Persistence and effects of some chlorinated anilines on nitrification in soil

1969 ◽  
Vol 15 (7) ◽  
pp. 791-796 ◽  
Author(s):  
F. R. Thompson ◽  
C. T. Corke
Keyword(s):  
Nitrate Nitrogen ◽  
Ammonium Nitrogen ◽  
Chemical Degradation ◽  
Substituted Anilines ◽  
Molecular Configuration ◽  
Nitrite Nitrogen

A study was made of the effects of aniline and monochlorine-substituted, and dichlorine-substituted anilines on nitrification in Guelph loam. These compounds were shown to be inhibitory against the oxidation of ammonium-nitrogen to nitrite-nitrogen, but not nitrite-nitrogen to nitrate-nitrogen. The chlorinated derivatives showed increased toxicity against Nitrosomonas in the following order, 4-chloroaniline, 3-CA, 2,6-DCA, 2-CA, 2,4-DCA, 3,5-DCA and 2,5-DCA. Two patterns of inhibition of the process of nitrification were noted in these experiments which were, in part, dependent on structure of the compound used.Decomposition studies of these compounds in soil indicated that the dichloroanilines were more persistent than aniline or the monochloroanilines. The disappearance of 3,4-DCA from soil was primarily due to chemical degradation, although bacterial participation was also involved.A discussion of the relationships of molecular configuration, lipophilic properties, and persistence of aniline and monochlorine- and dichlorine-substituted anilines to toxicity is presented.

scholarly journals Influence of lime on the accumulation of mineral nitrogen in incubation experiments of peat soils

1957 ◽  
Vol 29 (1) ◽  
pp. 229-237
Author(s):  
Armi Kaila ◽  
Sylvi Soini
Keyword(s):  
Nitrate Nitrogen ◽  
Nitrogen Nutrition ◽  
Ammonium Nitrogen ◽  
Mineral Nitrogen ◽  
Peat Soils ◽  
Prolonged Incubation ◽  
The Third ◽  
Nitrite Nitrogen ◽  
Incubation Experiments ◽  
Three Samples

In the present paper the effect of lime on the mobilization of peat nitrogen was studied using incubation experiments under laboratory conditions. In the first experiment in which 13 samples of virgin peat soils were incubated for four months at 7°C, lime caused a marked nitrification of ammonium nitrogen in three samples, and a fairly low increase in the ammonium nitrogen content of five samples. The accumulation of total mineral nitrogen was benefited by lime in five samples and only in one of them could a marked increase be detected. In the second experiment the amounts of lime applied to five peat samples corresponded to 4000, 8000 or 12 000 kg/ha of CaCO3. At the end of an incubation period of four months at 9—15°C the total amounts of mineral nitrogen accumulated did not depend on the fate of liming, as did the nitrification in SCp-and BCp-samples, and also, in part, in the Sp- and CSp-samples. After the prolonged incubation up to 12 months the amount of lime applied had little or no effect upon the accumulation of nitrate-nitrogen or total mineral nitrogen except in the SCp-sample in which a positive correlation between these figures existed. Traces of nitrite-nitrogen were detected in some of the samples incubated for four months with the heaviest applications of lime. In the third experiment carried out at 7°C the treatment with lime was equal to that in the second series, but half of the pots were treated with ammonium nitrate corresponding to 100 kg/ha of nitrogen. The effect of lime on the treated samples appeared to be similar to that in the untreated one. Owing to the large variation, the fate of applied mineral nitrogen could not be distinctly detected. The loss of ammonium nitrogen through volatilization from the most heavily limed pots may be a possible explanation for the lower amounts of total mineral nitrogen in the incubated BCp-samples. Some reasons for these variable results are discussed and attention is also paid to the importance of nitrification on the nitrogen nutrition of plants.

Fluctuations in available mineral nitrogen in a flooded rice soil on the sub-coastal plains of the Adelaide river, N.T

1969 ◽  
Vol 9 (40) ◽  
pp. 532 ◽  
Author(s):  
RW Strickland
Keyword(s):  
Nitrate Nitrogen ◽  
Ammonium Nitrogen ◽  
Mineral Nitrogen ◽  
Rice Soil ◽  
Nitrogen Levels ◽  
Growing Period ◽  
Flooded Rice ◽  
Nitrite Nitrogen ◽  
Flooded Rice Soil ◽  
Nitrate And Nitrite

Soil from the 0-3 inch and 3-12 inch layers of nitrogen fertilized and unfertilized cropped and fallow plots was sampled at two=weekly intervals throughout the growing period of flooded rice. The soil was extracted with sodium acetate-acetic acid (pH 4.8) and ammonium, nitrate, and nitrite nitrogen determined. Nitrite nitrogen levels fell from 0.4 p.p.m. before flooding to less than 0.1 p.p.m. after flooding. Ammonium nitrogen reached peak mean levels of 57 and 55 lb an acre in the surface 12 inches of the soil in fertilized and unfertilized plots respectively, eight weeks after flooding. The effect of added nitrogen was lost within four weeks of flooding. Nitrate nitrogen in the surface 12 inches of soil reached peak levels of 40 and 10 lb an acre two weeks before flooding and 28 and 25 lb an acre eight weeks after flooding in fertilized and unfertilized plots respectively. Changes in the levels of available mineral nitrogen are discussed in relation to soil pH, Eh, and temperature

Study on the Salinity Domestication and Mechanism of Nitrite Nitrogen Removal of Acinetobacter lwoffii

2015 ◽  
Vol 1092-1093 ◽  
pp. 641-644 ◽  
Author(s):  
Chun Ying Yuan ◽  
Chuan Xu Li ◽  
Yue Wang ◽  
Qing Man Cui
Keyword(s):  
Nitrogen Removal ◽  
Sodium Nitrite ◽  
Nitrate Nitrogen ◽  
Ammonium Nitrogen ◽  
The Body ◽  
Body Protein ◽  
Bacteria Growth ◽  
Nitrite Nitrogen ◽  
High Concentrations

In this paper, the salinity domestication and mechanism of nitrite nitrogen removal ofAcinetobacter lwoffiiwere studied.The results showed that the optimum domestication salinityof the bacteria was 0.5% NaCl. It was speculated that the bacteria might have both oxidase andreductase, transform the nitrite nitrogen into ammonium nitrogen and nitrate nitrogen, and then usethem to synthesis the body protein. It also found that high concentrations of sodium nitrite hadinhibition effect on the bacteria growth.

Based on HYDRUS-1D to Shifosi Reservoir Tri-Nitrogen Conversion Simulation Research in Hyporheic Zone

2013 ◽  
Vol 726-731 ◽  
pp. 1683-1686
Author(s):  
Jun Pan ◽  
Te Leng ◽  
Yang Liu
Keyword(s):  
Hyporheic Zone ◽  
Nitrate Nitrogen ◽  
Ammonium Nitrogen ◽  
Mutual Transformation ◽  
Nitrogen Gas ◽  
Simulation Research ◽  
Nitrite Nitrogen ◽  
Profile Depth ◽  
Nitrogen Conversion ◽  
Hydrus 1D

To study the hyporhic zone of Shifosi reservoir in the conversion process between the three main pollutants nitrogen, this paper applied HYDRUS-1D software to simulate 200cm of soil profile depth in 200 hours mutual transformation behaviors. Results show that interact in complex environment and microbial flora, under the action of the 105cm of ammonium nitrogen and nitrite-nitrogen fully translated into nitrate-nitrogen, 200cm nitrate-nitrogen denitrification process almost completely converted into nitrogen gas.

scholarly journals Behavior of Nitrate-Nitrogen and Nitrite-Nitrogen in Drinking Water

2018 ◽  
Vol 23 (3) ◽  
pp. 139-143 ◽  
Author(s):  
YOKO SATO ◽  
MASAYUKI ISHIHARA ◽  
KOICHI FUKUDA ◽  
SHINGO NAKAMURA ◽  
KAORU MURAKAMI ◽  
...  
Keyword(s):  
Drinking Water ◽  
Nitrate Nitrogen ◽  
Nitrite Nitrogen

scholarly journals Observations on the mobilization of peat nitrogen in incubation experiments

1959 ◽  
Vol 31 (1) ◽  
pp. 268-281
Author(s):  
Jaakko Kivekäs ◽  
Erkki Kivinen
Keyword(s):  
Nitrate Nitrogen ◽  
Ammonium Nitrogen ◽  
The Other ◽  
Incubation Experiments ◽  
Different Types ◽  
Working Out ◽  
Original Amount

60 peat samples from northern Finland representing different types of peat were incubated in a laboratory at a temperature of 17—18° C. The ammonium nitrogen, the nitrate nitrogen and the pH in the samples were determined after one month of incubation as well as after three months of incubation. The results were compared to results from determinations made before incubation. An attempt was made to elucidate the factors that influence the mobilization of nitrogen. On the basis of the above results it is evident that the differences between the various peat types as mobilizers of nitrogen are under these circumstances not very distinct, nor do these differences seem to be dependent on the types of peat. The following facts can, however, be established: In the amounts of ammonium nitrogen an increase takes place in most groups of samples during the first month. This increase is fairly big in the Sphagnum-dominated peats. The increase in ammonium nitrogen continues in the unlimed samples in most peat groups during all three months of incubation. After three months of incubation the amount of ammonium nitrogen in the limed samples is smaller than in the unlimed samples, although it is usually bigger than in the original samples. After the first month of incubation the amounts of nitrate nitrogen in all types of peat have decreased compared to the amounts in the original samples. In the limed samples the decrease is not as great as in the unlimed ones. After three months of incubation the amount of nitrate nitrogen has considerably increased as compared to the amount after one month of incubation. In the limed samples it might to some extent exceed the original amount of nitrate nitrogen, however, this is seldom the case in the unlimed samples. If the results are calculated on the basis of weight unit, it can be stated that the ability to mobilize nitrogen is greater in the Sphagnum peats than in the other peat groups. Working out the results in kg per ha it will be noted that somewhat more nitrogen is mobilized in the Carex-dominated than in the Sphagnum-dominated peats. The results obtained by experiments in the laboratory are not directly applicable to conditions in the field.

scholarly journals Effect of Nitrite and Nitrate Concentrations on the Performance of AFB-MFC Enriched with High-Strength Synthetic Wastewater

2015 ◽  
Vol 2015 ◽  
pp. 1-6 ◽  
Author(s):  
Jian-sheng Huang ◽  
Ping Yang ◽  
Chong-ming Li ◽  
Yong Guo ◽  
Bo Lai ◽  
...  
Keyword(s):  
Fuel Cell ◽  
Microbial Fuel Cell ◽  
Power Density ◽  
Nitrate Nitrogen ◽  
High Strength ◽  
Synthetic Wastewater ◽  
Flow Mode ◽  
Anode Chamber ◽  
Nitrite Nitrogen ◽  
One Year

In order to study the effect of nitrite and nitrate on the performance of microbial fuel cell, a system combining an anaerobic fluidized bed (AFB) and a microbial fuel cell (MFC) was employed for high-strength nitrogen-containing synthetic wastewater treatment. Before this study, the AFB-MFC had been used to treat high-strength organic wastewater for about one year in a continuous flow mode. The results showed that when the concentrations of nitrite nitrogen and nitrate nitrogen were increased from 1700 mg/L to 4045 mg/L and 545 mg/L to 1427 mg/L, respectively, the nitrite nitrogen and nitrate nitrogen removal efficiencies were both above 99%; the COD removal efficiency went up from 60.00% to 88.95%; the voltage was about 375 ± 15 mV while the power density was at 70 ± 5 mW/m2. However, when the concentrations of nitrite nitrogen and nitrate nitrogen were above 4045 mg/L and 1427 mg/L, respectively, the removal of nitrite nitrogen, nitrate nitrogen, COD, voltage, and power density were decreased to be 86%, 88%, 77%, 180 mV, and 17 mW/m2 when nitrite nitrogen and nitrate nitrogen were increased to 4265 mg/L and 1661 mg/L. In addition, the composition of biogas generated in the anode chamber was analyzed by a gas chromatograph. Nitrogen gas, methane, and carbon dioxide were obtained. The results indicated that denitrification happened in anode chamber.

scholarly journals Impact of Temperature on Biological Denitrification Process

1970 ◽  
Vol 7 (1) ◽  
pp. 121-126 ◽  
Author(s):  
Iswar Man Amatya ◽  
Bhagwan Ratna Kansakar ◽  
Vinod Tare ◽  
Liv Fiksdal
Keyword(s):  
Filtration Rate ◽  
Nitrate Nitrogen ◽  
Nitrate Removal ◽  
Biological Method ◽  
Biological Denitrification ◽  
Nitrite Nitrogen ◽  
Nitrogen Concentrations ◽  
In Series ◽  
Nitrate And Nitrite ◽  
Denitrification Process

Nitrate removal in groundwater was carried out by biological method of denitrification process. The denitrification and without denitrification were performed in two different sets of reactors. Each reactor consists of two columns connected in series packed with over burnt bricks as media. The filtration rate varied from 5.3 to 52.6 m/day for denitrification process. The ammonia, nitrate and nitrite nitrogen concentrations were measured at inlet, intermediate ports and outlet. The temperature varied from 10 to 30°C at 2°C intervals. The results demonstrated that high amount of nitrate nitrogen removed in groundwater at denitrification process. The nitrate nitrogen removed by denitrification varied from 3.50 to 39.08 gm/m3/h at influent concentration from 6.32 to 111.04 gm/m3/h. Denitrification was found more significant above 16°C.Key words: Over burnt brick, Denitrification, Filtration rate and TemperatureJournal of the Institute of Engineering, Vol. 7, No. 1, July, 2009 pp. 121-126doi: 10.3126/jie.v7i1.2070 

The effects of ammonium and nitrate nitrogen on the growth of perennial rye grass

1936 ◽  
Vol 26 (2) ◽  
pp. 249-257 ◽  
Author(s):  
A. H. Lewis
Keyword(s):  
Nitrogen Content ◽  
Nitrate Nitrogen ◽  
Ammonium Nitrogen ◽  
Early Stages ◽  
Rye Grass

The results show clearly a more rapid and greater uptake of ammonium than of nitrate nitrogen by perennial rye grass grown in a sand-bentonite medium of pH 7·61. The extent to which the extra uptake with added ammonia was reflected in increased yields was dependent upon the age of the grass.Except in the very early stages the percentage nitrogen content of the herbage was higher where nitrate nitrogen was applied than where ammonium nitrogen was applied. This indicates that any nitrate absorbed by the plant was less, efficient in increasing yields than was ammonium nitrogen.The percentage P205 content of the grass was higher where the nitrogen was applied in the ammoniacal form than where it was applied as nitrate, and it appears that this greater P205 uptake with ammonium nitrogen resulted in increased growth.

Influence of Photochemical Reactions on the Content and Transformation of Mineral Nitrogen in Sod-Podzol Soil

2018 ◽  
Vol 781 ◽  
pp. 195-199
Author(s):  
Sergey Novoselov
Keyword(s):  
Nitrate Nitrogen ◽  
Ammonium Nitrogen ◽  
Photochemical Reactions ◽  
Mineral Nitrogen ◽  
Light Energy ◽  
Second Stage ◽  
Humus Substances ◽  
Microbiological Oxidation ◽  
Two Stages

The article discusses the photochemical effects of sunlight on the soil. Under the influence of light energy the amount of mineral and easy hydrolysable nitrogen, as well as labile humus substances increased in the soil. The photochemical destruction of humus substances was accompanied by an increase in their mobility and loss of colour. The article shows that the process of mineral nitrogen formation in the soil during the photochemical destruction of humus substances has two stages. The first stage includes photochemical reactions with the formation of ammonium nitrogen. The second stage is the microbiological oxidation of ammonium nitrogen to the nitrate nitrogen.

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