In order to solve the environment pollution of limestone powder during production of limestone manufactured sand and gravel and problem of lack of high quality fly ash or slag powder in ocean engineering, ultra-fine limestone powder was selected for preparation of green high-performance marine concrete containing fly ash and limestone powder and that containing slag powder and limestone powder for tests on workability, mechanical performance, thermal performance, shrinkage, and resistance to cracking and chloride ion permeability. And comparison was made between such green high-performance concrete and conventional marine concrete containing fly ash and slag powder. Moreover, the mechanism of green high-performance marine concrete was preliminary studied. Results showed that ultra-fine limestone powder with average particle size around 10μm had significant water reducing function and could improve early strength of concrete. C50 high-performance marine concrete prepared with 30% fly ash and 20% limestone powder or with 30% slag powder and 30% limestone powder required water less than 130kg/m3, and showed excellent workability with 28d compressive strength above 60MPa, 56d dry shrinkage rate below 300με, cracking resistance of grade V, 56d chloride ion diffusion coefficient not exceeding 2.5×10-12m2/s. Mechanical performance and resistance to chloride ion permeability of limestone powder marine concrete were quite equivalent to those of conventional marine concrete. But it had better workability, volume stability and cracking resistance. Moreover, it can serve as a solution to the lack of high quality fly ash and slag powder.
Molecular dynamics and experimental study on the adhesion mechanism of polyvinyl alcohol (PVA) fiber in alkali-activated slag/fly ash
