RELATIVE STABILITY OF SINGLE GRAPHITE SHEETS OF POSITIVE, NEGATIVE AND ZERO CURVATURE

1995 ◽  
Vol 09 (25) ◽  
pp. 3319-3332 ◽  
Author(s):  
L. N. BOURGEOIS ◽  
L. A. BURSILL

The relative stability of single graphite sheets of zero, positive and negative curvature is investigated through a simple model where both strain and dangling bond energy are taken into account. Although it is found that flat sheets are always more stable than negatively curved ones, calculations show that above a critical radius of curvature there is a crossover from positive to negative curvature as the more stable geometry for a single sheet. A maximum size for a negatively curved sheet is also predicted. Similarly, positive curvature is found to be energetically favored over zero curvature below some value of the curvature radius and above a certain number of atoms of the sheet. These results are discussed in view of available transmission electron microscopy observations of sp2 amorphous carbon.

Nanoscale ◽  
2017 ◽  
Vol 9 (37) ◽  
pp. 14208-14214 ◽  
Author(s):  
Zhongwei Zhang ◽  
Jie Chen ◽  
Baowen Li

From the mathematic category of surface Gaussian curvature, carbon allotropes can be classified into three types: zero curvature, positive curvature, and negative curvature.


1997 ◽  
Vol 3 (S2) ◽  
pp. 419-420
Author(s):  
Yukihito Kondo ◽  
Kunio Takayanagi

Fullerenes have many families such as simple ball-shaped fullerenes, nanotubes, and onions. Additionally torus, Y-shaped particle, and graphitic network with periodic holes or dimples have been theoretically anticipated. The presence of various shapes in fullerenes is mainly attributed to the combination of five-membered and seven-membered rings in addition to six-membered rings composing ordinary graphite crystal. The five-membered rings are necessary for positive curvature of the fullerenes, while the seven-membered rings for negative curvature. Experimentally, the negative curvature has been restricted so far to the joint between cone and tube in nanotubes and the spiral tubes. We have found a new type of multishell fullerenes with negative curvature which consist of three horns protrude into three-fold symmetric directions, referred as three-horned multishell fullerene (THF) in this report, using a high resolution transmission electron microscope (TEM). Here, we first describe the formation briefly and secondly concerned with procedure to determine the structure of the THF.


Author(s):  
A. Kosiara ◽  
J. W. Wiggins ◽  
M. Beer

A magnetic spectrometer to be attached to the Johns Hopkins S. T. E. M. is under construction. Its main purpose will be to investigate electron interactions with biological molecules in the energy range of 40 KeV to 100 KeV. The spectrometer is of the type described by Kerwin and by Crewe Its magnetic pole boundary is given by the equationwhere R is the electron curvature radius. In our case, R = 15 cm. The electron beam will be deflected by an angle of 90°. The distance between the electron source and the pole boundary will be 30 cm. A linear fringe field will be generated by a quadrupole field arrangement. This is accomplished by a grounded mirror plate and a 45° taper of the magnetic pole.


Author(s):  
Christine Escher ◽  
Catherine Searle

Abstract Let ℳ 0 n {\mathcal{M}_{0}^{n}} be the class of closed, simply connected, non-negatively curved Riemannian n-manifolds admitting an isometric, effective, isotropy-maximal torus action. We prove that if M ∈ ℳ 0 n {M\in\mathcal{M}_{0}^{n}} , then M is equivariantly diffeomorphic to the free, linear quotient by a torus of a product of spheres of dimensions greater than or equal to 3. As a special case, we then prove the Maximal Symmetry Rank Conjecture for all M ∈ ℳ 0 n {M\in\mathcal{M}_{0}^{n}} . Finally, we show the Maximal Symmetry Rank Conjecture for simply connected, non-negatively curved manifolds holds for dimensions less than or equal to 9 without additional assumptions on the torus action.


2021 ◽  
Vol 237 ◽  
pp. 03013
Author(s):  
Wenqiang Li ◽  
Hui Qi ◽  
Yongfeng Yang ◽  
Guojun Zhao ◽  
Rong Liu ◽  
...  

With the continuous development of west of China, a new kind of tunnel, namely spiral tunnel, has appeared in the expressway. Due to the special linear pattern, the resistance of airflow in spiral tunnel has been found to change, but there are few relevant researches at present. Therefore, numerical calculation method is used to study the variation of flow resistance in spiral pipe with different curvature. The results show that when the fluid flows in the spiral pipe, the wind speed is not uniformly distributed. The highest speed is not in the center of the pipe, but on the outside of the pipe, and the offset distance decreases with the increase of the radius of curvature. In addition, the change of flow resistance in spiral pipe is studied, and it is found that the change rate of flow resistance decreases with the increase of curvature radius. It shows that the radius of curvature is negatively correlated with the flow resistance.


1996 ◽  
Vol 11 (10) ◽  
pp. 2406-2415 ◽  
Author(s):  
R. Gopalan ◽  
T. Rajasekharan ◽  
T. Roy ◽  
G. Rangarajan ◽  
V. Ganesan ◽  
...  

YBa2Cu3O7 (123) samples with varying Y2BaCuO5 (211) concentrations (0 mol%, 20 mol%, 28 mol%, and 50 mol%) were synthesized by the melt-growth process. Microstructural characterizations were done using x-ray diffraction (XRD), optical microscopy, scanning electron microscopy, and transmission electron microscopy (TEM). It was found that 123 platelet width, crack width between the platelets, and 211 particle size decreased systematically with increasing 211 concentration. TEM study showed that there is a critical radius of curvature (rc ≤ 0.2 μm-0.3 μm) of the 123/211 interface where defects/contrasts of strain field start to appear, and these defects are believed to be responsible for pinning the magnetic flux. Microhardness measurements showed that Vickers hardness (VHN) increases with increasing 211 content. Critical current density (Jc) values obtained from magnetization measurements using a SQUID magnetometer were found to increase in melt-grown samples by the addition of 211 content.


Author(s):  
Ihor RUDKO ◽  
Borys BAKAY ◽  
Abdullah AKAY ◽  
Vasyl BARYLIAK ◽  
Stanislav HORZOV

This article reviews the problem of measuring the actual radius of curvature for curved sections of existing forest roads, as forestry enterprises require reliable technical information about the current conditions of operated transport networks. It was identified that at this moment, a selection of methods are used for measuring the radii of horizontal curved sections of roads, which have certain advantages and disadvantages in specific natural production conditions. For calculating the radius of curvature for auto forest road projects it is recommended to apply the method of measured angles by chord angle deviation, which is sufficiently accurate for engineering purposes and does not require usage of special high-precision equipment and tools.


2008 ◽  
Vol 23 (5) ◽  
pp. 1393-1397 ◽  
Author(s):  
Yongzhen Yang ◽  
Xuguang Liu ◽  
Bingshe Xu

Fe-encapsulating carbon nano onionlike fullerenes (NOLFs) were obtained by chemical vapor deposition (CVD) using heavy oil residue as carbon source and ferrocene as catalyst precursor in an argon flow of 150 mL/min at 900 °C for 30 min. Field-emission scanning electron microscopy (FE-SEM), high-resolution transmission electron microscopy (HRTEM), energy-dispersive spectroscopy (EDS), x-ray diffraction (XRD), and Raman spectroscopy were used to characterize morphology and microstructure of the products. The results show that Fe-encapsulating NOLFs collected at the outlet zone of quartz tube had core/shell structures with sizes ranging from 3 to 6 nm and outer shells composed of poorly crystallized graphitic layers. Their growth followed particle self-assembling growth mechanism, and all atoms in the graphite sheets primarily arose from Fe-carbide nanoparticles.


2000 ◽  
Vol 610 ◽  
Author(s):  
F. Cristiano ◽  
B. Colombeau ◽  
B. de Mauduit ◽  
F. Giles ◽  
M. Omri ◽  
...  

AbstractIn this work, we have studied the relative stability of perfect (PDLs) and faulted (FDLs) dislocation loops formed during annealing of preamorphised silicon. In particular, we have investigated the effect of the initial supersaturation of Si interstitial atoms (Si(int)s) created by the implantation process on their thermal evolution. Transmission Electron Microscopy analysis shows that in samples with a low Si interstitial supersaturation, FDLs are the dominant defects while PDLs appear as the most stable defects in highly supersaturated samples. We have calculated the formation energies of both types of dislocation loops and found that, for defects of the same size, FDLs are more energetically stable than PDLs, if their diameter is smaller than 80 nm and viceversa. The application of these calculations to the samples studied in this work indicates that a direct correspondence exists between the formation energy of the two defect families and the number of atoms bound to them. Moreover, we have shown that the relative stability of FDLs and PDLs depends on the initial supersaturation of Si(int)s created during the implantation process.


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