scholarly journals Impact of Shell Composition, Thickness and Heating Temperature on the Performance of Nickel-Rich Cobalt-Free Core-Shell Materials

2021 ◽  
Vol 167 (16) ◽  
pp. 160556
Author(s):  
Yulong Liu ◽  
Haohan Wu ◽  
Yiqiao Wang ◽  
Kui Li ◽  
Shuo Yin ◽  
...  
2003 ◽  
Vol 789 ◽  
Author(s):  
Mathew M. Maye ◽  
Sandy Chen ◽  
Wai-Ben Chan ◽  
Lingyan Wang ◽  
Peter Njoki ◽  
...  

ABSTRACTThe application of molecularly-capped gold nanoparticles (1–5 nm) in catalysis (e.g., electrocatalytic oxidation of CO and methanol) requires a thorough understanding of the surface composition and structural properties. Gold nanoparticles consisting of metallic or alloy cores and organic encapsulating shells serve as an intriguing model system. One of the challenges for the catalytic application is the ability to manipulate the core and the shell properties in controllable ways. There is a need to understand the relative core-shell composition and the ability to remove the shell component under thermal treatment conditions. In this paper, we report results of a thermogravimetric analysis of the alkanethiolate monolayer-capped gold nanoparticles. This investigation is aimed at enhancing our understanding of the relative core-shell composition and thermal profiles.


2017 ◽  
Vol 14 (3) ◽  
pp. 757-769 ◽  
Author(s):  
Mohammed S. Alqahtani ◽  
M. Saiful Islam ◽  
Satheesh Podaralla ◽  
Radhey S. Kaushik ◽  
Joshua Reineke ◽  
...  

2011 ◽  
Vol 1342 ◽  
Author(s):  
Moritz Milde ◽  
Sofia Dembski ◽  
Sabine Rupp ◽  
Carsten Gellermann ◽  
Gerhard Sextl ◽  
...  

ABSTRACTSiO2 nanoparticles (NPs) were coated with Eu3+-doped calcium phosphate (CP) and Mn2+-doped ZnO to give Zn2SiO4 via a modified Pechini sol-gel process. Annealing at high temperatures resulted in NPs with an amorphous core and a crystalline luminescent shell. It was shown that this procedure can be applied to silica cores with diameters below 300 nm. By transmission electron microscopy, elemental analysis and from X-ray diffraction patterns it was determined that shell composition and structure are influenced by the annealing temperature and pH of the coating solution. Measurements of photoluminescence intensities displayed their dependency on the concentration of dopant in the resulting core/shell NPs.


2021 ◽  
Vol 56 (17) ◽  
pp. 10293-10311
Author(s):  
Wen Shao ◽  
Minmin Liu ◽  
Guoxiu Tong ◽  
Tong Wu ◽  
Tianxi Lv

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