Improvement in skin–core adhesion of multiwalled carbon nanotubes modified carbon fiber prepreg/Nomex honeycomb sandwich composites

2017 ◽  
Vol 36 (8) ◽  
pp. 608-618 ◽  
Author(s):  
Chao Chen ◽  
Yanxia Li ◽  
Yizhuo Gu ◽  
Min Li ◽  
Zuoguang Zhang
Keyword(s):  
Carbon Nanotubes ◽  
Carbon Fiber ◽  
Multiwalled Carbon Nanotubes ◽  
Peel Test ◽  
Sandwich Composites ◽  
Honeycomb Core ◽  
Multiwalled Carbon ◽  
Honeycomb Sandwich ◽  
The Matrix ◽  
Nomex Honeycomb

An experimental investigation on the sandwich composites composed of the carbon fiber face sheets and Nomex honeycomb core has been carried out in this study. Multiwalled carbon nanotubes were added into the matrix of prepreg for converting the traditional pure resin adhesive fillet to composites. Resin viscosity was measured to evaluate the effect of the additive amount of multiwalled carbon nanotubes on the rheological properties. The size of adhesive fillet was obtained from the optical microscopy to assess the forming quality. Climbing drum peel test and edgewise compression test were employed for the mechanical assessment. The results showed that the addition of multiwalled carbon nanotubes reinforcement to epoxy resin in the prepreg was very effective in improving the skin–core adhesion. The peel load and peel energy release rate as well as the edgewise compressive strength and edgewise compressive modulus of the sandwich composites varied with different magnitudes due to the additive amount of multiwalled carbon nanotubes. Reinforcing mechanism of the adhesive fillet with multiwalled carbon nanotubes reinforcement was discussed on the basis of the fractographic observations by scanning electron microscopy.

In-plane shear of nanoprepreg/nanostitched three-dimensional carbon/epoxy multiwalled carbon nanotubes composites

2019 ◽  
Vol 53 (24) ◽  
pp. 3413-3431 ◽  
Author(s):  
Kadir Bilisik ◽  
Nesrin Karaduman ◽  
Gulhan Erdogan ◽  
Erdal Sapanci ◽  
Sila Gungor
Keyword(s):  
Carbon Nanotubes ◽  
Multiwalled Carbon Nanotubes ◽  
Shear Fracture ◽  
Three Dimensional ◽  
Carbon Fabric ◽  
Multiwalled Carbon ◽  
Plane Shear ◽  
The Matrix ◽  
Delamination Area ◽  
Base Structure

The in-plane shear properties of nanostitched three-dimensional (3D) carbon/epoxy composites were investigated. Adding the stitching fiber or multiwalled carbon nanotubes or nanostitched fiber into carbon fabric preform slightly improved the shear strength and modulus of stitched and stitched nanocomposites. The in-plane shear fracture of the base and nanostructures was extensive delamination and tensile fiber failures in the sheared region. But, the stitched and stitched nanocomposites had angular deformation of the stitching yarns in the fiber scissoring areas, shear hackles in the matrix and successive fiber breakages in the interlayers. Probably, this mechanism prohibited extensive interlayer opening in the nanostitched composites. The results exhibited that introducing the stitching fiber (1.44%) and multiwalled carbon nanotubes (0.03125%) in the base structure enhanced its transverse fracture properties as a form of confined delamination area. Therefore, the damaged tolerance properties of the stitched nanocomposites were enhanced.

scholarly journals Experimental analysis of composite scarf adhesive joints modified with multiwalled carbon nanotubes under bending and thermomechanical impact loads

2019 ◽  
Vol 234 (1) ◽  
pp. 48-64 ◽  
Author(s):  
UA Khashaba ◽  
Ramzi Othman ◽  
IMR Najjar
Keyword(s):  
Carbon Nanotubes ◽  
Carbon Fiber ◽  
Multiwalled Carbon Nanotubes ◽  
Adhesive Joints ◽  
Impact Loads ◽  
Fiber Reinforced ◽  
Multiwalled Carbon ◽  
Impact Tests ◽  
Carbon Fiber Reinforced ◽  
The Impact

Scarf adhesive joints have attracted an increasing attention in joining/repairing of carbon fiber reinforced epoxy composite structures due to their zero eccentricity, which provides lower stress distribution across the adhesive layer and better aerodynamic surfaces compared to other bonded joints. The main objective of this study is to evaluate the performance of the scarf adhesive joints in carbon fiber reinforced epoxy composites under thermomechanical impact loads, which is very important for the aerospace and automotive industries. The adhesive was modified with optimum percentage of multiwalled carbon nanotubes. The impact tests were performed at 25 ℃, 50 ℃, and 75 ℃. The residual flexural properties of the unfailed impacted joints were measured using three-point bending test. Results from impact tests at 25 ℃, 50 ℃, and 75 ℃ showed improvement in the impact bending stiffness of the modified scarf adhesive joints by 8.3%, 7.4%, and 11.8% and maximum contact force by 15.6%, 21.3%, and 18.9%, respectively. The energy at failure of the modified scarf adhesive joints with multiwalled carbon nanotubes was improved by 15.2% and 16.4% respectively at 25 ℃ and 50 ℃. At test temperature of 75 ℃, the scarf adhesive joints have hysteresis load–displacement behavior and energy–time curve with rebound energy of 35% and absorbed (damage) energy of 65%. The residual flexural strength of the modified and unmodified scarf adhesive joints is 98.2% and 86.1% respectively, while their residual moduli have remarkable decrease to 71.7% and 81.3%.

scholarly journals Effect of Increasing the Strength of Aluminum Matrix Nanocomposites Reinforced with Microadditions of Multiwalled Carbon Nanotubes Coated with TiC Nanoparticles

Nanomaterials ◽  
2019 ◽  
Vol 9 (11) ◽  
pp. 1596 ◽  
Author(s):  
Artemiy Aborkin ◽  
Kirill Khorkov ◽  
Evgeny Prusov ◽  
Anatoly Ob’edkov ◽  
Kirill Kremlev ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Carbon Nanotubes ◽  
Multiwalled Carbon Nanotubes ◽  
Aluminum Matrix ◽  
High Energy ◽  
High Tech ◽  
Multiwalled Carbon ◽  
The Matrix ◽  
Tic Nanoparticles ◽  
Matrix Nanocomposites

Aluminum matrix composites reinforced with multiwalled carbon nanotubes (MWCNTs) are promising materials for applications in various high-tech industries. Control over the processes of interfacial interaction in Al/MWCNT composites is important to achieve a high level of mechanical properties. The present study describes the effects of coating MWCNTs with titanium carbide nanoparticles on the formation of mechanical properties and the evolution of the reinforcement structure in bulk aluminum matrix nanocomposites with low concentrations of MWCNTs under conditions of solid-phase consolidation of ball-milled powder mixtures. Using high-energy ball milling and uniaxial hot pressing, two types of bulk nanocomposites based on aluminum alloy AA5049 that were reinforced with microadditions of MWCNTs and MWCNTs coated with TiC nanoparticles were successfully produced. The microstructural and mechanical properties of the Al/MWCNT composites were investigated. The results showed that, on the one hand, the TiC nanoparticles on the surface of the MWCNT hybrid reinforcement reduced the damage of reinforcement under the intense exposure of milling bodies, and on the other hand, they reduced the contact area of the MWCNTs with the matrix material (acting as a barrier interface), which also locally inhibited the reaction between the matrix and the MWCNTs.

Experimental Investigation of the Machinability of Polycarbonate Reinforced With Multiwalled Carbon Nanotubes

2005 ◽  
Vol 128 (2) ◽  
pp. 465-473 ◽  
Author(s):  
J. Samuel ◽  
R. E. DeVor ◽  
S. G. Kapoor ◽  
K. J. Hsia
Keyword(s):  
Carbon Nanotubes ◽  
Carbon Fiber ◽  
Multiwalled Carbon Nanotubes ◽  
Cutting Forces ◽  
Fiber Composite ◽  
Chip Morphology ◽  
Surface Characteristics ◽  
Carbon Fiber Composite ◽  
Multiwalled Carbon ◽  
Machined Surface

The machinability of a polycarbonate nanocomposite containing multiwalled carbon nanotubes is investigated and contrasted with its base polymer and with a conventional carbon fiber composite. The material microstructures are characterized using transmission electron and scanning electron microscopy methods. Micro-endmilling experiments are conducted on the three materials. Chip morphology, machined surface characteristics, and the nature of the cutting forces are employed as machinability measures for comparative purposes. Polycarbonate chips are seen to transition from being discontinuous to continuous as the feed-per-tooth (FPT) increases, while, at all FPT values the nanocomposite is seen to form comparatively thicker continuous chips. The nanocomposite and the carbon fiber composite are seen to have the lowest and the highest magnitudes, respectively, for both the surface roughness and cutting forces. Shearing along the nanotube-polymer interface and better thermal conductivity are speculated to be the mechanisms responsible for the observations seen in the nanocomposite.

scholarly journals Thermal Conductivity of Carbon Nanoreinforced Epoxy Composites

2016 ◽  
Vol 2016 ◽  
pp. 1-12 ◽  
Author(s):  
C. Kostagiannakopoulou ◽  
E. Fiamegkou ◽  
G. Sotiriadis ◽  
V. Kostopoulos
Keyword(s):  
Thermal Conductivity ◽  
Carbon Nanotubes ◽  
Carbon Fiber ◽  
Multiwalled Carbon Nanotubes ◽  
Epoxy Matrix ◽  
Epoxy Composites ◽  
Graphite Nanoplatelets ◽  
Multiwalled Carbon ◽  
Micromechanical Models ◽  
Carbon Fiber Epoxy

The present study attempts to investigate the influence of multiwalled carbon nanotubes (MWCNTs) and graphite nanoplatelets (GNPs) on thermal conductivity (TC) of nanoreinforced polymers and nanomodified carbon fiber epoxy composites (CFRPs). Loading levels from 1 to 3% wt. of MWCNTs and from 1 to 15% wt. of GNPs were used. The results indicate that TC of nanofilled epoxy composites increased with the increase of GNP content. Quantitatively, 176% and 48% increase of TC were achieved in nanoreinforced polymers and nanomodified CFRPs, respectively, with the addition of 15% wt. GNPs into the epoxy matrix. Finally, micromechanical models were applied in order to predict analytically the TC of polymers and CFRPs. Lewis-Nielsen model with optimized parameters provides results very close to the experimental ones in the case of polymers. As far as the composites are concerned, the Hashin and Clayton models proved to be sufficiently accurate for the prediction at lower filler contents.

Preparation and Characterization of Multiwalled Carbon Nanotubes-Reinforced pCBT by Ring-Opening Polymerization of Cyclic Butylene Terephthalate

2016 ◽  
Vol 848 ◽  
pp. 125-131
Author(s):  
Yin He Su ◽  
Jun Rong Yu
Keyword(s):  
Carbon Nanotubes ◽  
Multiwalled Carbon Nanotubes ◽  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Scanning Calorimetry ◽  
Multiwalled Carbon ◽  
Butylene Terephthalate ◽  
Cyclic Butylene Terephthalate ◽  
The Matrix ◽  
Higher Temperature

Multiwalled carbon nanotubes (MWCNT)-reinforced polymerized cyclic butylene terephthalate (pCBT) nanocomposites were prepared by in situ ring opening polymerization of cyclic butylene terephthalate oligomers (CBT). The results of differential scanning calorimetry (DSC) indicated that the melting peak located at the low temperature (Tm1) increased and that at higher temperature (Tm2) decreased with the increasing of content of the MWCNT. During the cooling the MWCNT served as nucleation points from where crystallization can start. The more the MWCNT in the system the earlier the crystallization starts. The Morphological investigations performed by scanning electron microscopy (SEM) shown that the MWCNT were embedded in the matrix and held tightly by the matrix. The modulus and strength increased with MWCNT concentration in the nanocomposites, however, the elongation at break, absorbed energy at break and impact strength were decreased with the increasing of MWCNT content.

scholarly journals CVD Synthesis of Hierarchical 3D MWCNT/Carbon-Fiber Nanostructures

2008 ◽  
Vol 2008 ◽  
pp. 1-7 ◽  
Author(s):  
Toma Susi ◽  
Albert G. Nasibulin ◽  
Hua Jiang ◽  
Esko I. Kauppinen
Keyword(s):  
Electron Microscopy ◽  
Carbon Nanotubes ◽  
Carbon Fiber ◽  
Multiwalled Carbon Nanotubes ◽  
Carbon Fibers ◽  
Gas Flow ◽  
Carbon Precursor ◽  
Optimal Temperature ◽  
Multiwalled Carbon ◽  
Cvd Synthesis

Multiwalled carbon nanotubes (MWCNTs) were synthesized by CVD on industrially manufactured highly crystalline vapor-grown carbon fibers (VGCFs). Two catalyst metals (Ni and Fe) and carbon precursor gases (C2H2and CO) were studied. The catalysts were deposited on the fibers by sputtering and experiments carried out in two different reactors. Samples were characterized by electron microscopy (SEM and TEM). Iron was completely inactive as catalyst with bothC2H2and CO for reasons discussed in the paper. The combination of Ni andC2H2was very active for secondary CNT synthesis, without any pretreatment of the fibers. The optimal temperature for CNT synthesis was750∘C, with total gas flow of 650 cm3min⁡−1ofC2H2,H2, and Ar in 1.0:6.7:30 ratio.

Tribological, Mechanical, and Microstructural of Multiwalled Carbon Nanotubes/Short Carbon Fiber Epoxy Composites

2017 ◽  
Vol 140 (2) ◽  
Author(s):  
O. J. Gbadeyan ◽  
Krishnan Kanny ◽  
Mohan Turup Pandurangan
Keyword(s):  
Carbon Nanotubes ◽  
Carbon Fiber ◽  
Wear Rate ◽  
Multiwalled Carbon Nanotubes ◽  
High Heat ◽  
Structural Development ◽  
Multiwalled Carbon ◽  
Short Carbon Fiber ◽  
Uniform Dispersion ◽  
Short Carbon

In the present work, composites were developed with novel combination of particular fillers and fibers for an automotive brake system. The influence of short carbon fiber (SCF) on wear rate, coefficient of friction (CoF), modulus, compressive strength, hardness, and surface morphology of worn surface were examined. This investigation confirmed that 0.1% multiwalled carbon nanotubes (MWCNTs) reduced wear rate, CoF for all combinations of composite with carbon fiber. Results indicate that 0.1% (MWCNTs) and 10% SCF-filled composite had superior properties. This performance may be attributed to the uniform dispersion of fiber and the synergistic effect of SCF and MWCNTs, acting in concert that formed a more stable structure resulting in a high strength, stiffness, tougher, and high-heat absorption. Scanning electron microscopy (SEM) microstructure subsequently performed show change in structural development with a corresponding increase of the incorporation of SCF and MWCNTs, which eventually explained the improved properties of composite.

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