment temperatures up to 1700 ∘C was developed. Results were also evaluated at room temperature by a four-point probe set-up with adjustable load. It is shown that the electrical resistivity of charcoal decreases with increasing heat treatment temperature and approaches the resistivity of fossil carbon materials at temperatures greater than 1400 ∘C. The heat treatment temperature of carbon material is the main influencing parameter, whereas the measurement temperature and residence time showed only a minor effect on electrical resistivity. Bulk density of the carbon material and load on the burden have a large impact on the electrical resistivity of each material, while the effect of particle size can be neglected at high heat treatment temperature or compacting pressure. The mechanical durability of charcoal slightly increased after heat treatment and decreased for coal and semi-coke samples. The results indicate that charcoal can be used as an efficient carbon source for electric arc furnaces.


2014 ◽  
Vol 809-810 ◽  
pp. 815-821
Author(s):  
Xiao Hu Hua ◽  
Xiao Gang Wang ◽  
Jia Qing Yang ◽  
Shu He Lu ◽  
Li Rong Deng ◽  
...  

Anthracite and bitumite were processed respectively at 1400°C,1700°C, 2000°C, 2200°C, 2400°C and 2600°C,and their chemical composition,resistivity,microstructure, phase composition,and the internal migration of molecular functional group were tested and characterized. The results indicate that moisture, ash and volatile in coal have gradually shifted and lost with the elevation of heat treatment temperature, while the higher temperature, the quicker and completer phase change. Heat treatment can make the coal transform from approximately insulative phase to conductive phase,. Furthermore, as the temperature increases, the conductive phase transformation effect is better. The higher the heat treatment temperature of coal, the more amorphous carbon transforming into crystalline carbon completely, but the less types of phases .


2000 ◽  
Vol 659 ◽  
Author(s):  
Y.-A Jee ◽  
B. Ma ◽  
M. Li ◽  
B. L. Fisher ◽  
U. Balachandran

ABSTRACTYBa2Cu3Ox (YBCO) thin films were fabricated by the trifluoroacetate (TFA) process on LaAlO3 (LAO) single crystal in an argon atmosphere. We focused on lowering the heat treatment temperature by decreasing the oxygen partial pressure to adopt the TFA process to metallic substrates. YBCO phase formation was checked by measuring Tc with the inductive method. In-plane and out-of-plane film textures were evaluated by phi-scan and omega scan, respectively. Raman spectroscopy was used to estimate grain connectivity, in-plane texture, and second-phase formation of the films. Although Raman spectroscopy revealed some evidence of cation disorder, the film prepared at 750°C shows a sharp superconducting transition at 91 K and critical current density of 1.3 MA/cm2 at 77 K. Optimal heat treatment temperature was 750°C in the argon atmosphere, which is consistent with the thermodynamic estimate that heat treatment temperature decreases as oxygen partial pressure decreases.


2018 ◽  
Vol 281 ◽  
pp. 959-963
Author(s):  
Feng Zhang ◽  
Chuan Qi Hu ◽  
Shi Chao Zhang ◽  
Hao Ran Sun ◽  
Yuan Tian ◽  
...  

In this paper, the modified phenolic resin-based adhesive was prepared by dissolving different components. After low temperature curing, SiC samples were bonded by the binder. The samples were treated at different temperatures (400°C, 800°C, 1200°C, 1500°C) under an inert atmosphere. The bonding strength of samples was tested after heat treatment at room temperature. The results showed that the bonding strength of the B4C modified phenolic resin (PF) based adhesive is the highest. When the heat treatment temperature was above 1200°C, the bond strength increased with the additive amount of boron carbide at room temperature. The microstructures of the samples were observed by optical microscope and scanning electron microscope. The effects of the modified filler and heat treatment temperature on the bonding strength of the phenolic resin based adhesive were investigated. The bonding strength of boron carbide-modified phenolic resin-based binder was tested under high temperature. It was found that the bond strength at high temperature was lower than that at room temperature, and the bond strength decreased with the increase of temperature.


2021 ◽  
Vol 353 ◽  
pp. 01020
Author(s):  
Yan Xu ◽  
Yinglai Liu ◽  
Xianghui Nie ◽  
Zhenjun Feng ◽  
Liang Li ◽  
...  

During the welding of in-service pipeline, natural gas is continuously transported in the pipeline, which maintains a high gas pressure. Therefore, the welding process is completed under strong cooling conditions, and welding delay crack is easy to occur. Preheating before welding and heat treatment after welding can effectively control the hardened microstructure, reduce the residual stress and ensure the welding quality. In this study, the influence of heating temperature on the bearing capacity of high steel grade pipe during in-service welding repair was studied. The high temperature tensile test was used to simulate the bearing capacity of the pipe under heating and high temperature environment. It is found that when the heating temperature is below 400°C, the pipe strength remains at the original level. With the increase of heating temperature, when the test temperature is higher than 400°C, the yield strength and tensile strength of the pipe decrease significantly. When the test temperature is 450°C, the yield strength and tensile strength of the material decrease by 15.8% and 11.1%, respectively, compared with the normal temperature, which are lower than the pipe standard requirements. Therefore, it is suggested that when the heat treatment temperature is higher than 400°C during in-service welding repair, it is necessary to consider reducing the pipeline pressure. At the same time, the box furnace heat treatment method was adopted to heat treat the pipe, and the tensile properties of the pipe after heat treatment were tested to analyze the bearing capacity of the pipe after heat treatment. It is found that when the heating temperature is higher than 700°C, the tensile properties of high grade pipeline steel pipe decrease sharply. It is suggested that when the heat treatment temperature is higher than 700°C, the risk assessment of the service safety of the heat treated pipeline should be carried out.


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