Donor States in Spherical GaAs-Ga1-xAlxAs Quantum Dots

1997 ◽  
Vol 11 (15) ◽  
pp. 673-679 ◽  
Author(s):  
Ecaterina C. Niculescu ◽  
Ana Niculescu

The effect of the central cell correction on the binding energies of shallow donors in a spherical GaAs-Ga 1-x Al x As quantum dot is studied. The effective-mass approximation within a variational scheme is adopted and central cell corrections are calculated by using a Coulomb potential modified with an adjustable parameter. For small values of the radius of the dot large corrections are obtained for the shallow donors studied.

2001 ◽  
Vol 692 ◽  
Author(s):  
C. A. Duque ◽  
N. Porras-Montenegro ◽  
M. de Dios-Leyva ◽  
L. E. Oliveira

AbstractThe evidence of a parabolic potential well in quantum wires and dots was reported in the literature, and a parabolic potential is often considered to be a good representation of the “barrier” potential in semiconductor quantum dots. In the present work, the variational and fractionaldimensional space approaches are used in a thorough study of the binding energy of on-center shallow donors in spherical GaAs-Ga1-xAlxAs quantum dots with potential barriers taken either as rectangular [Vb (eV) ??1.247 x for r >] or parabolic [Vb (r) ??β2?r2] isotropic barriers. We define the parabolic potential with a β?parameter chosen so that it results in the same E0 groundstate energy as for the spherical quantum dot of radius R and rectangular potential in the absence of the impurity. Calculations using either the variational or fractional-dimensional approaches both for rectangular and parabolic potential result in essentially the same on-center binding energies provided the dot radius is not too small. This indicates that both potentials are alike representations of the quantum-dot barrier potential for a radius R quantum dot provided the parabolic potential is defined with?β?chosen as mentioned above.


2009 ◽  
Vol 23 (26) ◽  
pp. 5109-5118 ◽  
Author(s):  
A. JOHN PETER

The binding energy of shallow hydrogenic impurities in parabolic GaAs/GaAlAs quantum dots is calculated as a function of dot radius in the influence of magnetic field. The binding energy has been calculated following a variational procedure within the effective-mass approximation. Calculations are presented with constant effective-mass and position dependent effective masses. A finite confining potential well with depth is determined by the discontinuity of the band gap in the quantum dot and the cladding. The results show that the impurity binding energy (i) increases as the dot radius decreases for the infinite case, (ii) reaches a peak value around 1R* as the dot radius decreases and then diminishes to a limiting value corresponding to the radius for which there are no bound states in the well for the infinite case, and (iii) increases with the magnetic field. Also it is found that (i) the use of constant effective mass (0.067 m0) is justified for dot sizes ≥ a* where a* is the effective Bohr radius which is about 100 Å for GaAs , in the estimation of ionization energy and (ii) the binding energy shows complicated behavior when the position dependent mass is included for the dot size ≤ a*. These results are compared with the available existing literatures.


2020 ◽  
Author(s):  
Alyxandra Thiessen ◽  
Lijuan Zhang ◽  
Anton Oliynyk ◽  
Haoyang Yu ◽  
Kevin O'Connor ◽  
...  

<p>Two quantum dots, both alike in composition, but differing in structure, where we lay our scene. From broader classes, to bring deeper understanding, to the crystalline core that drives the quantum dot's sheen. In this contribution we examine two families of silicon quantum dots (SiQDs) that bring to mind the Capulets and the Montagues in Shakespeare’s Romeo and Juliet because of their stark similarities and differences. SiQDs are highly luminescent, heavy-metal-free and based upon earth-abundant elements. As such, they have attracted attention for far reaching applications ranging from biological imaging to luminescent solar concentrators to light-emitting diodes that rely on their size-dependent optical response. Unfortunately, correlating SiQD “size” to their photoluminescence maximum is often challenging. Herein, we provide essential structural insight into the correlation of SiQD dimension and PL maximum through a direct comparison of samples that exhibit statistically identical physical dimensions (d<sub>TEM</sub>) and chemical compositions, but different crystallite size (d<sub>XRD</sub>) and PL maxima. We then expand the scope of this investigation and systematically compare groupings of SiQDs: one in which the d<sub>XRD</sub> and d<sub>TEM</sub> agree and one where d<sub>XRD </sub>< d<sub>TEM</sub>. This latter comparison clearly shows d<sub>XRD</sub> better predicts SiQD optical response when using the well-established effective mass approximation. </p>


2014 ◽  
Vol 895 ◽  
pp. 415-419
Author(s):  
Chin Y. Woon ◽  
Geri Gopir ◽  
Ahmad Puaad Othman

Recently, theoretical analysis of the electronic properties of quantum dot has attracted a great attention when modern nanotechnology has made it possible to fabricate a realistic quantum dots in laboratory [. Quantum dot structures which provide electron confinement in three dimensions can be grown by the so called self-assembly effect or Stranski-Krastanov growth mode. Particular interest attracts ordering effects in StranskiKrastanow growth which proceeds on a lattice-mismatched substrate via formation of essentially three-dimensional islands. This is especially true for the InAs-GaAs system where the lattice mismatch is high and the nucleation process is rapid. Although, quantum dots have being studied experimentally but large amount of numerical studies of electron confined states also have been developed to simulate electronic and optical properties in quantum dots. The single band effective mass is one of the formalism of envelope function which has been widely used to solve quantum dot systems. However, the effective massm*is usually position dependent in semiconductor heterostrutures. Consequently, the concerning about the form of the boundary conditions to impose on different material interface arisen [3]. According to the present works [2, , the position dependent Hamiltonian is given by: . wherem=m(r) is the position dependent effective mass of an electron in conduction band. The constant α, β, and γ is arbitrary set to satisfy α + β + γ = -1. Various approximations regarding the actual constant of α, β, and γ in position dependent effective mass have been observed, example Gora & William (by putting α = -1 and β = γ = 0), Zhu & Kroemer (α = γ = -1/2 and β = 0), and BenDaniel-Duke (α = γ = 0 and β = -1). Among them, β = 1 (known as the Ben DanielDuke Hamiltonian [) is most popular method for solving mass continuity problem on the classic Hamiltonian [. Extensively, these interface condition was been used to solved most of the heterostructure problem such as quantum dots [. However, there is a qualitative argument based upon the Ben DanielDuke choice violates the Heisenberg uncertainty principle and the issue of the correct effective-mass equation was further questioned by Pistol, M. E. which he claims that all the possible equations lead to the same interfacial conditions on the envelope function [. In this paper, we will investigate the effect of discontinuity mass within interface of two semiconductor materials inside InAs-GaAs quantum dot by using the classic constant mass Hamiltonian (CH), position dependent effective mass Hamiltonian (PDH) and Ben Daniel and Duke Hamiltonian (BDH). The most common analytic methods are solving the transcendental equation obtained by matching the interface boundary condition on the envelope function. But this kind of method will suffer from complexity of model quantum dots that contain multiple layer or geometry that unable to derive into analytic formulation. Thus, this study will focus on comparison between difference finite difference formalism to illustrate the mass discontinuity effect on the numerical solution.


2005 ◽  
Vol 94 (9) ◽  
Author(s):  
Serguei B. Orlinskii ◽  
Jan Schmidt ◽  
Edgar J. J. Groenen ◽  
Pavel G. Baranov ◽  
Celso de Mello Donegá ◽  
...  

2011 ◽  
Vol 10 (04n05) ◽  
pp. 665-668 ◽  
Author(s):  
A. MERWYN JASPER DE REUBEN ◽  
K. JAYAKUMAR

The effect of geometry, concentration of Mn ion and the magnetic field on the binding energy of a donor and the donor bound magnetic polaronic shift in a finite Cd 1–x1 Mn x1 Te / Cd 1–x2 Mn x2 Te Quantum Dot within the effective mass approximation is carried out employing the variational principle. The results are presented and discussed.


2010 ◽  
Vol 24 (29) ◽  
pp. 5761-5770 ◽  
Author(s):  
A. MIGUEZ ◽  
R. FRANCO ◽  
J. SILVA-VALENCIA

We calculated the binding energies of shallow donors and acceptors in a spherical GaAs - Ga 1-x Al x As quantum dot under the combined effect of isotropic hydrostatic pressure and an intense laser. We used a variational approach within the effective mass approximation. The binding energy was computed as a function of hydrostatic pressure, dot sizes and laser field amplitude. The results showed that the impurity binding energy increases with pressure and decreases with the laser field amplitude when other parameters are fixed. We also found that the pressure effects are more dramatic for donor than acceptor impurities, especially for quantum dots with small radii.


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