Bismuth-bearing assemblages from the Northern Pennine Orefield

1996 ◽  
Vol 60 (399) ◽  
pp. 317-324 ◽  
Author(s):  
R. A. Ixer ◽  
B. Young ◽  
C. J. Stanley

AbstractBismuthinite-bearing quartz veins from the Alston Block of the North Pennine Orefield are all close to, or above, the Rookhope and Tynehead cupolas of the buried Weardale Granite. They are uniform in composition and paragenesis and are earlier than the main fluorite-baryte-galena-sphalerite mineralization of the orefield. Rhythmical crystallization of quartz, chalcopyrite and minor pyrite is followed by fluorite-quartz-chalcopyrite-minor sphalerite-altered pyrrhotite mineralization. Early tin-bearing (up to 0.29 wt.% Sn) chalcopyrite encloses trace amounts of bismuthinite (Bi2S3), synchysite (CaREE(CO3)F2), argentopentlandite (Ag(FeNi)8S8) (close to being stoichiometric), pyrrhotite, cubanite and cosalite (Pb2Bi2S5), while early pyrite carries monoclinic pyrrhotite (close to Fe7S8) and tungsten-bearing cassiterite (up to 1.03 wt.% WO3). Bismuthinite is macroscopically visible and is associated with native bismuth and small, fine-grained, spherical aggregates that qualitative analysis suggests may be cosalite crystals. Synchysite and more rarely monazite, xenotime and adularia are intergrown with bismuthinite. These mineralogical data form part of the basis for an increasing awareness of the contribution of the Weardale Granite to the early phases of mineralization in the Alston Block.

Author(s):  
Max H. Hey ◽  
F. A. Bannister ◽  
Arthur Russell

In May, 1936, a quantity of pale yellow, rounded fragments, averaging 7 mm. across, was submitted to us by Mr. Arthur Russell for examination, with the information that the material came from the Castle-an-Dinas wolfram mine, and contained bismuth and tungsten. Chemical and spectroscopic examination showed that, besides bismuth and tungsten, the mineral contained only traces of silicon, arsenic, and iron. A sample of the same material had also been given to the British Museum by Mr. E. H. Davison in 1934 and registered provisionally as bismuth tungstate. This, however, would not have provided sufficient of the yellow mineral for chemical analysis. We are also indebted to Mr. Davison for a further generous supply of yellow pellets picked from the wolfram concentrates received since tile present work was begun. The mineral has all the attributes of an alteration product probably of native bismuth. It is fine-grained and compact, with hardness 3½, and on fracture it gives a clay-like odour. Some of the pellets show traces of a micaeeous mineral and quite frequently enclose native bismuth, wolframite, and bismuthinite. Mr. Russell has picked out from tihe material he had collected a few green pellets and some showing both the yellow and the green mineral. Spectrographs of the two are identical, but an X-ray powder photograph of the green mineral is quite distinct from that of tile yellow mineral.


2021 ◽  
pp. 1-21
Author(s):  
Julian C. Hughes ◽  
Jordan Baseman ◽  
Catherine Hearne ◽  
Mabel Leng Sim Lie ◽  
Dominic Smith ◽  
...  

Abstract This paper reports on a study which examined the notions of authenticity and citizenship for people living with cognitive impairment or dementia in a care home in the North-East of England. We demonstrated that both notions were present and were encouraged by engagement with an artist, where this involved audio and visual recordings and the creation of a film. The artist's interactions were observed by a non-participant observer using ethnographic techniques, including interviews with the residents, their families and the staff of the care home. The data were analysed using grounded theory and the constant comparative method of qualitative analysis. Our findings suggest that participatory art might help to maintain and encourage authenticity and citizenship in people living with dementia in a care home. Certainly, authenticity and citizenship are notions worth pursuing in the context of dementia generally, but especially in care homes.


1874 ◽  
Vol 1 (1) ◽  
pp. 1-2
Author(s):  
Edward Hull

This granite forms an isolated mass, rising into two eminences a few miles south of Louisburg, called Corvock Brack (1287 feet) and Knockaskeheen (1288 feet). It is a greyish granite—generally fine—grained—consisting of quartz, two felspars,—one orthoclase, the other triclinic, probably oligoclase—and dark green mica. In some places there are patches in which the felspar assumes the appearance of “graphic granite.” Numerous boulders of this granite are strewn over the district to the north-west, and on the south side of Knockaskeheen; the rock is traversed by regular joints ranging N. 10 W., along which it splits off into nearly vertical walls. The position of the granite is shown on Griffith's Geological Map of Ireland, and it is surrounded by schistose beds, generally metamorphosed, and probably of Lower Silurian age. The granite itself is of older date than the Upper Llandovery beds, which lie to the southward.


Geofluids ◽  
2020 ◽  
Vol 2020 ◽  
pp. 1-21
Author(s):  
Xinglin Chen ◽  
Yongjun Shao ◽  
Chunkit Lai ◽  
Cheng Wang

The Longmendian Ag–Pb–Zn deposit is located in the southern margin of the North China Craton, and the mineralization occurs mainly in quartz veins, altered gneissic wallrocks, and minor fault breccias in the Taihua Group. Based on vein crosscutting relations, mineral assemblages, and paragenesis, the mineralization can be divided into three stages: (1) quartz–pyrite, (2) quartz–polymetallic sulfides, and (3) quartz–carbonate–polymetallic sulfides. Wallrock alteration can be divided into three zones, i.e., chlorite–sericite, quartz–carbonate–sericite, and silicate. Fluid inclusions in all Stage 1 to 3 quartz are dominated by vapor-liquid two-phase aqueous type (W-type). Petrographic and microthermometric analyses of the fluid inclusions indicate that the homogenization temperatures of Stages 1, 2, and 3 are 198–332°C, 132–260°C, and 97–166°C, with salinities of 4.0–13.3, 1.1–13.1, and 1.9–7.6 wt% NaCleqv, respectively. The vapor comprises primarily H2O, with some CO2, H2, CO, N2, and CH4. The liquid phase contains Ca2+, Na+, K+, SO42−, Cl−, and F−. The sulfides have δ34S=–1.42 to +2.35‰ and 208Pb/204Pb=37.771 to 38.795, 207Pb/204Pb=15.388 to 15.686, and 206Pb/204Pb=17.660 to 18.101. The H–C–O–S–Pb isotope compositions indicate that the ore-forming materials may have been derived from the Taihua Group and the granitic magma. The fluid boiling and cooling and mixing with meteoric water may have been critical for the Ag–Pb–Zn ore precipitation. Geological and geochemical characteristics of the Longmendian deposit indicate that the deposit is best classified as medium- to low-temperature intermediate-sulfidation (LS/IS) epithermal-type, related to Cretaceous crustal-extension-related granitic magmatism.


Author(s):  
A. V. Maslov

Background. The lithogeochemical features of fine-grained detrital rocks (mudstones, shales, and fine-grained siltstones) allow, with a certain degree of success, the main parameters of the formation of sedimentary sequences to be reconstructed. These parameters include (primarily in terms of their REE and Th systematics) the types of river systems supplying thin terrigenous suspension in the sedimentation area: the rivers of the 1st category – large rivers with a catchment area of more than 100,000 km2; 2nd category – rivers feeding on the products of erosion of sedimentary deposits; 3rd category – rivers draining mainly igneous and metamorphic rocks; and 4th category – rivers carrying erosion products of volcanic associations.Aim. To reveal, based on the analysis of interrelationships between such parameters as (La/Yb)N, Eu/Eu* and the Th content, the types of river systems that fed the Jurassic and Lower Cretaceous deposits of the Shaim oil and gas region (OGR) (Sherkalinsky, Tyumen, Abalak and Mulymya formations) and the region of the North Pokachevsky field of the Shirotnoe Priobye region (Sherkalinsky, Tyumen and Bazhenov formations, Lower Cretaceous deposits).Materials and methods. The ICP MS data for almost 100 samples of mudstones and fine-grained clayey siltstones were used to analyse the features of distribution of lanthanides and Th in the Jurassic and Lower Cretaceous clayey rocks of the Shaim OGR and the area of the North Pokachevsky deposits. Individual and average composition points for formations, members and layers were plotted on the (La/Yb)N-Eu/Eu*, (La/Yb)N–Th diagrams developed by us with classification areas of the composition of fine suspended material of modern rivers of different categories.Results and conclusion. The results presented in the article showed that during the formation of the deposits of the Shaim OGR in the Early and Middle Jurassic, erosion affected either mainly sedimentary formations or paleo-catchment areas that were very variegated in their rock composition. In the Late Jurassic, the source area was, most likely, a volcanic province, composed mainly of igneous rocks of the basic composition, and located within the Urals. This conclusion suggested that the transfer of clastic material from the Urals to the Urals part of the West Siberian basin “revived” much earlier than the Hauterivian. The Jurassic-Lower Cretaceous section of the vicinity of the North Pokachevsky field was almost entirely composed of thin aluminosilicaclastics formed due to the erosion of volcanic formations. These volcanic formations were located, as followed from the materials of earlier performed paleogeographic reconstructions, probably within the Altai-Sayan region or Northern Kazakhstan. Thus, the supply of detrital material in the considered territories of the West Siberian basin had a number of significant differences in the Jurassic and early Cretaceous.


2017 ◽  
Vol 54 (4) ◽  
pp. 379-392
Author(s):  
David G. Bailey ◽  
Marian Lupulescu ◽  
Jeffrey Chiarenzelli ◽  
Jonathan P. Traylor

Two syenite sills intrude the local Paleozoic strata of eastern New York State and are exposed along the western shore of Lake Champlain. The sills are fine-grained, alkali feldspar syenites and quartz syenites, with phenocrysts of sanidine and albite. The two sills are compositionally distinct, with crossing rare earth element profiles and different incompatible element ratios, which eliminates the possibility of a simple petrogenetic relationship. Zircon extracted from the upper sill yields a U–Pb age of 131.1 ± 1.7 Ma, making the sills the youngest known igneous rocks in New York State. This age is similar to that of the earliest intrusions in the Monteregian Hills of Quebec, >100 km to the north. Sr and Nd radiogenic isotope ratios are also similar to those observed in some of the syenitic rocks of the eastern Monteregian Hills. The Cannon Point syenites have compositions typical of A-type, within-plate granitoids. They exhibit unusually high Ta and Nb concentrations, resulting in distinct trace element signatures that are similar to those of the silicic rocks of the Valles Caldera, a large, rift-related magmatic system. We suggest that the Cannon Point syenites were melts derived primarily by anatexis of old, primitive, lower crustal material in response to Mesozoic rifting and to the intrusion of mantle-derived magmas. The sills indicate that the effects of continental rifting were spatially and temporally extensive, resulting in the reactivation of basement faults in the Lake Champlain Valley hundreds of kilometers west of the active rift boundary, and crustal melting >50 Ma after the initiation of rifting.


1975 ◽  
Vol 12 (3) ◽  
pp. 361-370 ◽  
Author(s):  
Jackson M. Barton Jr. ◽  
Erika S. Barton

The Snyder breccia is composed of angular to subrounded xenoliths of migmatites and amphibolites in a very fine grained matrix. It is apparently intrusive into the metasediments of the Snyder Group exposed at Snyder Bay, Labrador. The Snyder Group unconformably overlies a migmatitic and amphibolitic basement complex and is intruded by the Kiglapait layered intrusion. K–Ar ages indicate that the basement complex is Archean in age (> 2600 m.y. old) and that the Kiglapait layered intrusion was emplaced prior to 1280 m.y. ago. Major and trace element analyses of the matrix of the Snyder breccia indicate that while it was originally of tonalitic composition, later it locally underwent alteration characterized by loss of sodium and strontium and gain of potassium, rubidium and barium. Rb–Sr isotopic analyses show that this alteration occurred about 1842 m.y. ago, most probably contemporaneously with emplacement of the breccia. The Snyder Group thus was deposited sometime between 2600 and 1842 m.y. ago and may be correlative with other Aphebian successions preserved on the North Atlantic Archean craton.


2010 ◽  
Vol 181 (3) ◽  
pp. 227-241 ◽  
Author(s):  
Dominique Gasquet ◽  
Jean-Michel Bertrand ◽  
Jean-Louis Paquette ◽  
Jérémie Lehmann ◽  
Gueorgui Ratzov ◽  
...  

Abstract U-Pb and Th-Pb dating of monazite from hydrothermal quartz veins (“Alpine veins”) from the Lauzière massif (North Belledonne) together with Ar/Ar ages of adularias from the same veins constrain the age of the last tectono-metamorphic events that affected the External Crystalline Massifs (ECM). Ages obtained are surprisingly young. The study of the structural context of the veins combined with our chronological data, allow us to propose a tectonic scenario of the northern ECM for the 15-5 Ma period, which was poorly documented so far. The quartz veins are of two types: (i) the oldest are poorly mineralized (chlorite and epidote), flat-lying veins. The quartz fibres (= extension direction) are near vertical and seem to be associated with a subvertical dissolution schistosity superimposed upon an early Alpine deformation underlined by “mini-biotite”. They bear a sub-horizontal stretching lineation; (ii) the youngest veins are very rich in various minerals (anatase, rutile, phénacite, meneghinite, beryl, synchysite, ….). They are almost vertical. Their “en echelon” geometry as well as the horizontal attitude of their quartz fibres show a dextral strike-slip regime. Two groups of Th-Pb ages have been obtained: 11 to 10 Ma and 7 to 5 Ma. They were obtained from the most recent veins (vertical veins) sampled in different areas of the massif. The ca. 10 Ma ages are related to veins in the Lauzière granite and its metamorphic country-rocks at about 2 km from the eastern contact of the massif, while the ages of ca. 5 Ma correspond to veins occurring in mylonites along this contact. Adularias provided Ar/Ar ages at ca. 7 Ma. By contrast, a monazite from a vein of the Pelvoux massif (Plan du Lac) yielded a Th-Pb age of 17.6 Ma but in a different structural setting. Except fission track ages, there are very little ages of this range published in the recent literature on the Alps. The latter concern always gold mineralized veins (NE Mont Blanc and SW Lepontine dome). The last compressive tectonic regime dated between 15 and 12 Ma is coeval with (i) the late “Roselend thrust” event, which is recorded in the Mont Blanc by shear-zones with vertical lineation, (ii) the last movements in the basal mylonites of the Swiss Nappes, (iii) the horizontal Alpine veins from the Mont Blanc and Belledonne massifs (with vertical quartz fibres), which are similar to the early veins of the Lauzière. On the contrary, the vertical veins of the Lauzière, dated between 11 and 5 Ma, correspond to a dextral strike slip regime. This suggests that most of the strike-slip tectonics along the ECM took place during two stages (ca. 10 Ma and ca. 7-5 Ma) and not only at 18 Ma as had been proposed previously. Our ages are consistent with the late Miocene-Pliocene overlap of the Digne thrust to the South and to part of the normal movement along the Simplon fault to the North. Thus, all the external crystalline massifs were tectonically active during the late Miocene. This suggests that tectonic events in the external alpine belt may have contributed to some extent to the geodynamical causes of the Messinian crisis.


1942 ◽  
Vol 22 (2) ◽  
pp. 113-122 ◽  
Author(s):  
James G. Mann

The two gauntlets which were exhibited to the Society by kind permission of the Archdeacon of Richmond, on 26th November 1941, form part of the funeral achievement of Sir Edward Blackett (died 1718), hanging above his monument in the north transept of Ripon Cathedral. The achievement consists of a close-helmet of the sixteenth century with a wooden funeral crest of a falcon (for Blackett); a tabard; a cruciform sword in its scabbard, of the heraldic pattern of the early eighteenth century; and two iron gauntlets. The wooden escutcheon and pair of spurs which must once have completed the group are now missing.


2021 ◽  
Author(s):  
Wei Jian ◽  
Jingwen Mao ◽  
Bernd Lehmann ◽  
Nigel J. Cook ◽  
Guiqing Xie ◽  
...  

Abstract We present petrographic and microthermometric evidence for precipitation of Au-Ag-Te–rich melt directly from hydrothermal fluids and subsequent entrapment as primary melt inclusions within pyrite from quartz veins of the Xiaoqinling lode gold district, southern margin of the North China craton. We propose the formation of Au-Ag-Te–rich melt through adsorption-reduction mechanisms on pyrite and subsequent growth of the melt nuclei via direct scavenging of metals from fluids. Because neither initial formation nor later growth of the melt require saturation of the ore fluid with respect to the constituent metals, this mechanism offers a new understanding of the enrichment of low-abundance ore components, such as gold. Our model may thus partly explain the discrepancy between the high gold solubilities reported from experimental studies and the much lower gold concentrations usually measured in natural fluids. This study also implies that Au-Ag-Te–rich melt has probably gone unrecognized in other lode gold deposits in which Au-Ag tellurides are present.


Sign in / Sign up

Export Citation Format

Share Document