scholarly journals The AC and DC Conductivity of Nanocomposites

2007 ◽  
Vol 2007 ◽  
pp. 1-9 ◽  
Author(s):  
David S. McLachlan ◽  
Godfrey Sauti

The microstructures of binary (conductor-insulator) composites, containing nanoparticles, will usually have one of two basic structures. The first is the matrix structure where the nanoparticles (granules) are embedded in and always coated by the matrix material and there are no particle-particle contacts. The AC and DC conductivity of this microstructure is usually described by the Maxwell-Wagner/Hashin-Shtrikman or Bricklayer model. The second is a percolation structure, which can be thought to be made up by randomly packing the two types of granules (not necessarily the same size) together. In percolation systems, there exits a critical volume fraction below which the electrical properties are dominated by the insulating component and above which the conducting component dominates. Such percolation systems are best analyzed using the two-exponent phenomenological percolation equation (TEPPE). This paper discusses all of the above and addresses the problem of how to distinguish among the microstructures using electrical measurements.

2000 ◽  
Vol 15 (11) ◽  
pp. 2368-2374 ◽  
Author(s):  
Dan Zabetakis

A method was presented for the formation and metallization of cylindrical tubules from a diacetylenic lipid. This improved technique allowed for the production of metal microcylinders without the need for preliminary lipid purification and in large quantities. The physical and electrical properties of the material were investigated, and composites were used to form parallel plate capacitors. A comparison of the conductivity of the bulk material with the derived conductivity of a composite showing electromagnetic percolation showed the proportionality of the specific packing density and the critical volume fraction characteristic of percolating systems.


2012 ◽  
Vol 457-458 ◽  
pp. 449-452
Author(s):  
Ming Lin Xu ◽  
Xiao Qing Wu ◽  
Ming Kang An

The tensile test of NOL ring composites with different interply hybrid ratio is simulated by finite element software. The relationship between the stress of Naval Ordnance Laboratory(NOL) ring and the volume fraction of UHMWPEF is linear when the matrix suffering from the equal loading, but tower suddenly appears at the point of 56.25% which is about the critical volume fraction. The critical volume fraction of hybrid NOL ring is figured out on the basis of the constant strain model. By contrast, the results of the Finite Element Method (FEM) and constant strain model have subtle differences. Tooth contact analysis can exactly predict the stress of the interply hybrid NOL ring and the critical volume fraction of GF in interply hybrid NOL ring which has lower breaking strain than UHMWPEF does.


1997 ◽  
Vol 12 (3) ◽  
pp. 738-744 ◽  
Author(s):  
J. F. Kelso ◽  
R. R. Higgins ◽  
F. J. Krivda

The microstructure of Mo in an alumina/frit matrix was found to be dependent on the initial particle sizes of the alumina and Mo powders, the glass content in the matrix ceramic, and the amount of moisture in the firing atmosphere. The Mo microstructure had a significant influence on the critical volume fraction for conductivity in these cermets. Coarser alumina powder, finer Mo powder, and higher glass content promoted coalescence of Mo into conductive networks at lower metal contents. Drier firing atmospheres produced a more coarsened Mo microstructure with a slight decrease in the amount of network contiguity, causing an increase in the amount required for electrical percolation.


2018 ◽  
Author(s):  
Arnab Chanda

Skin is the first point of contact of the human body with the outer environment, and influences the biomechanics of different organ systems in normal and diseased states. Wearable electronics such as fitness tracking equipment, motion sensing devices, and advanced wearables in prosthetics and orthotics are often used to quantify the interaction of the body with the environment during different physical activities, and improve health. These wearable equipment can be bulky and a source of discomfort to the human skin with prolonged wear. To date, very few flexible polymers have been developed which can conduct electricity and be used in wearable devices. In the current work, a novel conductive synthetic skin composite system was developed, which would be indispensable for integration into wearable technologies, and also allow the biomechanical testing of the human skin for different engineering and medical applications. The mechanical behavior of this polymer can be tuned to mimic the human skin from different locations of the body with varying stiffnesses, with a phenomenal degree of accuracy. The composite system is composed of short carbon fibers dispersed in a multi part silicone based matrix material. The volume fraction of the fibers were varied to control the mechanical and electrical properties of the composite. Uniaxial tensile tests were conducted to generate stress versus strain responses of the synthetic skin composites at different fiber volume fractions, and electrical measurements were recorded at different strains. Microscopy was used to understand composite fiber orientations in unstretched and stretched states, and its effects on the electrical conductivity of the material. Additionally, non-linear material characterization models were developed to characterize the composite variants. To the best of our knowledge, such an accurate synthetic skin composite system with tailorable electrical properties has not been developed; making this state of the art in bio mimicking and functionalization of the human skin.


Author(s):  
N. Y. Jin

Localised plastic deformation in Persistent Slip Bands(PSBs) is a characteristic feature of fatigue in many materials. The dislocation structure in the PSBs contains regularly spaced dislocation dipole walls occupying a volume fraction of around 10%. The remainder of the specimen, the inactive "matrix", contains dislocation veins at a volume fraction of 50% or more. Walls and veins are both separated by regions in which the dislocation density is lower by some orders of magnitude. Since the PSBs offer favorable sites for the initiation of fatigue cracks, the formation of the PSB wall structure is of great interest. Winter has proposed that PSBs form as the result of a transformation of the matrix structure to a regular wall structure, and that the instability occurs among the broad dipoles near the center of a vein rather than in the hard shell surounding the vein as argued by Kulmann-Wilsdorf.


2021 ◽  
pp. 002199832110112
Author(s):  
Qing Yang Steve Wu ◽  
Nan Zhang ◽  
Weng Heng Liew ◽  
Vincent Lim ◽  
Xiping Ni ◽  
...  

Propagation of ultrasonic wave in Carbon Fiber Reinforced Polymer (CFRP) is greatly influenced by the material’s matrix, resins and fiber volume ratio. Laser ultrasonic broadband spectral technique has been demonstrated for porosity and fiber volume ratio extraction on unidirection aligned CFRP laminates. Porosity in the matrix materials can be calculated by longitudinal wave attenuation and accurate fiber volume ratio can be derived by combined velocity through the high strength carbon fiber and the matrix material with further consideration of porosity effects. The results have been benchmarked by pulse-echo ultrasonic tests, gas pycnometer and thermal gravimetric analysis (TGA). The potentials and advantages of the laser ultrasonic technique as a non-destructive evaluation method for CFRP carbon fiber volume fraction evaluation were demonstrated.


1994 ◽  
Vol 116 (3) ◽  
pp. 359-366 ◽  
Author(s):  
S. C. Lin ◽  
Y. Hirose ◽  
T. Mura

Based upon the Mori-Tanaka method, the constitutive equations of power-law materials and the failure criteria of multiple cracks materials are investigated. The piecewise linear incremental approach is also employed to analyze the effective stress and strain of the power-law materials. Results are presented for the case of pure shear where the matrix is a power-law material with rigid or void inhomogeneities. For the multiple cracked materials, the Griffith fracture criterion is applied to determine the critical volume fraction which causes the catastrophic failure of a material. The failure criteria of penny shaped, flat ellipsoidal, and slit-like cracked materials are examined and it is found that the volume fraction of cracks and critical applied stress are in linear relation.


2021 ◽  
Author(s):  
Ramratan Guru ◽  
Anupam Kumar ◽  
Rohit Kumar

This research work has mainly utilized agricultural waste material to make a good-quality composite sheet product of the profitable, pollution free, economical better for farmer and industries. In this study, from corn leaf fibre to reinforced epoxy composite product has been utilized with minimum 35 to maximum range 55% but according to earlier studies, pulp composite material was used in minimum 10 to maximum 27%. Natural fibre-based composites are under intensive study due to their light weight, eco-friendly nature and unique properties. Due to the continuous supply, easy of handling, safety and biodegradability, natural fibre is considered as better alternative in replacing many structural and non-structural components. Corn leaf fibre pulp can be new source of raw material to the industries and can be potential replacement for the expensive and non-renewable synthetic fibre. Corn leaf fibre as the filler material and epoxy as the matrix material were used by changing reinforcement weight fraction. Composites were prepared using hand lay-up techniques by maintaining constant fibre and matrix volume fraction. The sample of the composites thus fabricated was subjected to tensile, impact test for finding the effect of corn husk in different concentrations.


1994 ◽  
Vol 3 (2) ◽  
pp. 096369359400300
Author(s):  
Lun X. He ◽  
David K. Hsu ◽  
John P. Basart

In continuous fiber reinforced metal matrix composites, the volume fraction of voids in the matrix material is an important parameter for material property characterization. In analyzing a cross-sectional micrograph of such a composite, the presence of fiber images and voids occurring on the perimeter of fibers complicates the determination of void content. This paper describes image processing steps using mathematical morphology for the extraction of void fraction in a composite.


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