Linking the redox cycles of Fe oxides and Fe-rich clay minerals: an example from a palaeosol of the Upper Freshwater Molasse

Clay Minerals ◽  
2008 ◽  
Vol 43 (1) ◽  
pp. 69-82 ◽  
Author(s):  
H. Stanjek ◽  
C. Marchel
Keyword(s):  
Particle Size ◽  
Clay Minerals ◽  
Soil Formation ◽  
Mineralogical Composition ◽  
Rietveld Analysis ◽  
Fe Oxides ◽  
Redox Cycles ◽  
Upper Freshwater Molasse ◽  
Fine Clay ◽  
Dioctahedral Smectite

AbstractA profile within the Upper Freshwater Molasse (OSM) of eastern Switzerland was sampled. Particle-size analyses, bulk chemical analyses, cation exchange capacities and Fe fractions (oxalate- and dithionite-citrate-bicarbonate-soluble Fe, total Fe) were measured. The mineralogical composition was determined by X-ray diffraction and quantified with Rietveld analysis. The layer charge of selected fine-clay samples was determined with the alkylammonium method using chainnc= 12. The profile could be divided into a lower sequence (I) and an upper sequence (II) by a hiatus. Chemical data, particle-size distributions and calcite contents indicated that soil formation was essentially restricted to wetting-drying cycles associated with redox cycles evident from Feo/Fedand Fed/Fetratios. A significant correlation between thed060values of the dioctahedral smectite-illite mixed-layer phases and Feo/Fedwas interpreted as the influence of microbial Fe3+reduction, which affected both the Fe oxides and Fe-rich clay minerals. This is the first evidence that the Fe dynamics of both mineral groups may be linked. The amount of illitization also correlated with Feo/Fed, but only in the upper part of the profile. This indicates that wetting-drying cycles were necessary for the illitization process.

Particle Size Effects on Concentration of Metals in Lake Erie Bottom Sediments

1984 ◽  
Vol 19 (1) ◽  
pp. 27-36 ◽  
Author(s):  
Alena Mudroch
Keyword(s):  
Particle Size ◽  
Organic Matter ◽  
Clay Minerals ◽  
Surface Sediment ◽  
Size Effects ◽  
Lake Erie ◽  
Size Fraction ◽  
Mineralogical Composition ◽  
Major Elements ◽  
Sediment Samples

Abstract Surface sediment samples obtained at the offshore and nearshore area of Lake Erie were separated into eight different size fractions ranging from <2 µm to 250 µm. The concentration of major elements (Si, Al, Ca, Mg, K, Na, Fe, Mn and P), metals (Zn, Cu, Cr, Ni, V, Co and Pb) and organic matter was determined together with the mineralogical composition and morphology of the particles in each size fraction. The distribution of the metals in the offshore sediment was bimodal with the majority of the metals divided between the 63 to 250 um size fraction which also contained the highest concentration of organic matter (about 20%) and the <4 µm fraction containing up to 60% of clay minerals. However, the metals in the nearshore sediment were associated mainly with the clay minerals.

A Simple Dissolved Metals Mixing Route to Prepare Nanostructured Mg0.8Zn0.2TiO3 Solid Solution

2015 ◽  
Vol 1112 ◽  
pp. 47-52 ◽  
Author(s):  
Frida Ulfah Ermawati ◽  
Suasmoro Suasmoro ◽  
Suminar Pratapa
Keyword(s):  
Solid Solution ◽  
Particle Size ◽  
Rietveld Analysis ◽  
Dissolved Metals ◽  
Intermediate Phases ◽  
Particle Size Analyzer ◽  
Ft Ir ◽  
Xrd Patterns ◽  
Zn Ions

A study of liquid mixing route to synthesize high purity Mg0.8Zn0.2TiO3 nanopowder, a candidate dielectric ceramics, has been successfully performed. Formation of the phases on the dried powder was studied using TG/DTA, XRD and FT-IR data. Rietveld analysis on the collected XRD patterns confirmed the formation of solid solution in the system. Such solid solution can be obtained from the powder calcined at 500 °C, but calcination at 550 °C gave rise to the most optimum molar purity up to 98.5% without intermediate phases. The role of Zn ions on the formation of solid solution was also discussed. Homogeneity of particle size distribution and nano-crystallinity of the system was verified from the particle size analyzer data, TEM image and the Rietveld analysis output.

scholarly journals Study of clay minerals effect on curing characteristics of polymer blends and physical-mechanical properties of prepared vulcanizates

2018 ◽  
Vol 157 ◽  
pp. 07010
Author(s):  
Beáta Pecušová ◽  
Mariana Pajtášová ◽  
Zuzana Mičicová ◽  
Darina Ondrušová ◽  
Andrea Feriancová ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Polymer Blends ◽  
Clay Minerals ◽  
Structural Type ◽  
Partial Replacement ◽  
Curing Characteristics ◽  
Dioctahedral Smectite ◽  
The Common ◽  
The Given

The given paper deals with the study of the properties of clay minerals, namely montmorillonite and moreover, it is focused on effect of these clay minerals on the curing characteristics of the polymer blends and the physical-mechanical properties of prepared vulcanizates. Montmorillonite is a major clay mineral which has a wide application in many industrial branches. It belongs to the group of dioctahedral smectite minerals with structural type in the ratio of 2:1. Characteristics of prepared modified and organomodified clay minerals are based on sulphur vulcanisation accelerators which are used for the preparation of real polymer blend where they represent a partial replacement of the common carbon black filler and then, the effect on the curing characteristics of polymer blends as well as physical-mechanical properties of the prepared vulcanizates are investigated. The results exhibit that the clay-based filler (modified and organomodified clay minerals) can be used as a partial replacement while the quality of the prepared blends is preserved.

scholarly journals The Mineralogical Composition of Samos Zeoliitic Rocks and their potential use as Feed Additives and Nutrition Supplements

2020 ◽  
Vol 56 (1) ◽  
pp. 84
Author(s):  
Anestis Filippidis ◽  
Christina Mytiglaki ◽  
Nikolaos Kantiranis ◽  
Ananias Tsirambides
Keyword(s):  
Clay Minerals ◽  
Animal Species ◽  
Mineralogical Composition ◽  
Feed Additives ◽  
Feed Additive ◽  
X Ray Diffraction ◽  
Eu Regulation ◽  
Fibrous Minerals ◽  
Potential Use ◽  
The Eu

Fifteen (15) zeolitic rocks from Karlovassi-Marathokampos basin of Samos Island (Greece) were investigated for their mineralogical composition by X-Ray Diffraction (XRD) method. According to EU Regulation No 651/2013, clinoptilolite of sedimentary origin with ≥80 wt% clinoptilolite, ≤20 wt% clay minerals, free of fibres and quartz, can be used as feed additive for all animal species. Depending on the zeolites, the zeolitic rocks are grouped to those containing: Clinoptilolite (33-86 wt%), clinoptilolite (59 wt%) + mordenite (20-21 wt%), clinoptilolite (22 wt%) + analcime (29 wt%), clinoptilolite (17 wt%) + phillipsite (27 wt%), analcime (29-70 wt%), mordenite (62%) and chabazite (63 wt%). None of the clinoptilolite-containing rocks (10 samples) meet the requirements of the EU Regulation No 651/2013, and thus cannot be used as feed additives for all animal species and consequently as nutrition supplements, since all of them contain 2-5 wt% quartz, two of them 20-21 wt% mordenite (fibrous zeolite), nine of them <80 wt% clinoptilolite (17-73 wt%) and two of them >20 wt% clay minerals (27-42 wt%). Although the EU Regulation No 651/2013 refers to clinoptilolite of sedimentary origin, using the presence or absence of quartz and fibrous minerals, none of the five mordenite, analcime and chabazite containing zeolitic rocks, can be used as feed additives and nutrition supplements, since all of them contain 2-6 wt% quartz and one of them contains 62 wt% mordenite (fibrous zeolite).

scholarly journals Clay Minerals Variations in Quaternary Sediments of Basrah City-Iraq

2017 ◽  
Vol 6 (2) ◽  
pp. 41
Author(s):  
Mohanad Hamid Al-Jaberi
Keyword(s):  
Clay Minerals ◽  
Mineralogical Composition ◽  
Silty Sand ◽  
Recent Sediment ◽  
Quaternary Sediments ◽  
Marine Transgression ◽  
Fine Grain ◽  
Clayey Silt ◽  
Marine Facies ◽  
Mixed Layers

Mineralogical and chemical analysis of two well cutting in quaternary sediments at Basrah city. This study have been focused on the quaternary clay minerals variations which give a clear indication to marine transgression and or / regression in Hammar formation. Kaolinite, Illite, Palygoreskite, Illite-Palygorestike mixed layer, Chlorite, Montmorillonite, Vermiculte, and mixed layers of Illite- Smectite are the most quantitatively important phyllosilicates in soil studies in both boreholes. The mineralogical composition of cutting sediments shows significant variability in the different size fractions and depth distribution. Chlorite and kaolinite minerals were increase in the fine grain size especially in the clayey silt, whereas montmoriolllinite and vermiculite minerals were increase in coarse grains especially in silty sand texture. Kaolinite decrease in abundance with depth, which give indicative of a transition from non-marine in quaternary recent sediment ( fresh or brackish water silt) to marine facies in quaternary Hammar formation ( marine shelly silt) during last transgression of quaternary. Palygoreskite mineral percentages increasing at depths 27 and 28 meter , after decreased at 30, 32, 35 , and 40 m respectively , which give data indication that early quaternary marine transgression happened in 32m , and center of quaternary marine transgression detected in 27 and 28 meters , while late marine transgression detected in 17 m , and all of these represent by Hammar formation. Soil ageing also caused to downward increase of montmorillonite suggest to climate became more arid during the early quaternary. Variations ratio of montmorillonite versus kaolinite can be indicated to climatic fluctuation. Illite-Semectite featured indicates changes in both sediment source and paleoclimate. Illite transformation for Illite-Palygoreskite mixed layers with ageing. Vermiculite has strong susceptibility to increase with age. SiO₂, Al₂O₃, CaO, MgO, K₂O, and Fe₂O₃ were the major oxides that identified in present study and used as indicated of clay minerals in studied sediments.

scholarly journals Chemical and mineralogical composition of clay fraction found in Podillia upland haplic chernozems

2017 ◽  
pp. 278-292
Author(s):  
Igor Papish ◽  
Oleksii Telehuz
Keyword(s):  
Clay Fraction ◽  
Soil Formation ◽  
Mineralogical Composition ◽  
Development Stage ◽  
Potassium Feldspar ◽  
Forest Steppe ◽  
Molar Ratios ◽  
Haplic Chernozems ◽  
Typical Chernozems ◽  
Chemical And Mineralogical Composition

The article presents data on gross chemical and mineralogical composition of clay faction found in typical chernozems occurred within the Podillia Upland. Geographical regularities of formation as regards clayey profile of Chernozems pertaining to the same genetic series are revealed. The relationship between conditions and Chernozem development stage, character of vertical differentiation of basic mineral phases of clayey plasma and its chemical and mineralogical composition are shown. Izoclayey profile of hydromicas is the consequence of their relative accumulation as a result eluviation of colloid-dispersible mica-smectite minerals. The character of clay profile observed in Chernozems is determined by the correlation of intensity of carbonates leaching, lessivage and soils argillisation. Typical Podolian Chernozems are characterised with the like weathering crust of silicate type. The modern Chernozem clayey profile originated mainly during a wetter stage of soil formation. In the ploughable layer a high content of clastic minerals (quartz, potassium feldspar, sodium plagioclase) is observed. Random mixed and stratified mica-smectite minerals with a high content (>50 %) of smectite packets (33–63 %), hydromica (33–52 %), and kaolinite plus chlorite (4–15 %) are present in the profile. The mineralogical composition of soils clay fraction indicates obvious signs of smectite eluviation and relative illite accumulation. Clayey profile of the Bug upstream plateau located within the Podillia Upland is atypical for Chernozems found in the eastern forest-steppe and steppe areas. The distribution character of layered silicates, especially smectite, is even more contrastive. Clayey plasma redistributes differentially through leaching and lessivage processes. Accumulative type of sludge deposits formed in Chernozems of the Dniester plateau located within the Podillia Upland, even profile distribution of basic oxides and molar ratios of SiO2 : Al2O3 and SiO2 : Fe2O3 against the background of decreased downward smectite content indicate weakened eluviation of fine-grained clays towards the Dniester. The prevalence of smectite over hydromicas within the entire profile indicates argillisation of Chernozems. Key words: Chernozem, chemical-mineralogical composition, clayey minerals, hydromica, smectite, kaolinite, leaching, lessivage, argillisation.

A SUB-TILL SAPROLITE AND THE OVERLYING SOIL PROFILE NEAR MOUNT ORFORD, SOUTHERN QUEBEC

1984 ◽  
Vol 64 (4) ◽  
pp. 577-585 ◽  
Author(s):  
C. R. DE KIMPE ◽  
M. R. LAVERDIÈRE ◽  
P. LASALLE
Keyword(s):  
Key Words ◽  
Clay Minerals ◽  
Soil Profile ◽  
Mineralogical Composition ◽  
Magnetic Mineral ◽  
Mineral Assemblages ◽  
Extractable Al

A saprolite deposit and the overlying soil profile developed in a glacial diamicton were sampled near Mount Orford, Southern Quebec. The two materials differed mainly by the magnetic mineral and extractable Al contents, by the Fedithionite/Feoxalate ratio and by the mineralogical composition. Illite and chlorite were the dominant clay minerals in the till whereas muscovite and kaolinite were the major minerals in the saprolite. A comparison was also made with another previously described saprolite deposit 4 km away from this one, in which chlorite was slightly transformed to smectite. It is suggested, from the mineral assemblages, that the two saprolites have probably formed at different times, the first one during Tertiary and the second one during an interglacial stage. Key words: Saprolite, glacial diamicton, kaolinite, muscovite, Tertiary alteration

Clay mineral-grain size-calcite cement relationships in the Upper Cretaceous Chalk, UK: a preliminary investigation

Clay Minerals ◽  
2014 ◽  
Vol 49 (2) ◽  
pp. 299-325 ◽  
Author(s):  
C. V. Jeans ◽  
N. J . Tosca ◽  
X. F. Hu ◽  
S. Boreham
Keyword(s):  
Particle Size ◽  
Particle Size Distribution ◽  
Trace Element ◽  
Size Distribution ◽  
Clay Mineral ◽  
Preliminary Investigation ◽  
Clay Mineralogy ◽  
Minor Amount ◽  
Dioctahedral Smectite ◽  
Calcite Cement

AbstractThe idea is tested that the evolution of the Chalk’s clay mineral assemblage during diagenesis can be deduced by examining the relationships between its clay mineralogy, particle size distribution pattern, and the timing and trace element chemistry of the calcite cement. The preliminary results from five different examples of cementation developed at different stages of diagenesis in chalks with smectite-dominated clay assemblages suggest that this is a promising line of investigation. Soft chalks with minor amount of anoxic series calcite cement poor in Mg, Fe and Mn are associated with neoformed trioctahedral smectite and/or dioctahedral nontronite and talc. Hard ground chalk with extensive anoxic series calcite cement enriched in Mg and relatively high Fe, Mn and Sr are associated with neoformed glauconite sensu lato, berthierine and dioctahedral smectite, possibly enriched in Fe. The chalk associated with large ammonites shows extensive suboxic series calcite cement enriched in Mg, Mn and Fe that show no obvious correlation with its clay mineralogy. Nodular chalks with patchy suboxic series calcite cement enriched in Fe are associated with neoformed dioctahedral smectite, possibly enriched in Al, and berthierine. Regionally hardened chalk with extensive suboxic calcite cement and relatively high trace element contents contain pressure dissolution seams enriched in kaolin and berthierine. Laser-based particle-size distribution patterns suggest that each type of lithification has a typical complex clay mineral population, indicating that subtleties in mineralogy are not being identified and that there could be some control on the size and shape of the clay crystals by the different types of cementation.

scholarly journals The Occurrence of Authigenic Clay Minerals in Alkaline-Saline Lakes, Pantanal Wetland (Nhecolândia Region, Brazil)

Minerals ◽  
2020 ◽  
Vol 10 (8) ◽  
pp. 718
Author(s):  
Isis Armstrong Dias ◽  
Leonardo Fadel Cury ◽  
Bruno Guimarães Titon ◽  
Gustavo Barbosa Athayde ◽  
Guilherme Fedalto ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Clay Minerals ◽  
Saline Lakes ◽  
Clay Fraction ◽  
Water Bodies ◽  
X Ray Diffraction ◽  
X Ray ◽  
Transmission Electron ◽  
Fine Clay ◽  
Pantanal Wetland

Mg clay minerals are usually associated with carbonates in alkaline-saline environments, precipitated from solution and/or transformation from other minerals. The aim of this research is to identify the mineralogy and geochemistry of clay minerals in different alkaline lakes in the Nhecolândia region, the southernmost region of the Pantanal wetland (Brazil). Sediment samples were analyzed by X-ray diffraction, X-ray fluorescence, scanning electron microscopy and transmission electron microscopy. Water samples were analyzed, determining their main cations and anions, in order to understand their relationship with the clays. The analyses allowed classifying the water bodies as saline, oligosaline and freshwater lakes. The sediments are composed mainly of quartz and a fine-clay fraction, dominated by illite, kaolinite and smectite. The XRD results showed illite and smectite mixed-layered in the saline lakes at Barranco Alto farm, whereas at Nhumirim farm, trioctahedral smectite was only observed in one lake. The smectite minerals were normally identified coupled with calcite at the top of the sequences, associated with exopolymeric substances (EPS) in the lakes, suggesting that these minerals are precipitating due to the physical-chemical and biological conditions of the water bodies.

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