Ion/molecule reactions in allene. III. Reactions of the parent ion with neutral alkanes
Keyword(s):
Ion/molecule reactions between the ion C3H4+• ion, from allene and neutral alkanes were investigated by mass spectrometry. There are four H•/CH3•/H−/H2− transfer reactions and relative rate constants were calculated. The overall rates increased in the order CH4 < C2H6 < C3H8 < i-C4H10 < n-C4H10. There is also a stabilization process by alkanes of CeH8+• ion species, but its importance is lower than the above transfer processes.
1978 ◽
Vol 82
(22)
◽
pp. 2362-2369
◽
Keyword(s):
1996 ◽
Vol 03
(01)
◽
pp. 655-660
◽
1960 ◽
Vol 38
(11)
◽
pp. 2187-2195
◽
2006 ◽
Vol 40
(2)
◽
pp. 201-211
◽
1974 ◽
Vol 29
(4)
◽
pp. 642-649
◽