The effects of simulated acid precipitation in the surface horizons of two eastern Canadian forest Podzol soils
Undisturbed 18-cm soil cores of the L, F, H, Ae, and upper Bhf horizons of Ferro-Humic Podzols from the Turkey Lake Watershed (Ontario) and Montmorency Forest (Quebec) were treated in the laboratory with 10 m of simulated acid precipitation at pH 5.7, 3.5, and 2.0 over approximately 1 year. Leachate samples were collected from the bottom of the humus layer and the bottom of the soil core and the soils were analyzed at the completion of leaching. The soils from the two sites behaved similarly. Anion concentrations in the leachates adjusted to input levels after approximately 2 m of simulated rainfall. Leaching generally produced an initial flush of cations followed by lower concentrations. The pH 2.0 treatment caused major changes in some soil properties; the pH 3.5 and 5.7 treatment had a more modest effect. Base saturation was markedly reduced following the pH 2.0 treatment, slightly reduced following the pH 3.5 treatment, and slightly increased following the distilled water treatment. Cation exchange capacity was reduced only in the organic horizons receiving pH 2.0 treatment. Organic C, total N, and C/N ratios showed no changes on acidification. Leaching of Fe and Al was only substantial with the pH 2.0 treatment and much more Al than Fe was mobilized. Bicarbonate – extractable P in the mineral soil was doubled by the pH 2.0 treatment compared with the other treatments. X-ray diffraction of clays indicated a loss of hydroxyaluminum interlayers with increasing acidity, which is a stage in the acidic transformation of micaceous to smectite-like materials in Podzolic soils.