Russellite, a new British mineral

Author(s):  
Max H. Hey ◽  
F. A. Bannister ◽  
Arthur Russell

In May, 1936, a quantity of pale yellow, rounded fragments, averaging 7 mm. across, was submitted to us by Mr. Arthur Russell for examination, with the information that the material came from the Castle-an-Dinas wolfram mine, and contained bismuth and tungsten. Chemical and spectroscopic examination showed that, besides bismuth and tungsten, the mineral contained only traces of silicon, arsenic, and iron. A sample of the same material had also been given to the British Museum by Mr. E. H. Davison in 1934 and registered provisionally as bismuth tungstate. This, however, would not have provided sufficient of the yellow mineral for chemical analysis. We are also indebted to Mr. Davison for a further generous supply of yellow pellets picked from the wolfram concentrates received since tile present work was begun. The mineral has all the attributes of an alteration product probably of native bismuth. It is fine-grained and compact, with hardness 3½, and on fracture it gives a clay-like odour. Some of the pellets show traces of a micaeeous mineral and quite frequently enclose native bismuth, wolframite, and bismuthinite. Mr. Russell has picked out from tihe material he had collected a few green pellets and some showing both the yellow and the green mineral. Spectrographs of the two are identical, but an X-ray powder photograph of the green mineral is quite distinct from that of tile yellow mineral.

1996 ◽  
Vol 60 (399) ◽  
pp. 317-324 ◽  
Author(s):  
R. A. Ixer ◽  
B. Young ◽  
C. J. Stanley

AbstractBismuthinite-bearing quartz veins from the Alston Block of the North Pennine Orefield are all close to, or above, the Rookhope and Tynehead cupolas of the buried Weardale Granite. They are uniform in composition and paragenesis and are earlier than the main fluorite-baryte-galena-sphalerite mineralization of the orefield. Rhythmical crystallization of quartz, chalcopyrite and minor pyrite is followed by fluorite-quartz-chalcopyrite-minor sphalerite-altered pyrrhotite mineralization. Early tin-bearing (up to 0.29 wt.% Sn) chalcopyrite encloses trace amounts of bismuthinite (Bi2S3), synchysite (CaREE(CO3)F2), argentopentlandite (Ag(FeNi)8S8) (close to being stoichiometric), pyrrhotite, cubanite and cosalite (Pb2Bi2S5), while early pyrite carries monoclinic pyrrhotite (close to Fe7S8) and tungsten-bearing cassiterite (up to 1.03 wt.% WO3). Bismuthinite is macroscopically visible and is associated with native bismuth and small, fine-grained, spherical aggregates that qualitative analysis suggests may be cosalite crystals. Synchysite and more rarely monazite, xenotime and adularia are intergrown with bismuthinite. These mineralogical data form part of the basis for an increasing awareness of the contribution of the Weardale Granite to the early phases of mineralization in the Alston Block.


Author(s):  
W. J. Duffin ◽  
J. Goodyear

SummaryScarbroite, a fine-grained but compact deposit obtained from fissures in the sandstone on the north Yorkshire coast, is shown by chemical analysis to have an idealized formula Al2(CO3)3·12Al(OH)3. X-ray and electron diffraction data indicate a triclinic cell with a 9·94 Å., b 14·88 Å., c 26·47 Å., α 98·7°, β 96·5°, and γ 89·0°. A layer structure consisting of gibbsite-type sheets of Al(OH)3 and sheets of Al2(CO3)3 is proposed. The structure is stable from room temperature to about 125° C.


Author(s):  
F. A. Bannister

It has recently been shown by W. Nieuwenkamp that matlockite is identical in chemical composition and crystal-structure with artificial lead fluochloride PbFC1. His conclusion is based upon powder photographs of the two substances and a fluorine determination of a specimen of matlockite from Matlock, Derbyshire. The present work was undertaken primarily to check Nieuwenkamp's interesting results. Access to an exceptionally fine suite of matlockite specimens in the British Museum collection made possible single crystal X-ray measurements, accurate optical determinations, and a new chemical analysis.


1894 ◽  
Vol 55 (331-335) ◽  
pp. 142-146

As the preliminary investigation of the Makariwa stone had already indicated to Professor Ulrich the presence of mineral constituents having the physical characters of olivine, enstatite, glass, a substance resembling glass, nickel-iron, troilite, magnetite, hydrous oxide of iron, and possibly chromite, the quantitative chemical analysis presented difficulties, among which may be specially mentioned the fact that one chemical element (iron) enters into the composition of each of the above fine-grained and closely intermingled constituents. This chemical examination I was invited to undertake by Professor J. W. Judd, F. R. S., through whom-the two fragments of the stone sent to this country by Professor Ulrich have been generously presented to the British Museum.


Author(s):  
A. F. Hallimond

There is a close optical and chemical resemblance between chamosite, the chloritic mineral of the bedded ironstones, and daphnite, a low-temperature vein-chlorite common in some of the Cornish tin mines. New material has made it possible to undertake a fresh comparison of the two minerals: chemical analyses have been made by Mr. C. O. Harvey, chemist to H.M. Geological Survey, and a report on the X-ray measurements is contributed by Mr. F. A. Bannister, of the Mineral Department of the British Museum.The new analysis of chamosite agrees with the simple formula previously assigned: X-ray examination of material from several localities has now established the distinctive crystalline nature of this fine-grained mineral, which differs structurally from ordinary chlorites such as clinochlore. Daphnite, on the other hand, has the ordinary chlorite structure, but the new analysis fully confirms Tschermak's original opinion that it cannot be represented chemically as a mixture of serpentine and amesite.


Author(s):  
F. A. Bannister ◽  
J. E. T. Horne

Early in 1947 a black, opaque, radioactive mineral resembling samarskite in appearance was discovered at Mavnzi in the Tete distrier of Mozambique, Portuguese East Africa. Two small specimens, one a rough twinned crystal with trigonal symmetry (fig. 3), were sent by h. M. Macgregor; then Director of the Geological Survey of Southern Rhodesia, to the British Museum (Natural History) for investigation, and a chemical analysis by E. Golding (table I, no. 2) followed later in the same year. X-ray photographs of fragments and powder from both specimens were taken, but revealed on development no diffraction spots, lines, or haloes. Only after prolonged heat-treatment could powder lines characteristic of crystalline material be obtained. The metamict nature of the mineral before heat-treatment is not unexpected in view of its chemical composition, optical isotropy, and glassy fracture.


Author(s):  
A. L. Mackay

Alamosite was first described by Palachc and Merwin, i who thought it might be isomorphous with wollastolfite. For that reason it has been re-examined, using X-ray methods.A specimen from the original locality at Alamos, Sonora, Mexico (B.M. 1910,330) was made available through the courtesy of the British Museum (Natural History), and in physical appearance it tallied with the original description. The crystals were aggregates of fibres arranged in bundles which cleaved perfectly perpendicular to the fibre axes. Small tablets could be readily cut out for X-ray analysis. The refractive indices were very high and the dispersion was large. As the axial ratios found by X-ray methods agreed with those given by Palache and Merwin, the latter's chemical analysis and density determination were not repeated.


1973 ◽  
Vol 28 (1-2) ◽  
pp. 46-55 ◽  
Author(s):  
F. A. Schröder ◽  
J. Scherle

The direct reaction of MoO3 and WO3 with ethylenglycol and glycerol is reported. The prepared compounds were characterized by chemical analysis, IR-spectra and X-ray diffraction methods (powder and single cystal). Some chemical properties are given. All results indicate that the new compounds are derivatives of the hitherto unknown ortho-molybdic (VI) and tungstic (VI)-acids.


Author(s):  
A. V. Vershinin ◽  
M. V. Vershinina ◽  
E. G. Belyakova ◽  
E. V. Polyakov ◽  
V. G. Bamburov ◽  
...  

The purpose of the research was to study the structure of MPG-7 fine-grained graphite by X-ray inspection and scanning electron microscope investigation methods. We carried out a structural and local chemical analysis of inhomogeneities occurring in graphite blanks. According to the data obtained, we changed technical documentation for the incoming quality control of MPG-7 graphite blanks and details.


Clay Minerals ◽  
1994 ◽  
Vol 29 (4) ◽  
pp. 575-589 ◽  
Author(s):  
C. V. Jeans ◽  
J. G. Mitchell ◽  
M. Scherer ◽  
M. J. Fisher

AbstractClay mica is the predominant component of the fine-grained siliciclastic sediments of the Western European Permo-Trias and it may occur as the sole component of the clay assemblage. Its characteristics have been studied by chemical analysis, radioisotope (K/Ar) data, X-ray diffraction and electron microscopy in the clay assemblages from Triassic and Permian sediments in Spain, Western Approaches, South Devon and East Yorkshire. The clay mica is a ferric dioctahedral mineral containing on average 6.5% Fe2O3 and 7.5% K2O. Crystal thickness ranges from 8 × 10 Å to 115 × 10 Å, and varies with geological, stratigraphical and grain-size factors. Radioisotope data and geological considerations suggest that much of the Permo-Triassic clay mica was formed originally in coeval desert soils rather than being derived from pre-existing rocks. It was then eroded, sometimes mixed with much older material, and deposited as fine-grained detritus in adjacent areas. Upon deep burial, this detrital mica assemblage underwent recrystallization with the development of euhedral crystals and the alteration of the K/Ar values.


Sign in / Sign up

Export Citation Format

Share Document