scholarly journals Evaluation of the moisture content of tapioca starch using near-infrared spectroscopy

2015 ◽  
Vol 08 (02) ◽  
pp. 1550014 ◽  
Author(s):  
Kittisak Phetpan ◽  
Panmanas Sirisomboon
Keyword(s):  
Moisture Content ◽  
Near Infrared ◽  
Partial Least Square ◽  
Least Square ◽  
Coefficient Of Determination ◽  
Calibration Model ◽  
Drying Process ◽  
Data Set ◽  
Prediction Ability ◽  
Tapioca Starch

The purpose of this study was to develop a calibration model to evaluate the moisture content of tapioca starch using the near-infrared (NIR) spectral data in conjunction with partial least square (PLS) regression. The prediction ability was assessed using a separate prediction data set. Three groups of tapioca starch samples were used in this study: tapioca starch cake, dried tapioca starch and combined tapioca starch. The optimum model obtained from the baseline-offset spectra of dried tapioca starch samples at the outlet of the factory drying process provided a coefficient of determination (R2), standard error of prediction (SEP), bias and residual prediction deviation (RPD) of 0.974, 0.16%, -0.092% and 7.4, respectively. The NIR spectroscopy protocol developed in this study could be a rapid method for evaluation of the moisture content of the tapioca starch in factory laboratories. It indicated the possibility of real-time online monitoring and control of the tapioca starch cake feeder in the drying process. In addition, it was determined that there was a stronger influence of the NIR absorption of both water and starch on the prediction of moisture content of the model.

Hyperspectral Imaging for Predicting Soluble Solid Content of Starfruit

2015 ◽  
Vol 73 (1) ◽  
Author(s):  
Feri Candra ◽  
Syed Abd. Rahman Abu Bakar
Keyword(s):  
Hyperspectral Imaging ◽  
Near Infrared ◽  
Imaging System ◽  
Solid Content ◽  
Partial Least Square ◽  
Least Square ◽  
Coefficient Of Determination ◽  
Soluble Solid Content ◽  
Calibration Model ◽  
Soluble Solid

Hyperspectral imaging technology is a powerful tool for non-destructive quality assessment of fruits. The objective of this research was to develop novel calibration model based on hyperspectral imaging to estimate soluble solid content (SSC) of starfruits. A hyperspectral imaging system, which consists of a near infrared  camera, a spectrograph V10, a halogen lighting and a conveyor belt system, was used in this study to acquire hyperspectral  images of the samples in visible and near infrared (500-1000 nm) regions. Partial least square (PLS) was used to build the model and to find the optimal wavelength. Two different masks were applied for obtaining the spectral data. The optimal wavelengths were evaluated using multi linear regression (MLR). The coefficient of determination (R2) for validation using the model with first mask (M1) and second mask (M2) were 0.82 and 0.80, respectively.

scholarly journals Near Infrared (NIR) Spectroscopy to Predict Physical Properties of Acacia mangium at Three Different Age Classes

2017 ◽  
Vol 4 (1) ◽  
pp. 7-12
Author(s):  
Lina Karlinasari ◽  
Merry Sabed
Keyword(s):  
Moisture Content ◽  
Physical Properties ◽  
Wood Density ◽  
Near Infrared ◽  
Acacia Mangium ◽  
Nir Spectroscopy ◽  
Solid Wood ◽  
Partial Least Square ◽  
Least Square ◽  
Calibration Model

Near Infrared (NIR) spectroscopy has been used to predict several properties of wood. This is one of the nondestructive testing (NDT) methods providing fast and reliable wood characterization analysis which can be applied in various manufacture industry, included forest sector, in control and process monitoring task. Moisture content and wood density are important properties related to strength properties. The aim of this study was to evaluate NIR technique in obtaining calibration models for determining moisture content and wood density of Acacia mangium in the age of 5, 6, 7 years-old. Spectra were measured in both solid and ground wood samples. Laboratory testing of physical properties were determined by volumetric and gravimetric methods. The laboratory values were correlated with the NIR spectra using multivariate analysis statistic of Partial Least Square (PLS). The calibration-validation model of this relationship was evaluated by using the coefficient of determination (R2), root means square error of calibration (RMSEC) and cross-validation (RMSECV) values. Generally, a better accuracy was obtained by using calibration model of ground wood compared to that of solid wood samples. At age of 7 years-old, the R2 allowed the use of NIR spectra of solid samples to develop calibration and validation model, especially for wood density. Based on ratio of performance to deviation (RPD) and RMSE, ground samples demonstrated a higher value of RPD, RMSEC, and RMSECV compared to solid wood for all properties.

Prediction of internal compositions change in potato during storage using visible/near-infrared (Vis/NIR) spectroscopy

2020 ◽  
Vol 16 (4) ◽  
Author(s):  
Roya Farhadi ◽  
Amir H. Afkari-Sayyah ◽  
Bahareh Jamshidi ◽  
Ahmad Mousapour Gorji
Keyword(s):  
Moisture Content ◽  
Cold Storage ◽  
Near Infrared ◽  
Cross Validation ◽  
Nir Spectroscopy ◽  
Reducing Sugar ◽  
Partial Least Square ◽  
Least Square ◽  
Coefficient Of Determination ◽  
Reliable Technique

AbstractVisible/Near-infrared (Vis/NIR) spectroscopy at a range of 450–1000 nm was used to predict the values of three qualitative variables (starch, reducing sugar, and moisture content) on 200 potato tubers from 2 potato genotypes (‘Agria’ and ‘Clone 397009–8’) stored in both traditional and cold storages. After spectroscopy measurements, these variables were measured using reference methods. Then, Partial Least Square (PLS) models were developed. To evaluate developed models, Root Mean Square Error of calibration and cross validation (RMSEC and RMSECV), as well as coefficient of determination for calibration and cross validation (R2C and R2CV), and Residual Predictive Deviation (RPD) were used. The best prediction belonged to reducing sugar with statistical values of R2C = 0.99, R2CV = 0.98, RMSEC = 0.029, RMSECV = 0.037, and RPD = 7.57 in ‘Clone’ genotype stored under cold storage. The weakest prediction was related to moisture content with statistical values of R2C = 0.93, R2CV = 0.92, RMSEC = 0.268, RMSECV = 0.279, and RPD = 6.45 in stored ‘Clone’ genotypes under cold storage. Results of the study showed that, Vis/NIR spectroscopy as a non-destructive, fast, and reliable technique can be used for prediction of inner compositions of stored potatoes.

Quantitative Evaluation of Glycyrrhizic Acid That Affects the Product Quality of Kakkonto Extract, a Traditional Herbal Medicine, by a Chemometric near Infrared Spectroscopic Method

2009 ◽  
Vol 17 (2) ◽  
pp. 89-100 ◽  
Author(s):  
Yoshifumi Mohri ◽  
Yukoh Sakata ◽  
Makoto Otsuka
Keyword(s):  
Acid Content ◽  
Glycyrrhizic Acid ◽  
Near Infrared ◽  
Spectroscopic Method ◽  
Nir Spectroscopy ◽  
Partial Least Square ◽  
Least Square ◽  
Wave Number ◽  
Coefficient Of Determination ◽  
Calibration Model

The purpose of this study was to construct a calibration model for the prediction of glycyrrhizic acid content in Kakkonto extracts using near infrared (NIR) spectroscopy. The NIR spectra of the Kakkonto extracts were obtained using a Fourier transform NIR spectrometer in transmission mode and chemometric analysis was performed using partial least-square (PLS) regression. The calibration model was constructed by the selection of wave number regions and by the first derivative pre-treatment of NIR spectra. The glycyrrhizic acid content could be predicted using a calibration model comprising three principal components (PCs) obtained by the PLS method. The calibration model was theoretically analysed by investigating the standard error of prediction values, the loading vectors of each PC and the regression vector. The relationship between the actual and predicted glycyrrhizic acid contents in the Kakkonto extract exhibited a straight line with a coefficient of determination of 0.966 (calibration) and 0.945 (validation), respectively. The predicted glycyrrhizic acid content in the Kakkonto extract was within the 95% predictive intervals.

scholarly journals Histamine Control in Raw and Processed Tuna: A Rapid Tool Based on NIR Spectroscopy

Foods ◽  
2021 ◽  
Vol 10 (4) ◽  
pp. 885
Author(s):  
Sergio Ghidini ◽  
Luca Maria Chiesa ◽  
Sara Panseri ◽  
Maria Olga Varrà ◽  
Adriana Ianieri ◽  
...  
Keyword(s):  
Root Mean Square ◽  
Near Infrared ◽  
Nir Spectroscopy ◽  
Partial Least Square ◽  
Least Square ◽  
Partial Least Square Regression ◽  
Coefficient Of Determination ◽  
Mean Square ◽  
Tuna Fish ◽  
Mean Square Errors

The present study was designed to investigate whether near infrared (NIR) spectroscopy with minimal sample processing could be a suitable technique to rapidly measure histamine levels in raw and processed tuna fish. Calibration models based on orthogonal partial least square regression (OPLSR) were built to predict histamine in the range 10–1000 mg kg−1 using the 1000–2500 nm NIR spectra of artificially-contaminated fish. The two models were then validated using a new set of naturally contaminated samples in which histamine content was determined by conventional high-performance liquid chromatography (HPLC) analysis. As for calibration results, coefficient of determination (r2) > 0.98, root mean square of estimation (RMSEE) ≤ 5 mg kg−1 and root mean square of cross-validation (RMSECV) ≤ 6 mg kg−1 were achieved. Both models were optimal also in the validation stage, showing r2 values > 0.97, root mean square errors of prediction (RMSEP) ≤ 10 mg kg−1 and relative range error (RER) ≥ 25, with better results showed by the model for processed fish. The promising results achieved suggest NIR spectroscopy as an implemental analytical solution in fish industries and markets to effectively determine histamine amounts.

scholarly journals Application of FTIR Spectroscopy and Chemometrics for Halal Authentication of Beef Meatball Adulterated with Dog Meat

2018 ◽  
Vol 18 (2) ◽  
pp. 376 ◽  
Author(s):  
Wiranti Sri Rahayu ◽  
Abdul Rohman ◽  
Sudibyo Martono ◽  
Sudjadi Sudjadi
Keyword(s):  
Ftir Spectroscopy ◽  
Reliable Method ◽  
Cross Validation ◽  
Partial Least Square ◽  
Least Square ◽  
Coefficient Of Determination ◽  
Calibration Model ◽  
Mean Square ◽  
Folch Method ◽  
Halal Authentication

Beef meatball is one of the favorite meat-based food products among Indonesian community. Currently, beef is very expensive in Indonesian market compared to other common meat types such as chicken and lamb. This situation has intrigued some unethical meatball producers to replace or adulterate beef with lower priced-meat like dog meat. The objective of this study was to evaluate the capability of FTIR spectroscopy combined with chemometrics for identification and quantification of dog meat (DM) in beef meatball (BM). Meatball samples were prepared by adding DM into BM ingredients in the range of 0–100% wt/wt and were subjected to extraction using Folch method. Lipid extracts obtained from the samples were scanned using FTIR spectrophotometer at 4000–650 cm-1. Partial least square (PLS) calibration was used to quantify DM in the meatball. The results showed that combined frequency regions of 1782–1623 cm-1 and 1485-659 cm-1 using detrending treatment gave optimum prediction of DM in BM. Coefficient of determination (R2) for correlation between the actual value of DM and FTIR predicted value was 0.993 in calibration model and 0.995 in validation model. The root mean square error of calibration (RMSEC) and standard error of cross validation (SECV) were 1.63% and 2.68%, respectively. FTIR spectroscopy combined with multivariate analysis can serve as an accurate and reliable method for analysis of DM in meatball.

scholarly journals Estimating Soil Organic Carbon in Agricultural Gypsiferous Soils by Diffuse Reflectance Spectroscopy

Water ◽  
2020 ◽  
Vol 12 (1) ◽  
pp. 261 ◽  
Author(s):  
Maria Marques ◽  
Ana Álvarez ◽  
Pilar Carral ◽  
Iris Esparza ◽  
Blanca Sastre ◽  
...  
Keyword(s):  
Organic Carbon ◽  
Soil Organic Carbon ◽  
Near Infrared ◽  
Diffuse Reflectance Spectroscopy ◽  
Partial Least Square ◽  
Least Square ◽  
Partial Least Square Regression ◽  
Prediction Ability ◽  
Greenhouse Gas Inventories ◽  
Starting Point

Contents of soil organic carbon (SOC), gypsum, CaCO3, and quartz, among others, were analyzed and related to reflectance features in visible and near-infrared (VIS/NIR) range, using partial least square regression (PLSR) in ParLes software. Soil samples come from a sloping olive grove managed by frequent tillage in a gypsiferous area of Central Spain. Samples were collected in three different layers, at 0–10, 10–20 and 20–30 cm depth (IPCC guidelines for Greenhouse Gas Inventories Programme in 2006). Analyses were performed by C Loss-On-Ignition, X-ray diffraction and water content by the Richards plates method. Significant differences for SOC, gypsum, and CaCO3 were found between layers; similarly, soil reflectance for 30 cm depth layers was higher. The resulting PLSR models (60 samples for calibration and 30 independent samples for validation) yielded good predictions for SOC (R2 = 0.74), moderate prediction ability for gypsum and were not accurate for the rest of rest of soil components. Importantly, SOC content was related to water available capacity. Soils with high reflectance features held c.a. 40% less water than soils with less reflectance. Therefore, higher reflectance can be related to degradation in gypsiferous soil. The starting point of soil degradation and further evolution could be established and mapped through remote sensing techniques for policy decision making.

scholarly journals Monitoring of CO2 Absorption Solvent in Natural Gas Process Using Fourier Transform Near-Infrared Spectrometry

2020 ◽  
Vol 2020 ◽  
pp. 1-9
Author(s):  
Mohd Yusop Nurida ◽  
Dolmat Norfadilah ◽  
Mohd Rozaiddin Siti Aishah ◽  
Chan Zhe Phak ◽  
Syafiqa M. Saleh
Keyword(s):  
Fourier Transform ◽  
Near Infrared ◽  
Nir Spectroscopy ◽  
Partial Least Square ◽  
Least Square ◽  
Infrared Spectrometry ◽  
Calibration Model ◽  
Co2 Absorption ◽  
Processing Unit

The analytical methods for the determination of the amine solvent properties do not provide input data for real-time process control and optimization and are labor-intensive, time-consuming, and impractical for studies of dynamic changes in a process. In this study, the potential of nondestructive determination of amine concentration, CO2 loading, and water content in CO2 absorption solvent in the gas processing unit was investigated through Fourier transform near-infrared (FT-NIR) spectroscopy that has the ability to readily carry out multicomponent analysis in association with multivariate analysis methods. The FT-NIR spectra for the solvent were captured and interpreted by using suitable spectra wavenumber regions through multivariate statistical techniques such as partial least square (PLS). The calibration model developed for amine determination had the highest coefficient of determination (R2) of 0.9955 and RMSECV of 0.75%. CO2 calibration model achieved R2 of 0.9902 with RMSECV of 0.25% whereas the water calibration model had R2 of 0.9915 with RMSECV of 1.02%. The statistical evaluation of the validation samples also confirmed that the difference between the actual value and the predicted value from the calibration model was not significantly different and acceptable. Therefore, the amine, CO2, and water models have given a satisfactory result for the concentration determination using the FT-NIR technique. The results of this study indicated that FT-NIR spectroscopy with chemometrics and multivariate technique can be used for the CO2 solvent monitoring to replace the time-consuming and labor-intensive conventional methods.

scholarly journals In-Situ Screening of Soybean Quality with a Novel Handheld Near-Infrared Sensor

Sensors ◽  
2020 ◽  
Vol 20 (21) ◽  
pp. 6283
Author(s):  
Didem Peren Aykas ◽  
Christopher Ball ◽  
Amanda Sia ◽  
Kuanrong Zhu ◽  
Mei-Ling Shotts ◽  
...  
Keyword(s):  
Amino Acids ◽  
Fatty Acid ◽  
Moisture Content ◽  
Real Time ◽  
Crude Protein ◽  
Near Infrared ◽  
Partial Least Square ◽  
Least Square ◽  
Partial Least Square Regression ◽  
Sensor Technology

This study evaluates a novel handheld sensor technology coupled with pattern recognition to provide real-time screening of several soybean traits for breeders and farmers, namely protein and fat quality. We developed predictive regression models that can quantify soybean quality traits based on near-infrared (NIR) spectra acquired by a handheld instrument. This system has been utilized to measure crude protein, essential amino acids (lysine, threonine, methionine, tryptophan, and cysteine) composition, total fat, the profile of major fatty acids, and moisture content in soybeans (n = 107), and soy products including soy isolates, soy concentrates, and soy supplement drink powders (n = 15). Reference quantification of crude protein content used the Dumas combustion method (AOAC 992.23), and individual amino acids were determined using traditional protein hydrolysis (AOAC 982.30). Fat and moisture content were determined by Soxhlet (AOAC 945.16) and Karl Fischer methods, respectively, and fatty acid composition via gas chromatography-fatty acid methyl esterification. Predictive models were built and validated using ground soybean and soy products. Robust partial least square regression (PLSR) models predicted all measured quality parameters with high integrity of fit (RPre ≥ 0.92), low root mean square error of prediction (0.02–3.07%), and high predictive performance (RPD range 2.4–8.8, RER range 7.5–29.2). Our study demonstrated that a handheld NIR sensor can supplant expensive laboratory testing that can take weeks to produce results and provide soybean breeders and growers with a rapid, accurate, and non-destructive tool that can be used in the field for real-time analysis of soybeans to facilitate faster decision-making.

A Consensus Partial Least Squares Regression for Analysis of Near-Infrared Spectroscopy

2013 ◽  
Vol 765-767 ◽  
pp. 528-531
Author(s):  
Dan Peng ◽  
Qing Chen Nie
Keyword(s):  
Least Squares ◽  
Partial Least Squares ◽  
Near Infrared ◽  
Partial Least Square ◽  
Least Square ◽  
Partial Least Square Regression ◽  
Least Squares Regression ◽  
Prediction Ability ◽  
Successful Model ◽  
Consensus Strategy

To improve the prediction performance of partial least square regression algorithm (PLS), the consensus strategy was applied to develop the multivariate regression model using near-infrared (NIR) spectra and named as C-PLS. Coupled with the consensus strategy, this algorithm can take the advantage of reducing dependence on single model to obtain prediction precision and stability by randomly changing the calibration set. Through an optimization of the parameters involved in the model including criterion threshold and number of sub-models, a successful model was achieved by effectively combining many sub-models with different accuracy and diversity together. To validate the C-PLS algorithm, it was applied to measure the original extract concentration of beer using NIR spectra. The experimental results showed that the prediction ability and robustness of model obtained in subsequent partial least squares calibration using consensus strategy was superior to that obtained using conventional PLS algorithm, and the root mean square error of prediction can improve by up to 45.2%, indicating that it is an efficient tool for NIR spectra regression.

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