scholarly journals Zinc Adsorption in Relation to Soil Properties, Analysed with Langmuir and Freundlich Models in Soils of Kashmir Valley

2019 ◽  
Vol 7 (1) ◽  
pp. 68-73
Author(s):  
Syed Sadat ◽  
N. Z. Rehman ◽  
M. A. Bhat ◽  
M.A. Wani

The phenomenon of fixation of added zinc in soils considerably affects the availability and efficiency of applied zinc. Pertaining to this situation, different land-use soil samples across the valley were analysed for various physico-chemical properties and adsorption capacities. The results showed that the soils were slightly acidic to alkaline in reaction and differ far and wide in other soil properties. Cation exchange capacity (CEC) of the soils showed little variation between the samples and varied from13.3 to 17.2 cmol(p+) kg-1 with an average value of 15.1 cmol(p+) kg-1of soil. The maximum of zinc adsorption were greatly influenced by soil organic matter, clay content and CEC of the soils. The data was fitted to Langmuir and Freundlich equations and the results yielded that the Freundlich equation showed better fit to the sorption data at higher zinc concentrations. However, both the models were having satisfactory results for the obtained data.

Soil Systems ◽  
2020 ◽  
Vol 4 (4) ◽  
pp. 62 ◽  
Author(s):  
José Manuel Mirás-Avalos ◽  
María Fandiño ◽  
Benjamín J. Rey ◽  
Jorge Dafonte ◽  
Javier J. Cancela

Soil properties show a high spatio-temporal variability, affecting productivity and crop quality within a given field. In new vineyard plantations, with changes in the initial topographic profile, this variability is exacerbated due to the incorporation of soil from different origins and qualities. The aim of the current study was to characterize the variability of soil properties in a newly established vineyard, and delineating zones for site-specific management of fertilization. For this purpose, the soil apparent electrical conductivity (ECa) in the first 150 cm was measured with an electromagnetic induction sensor. A soil sampling was performed following a regular grid (35 × 35 m, 149 samples), collecting samples down to 40 cm depth for determining soil chemical properties. Spatial variability was assessed through semivariogram calculation and ordinary kriging. The soil properties that better represent the variability in this newly established vineyard were pH, effective cation exchange capacity (ECEC), carbon content, clay and ECa. The ECa was homogeneous all over the vineyard, except for the area closer to the river where a greater human intervention had occurred, with contributions of external soil at a greater depth. Soil properties showed a great spatial variability. Interpolated maps allowed for detecting areas with a lack of nutrients in which a differential fertilization could be performed in search of a sustainable and balanced production. The information provided by the maps of pH, ECEC and carbon and potassium contents allow for performing a differential management of the vineyard in terms of fertilization. In addition, the results obtained suggest that the vineyard should be divided into two sectors for a differential irrigation management. The ECa was not significantly correlated to most of the soil properties determined in the current study; however, it allowed for a low-cost mapping of the vineyard soil and established large areas of management within the vineyard.


Environments ◽  
2021 ◽  
Vol 8 (5) ◽  
pp. 38
Author(s):  
Judith Álvarez ◽  
Elías Afif ◽  
Tomás E. Díaz ◽  
Laura García ◽  
Jose A. Oliveira

Fertilization and mowing affects the physico-chemical properties of soils, as well as the characteristics of the plants growing on them. Changes in the management techniques are causing semi-natural grasslands to disappear all over Europe. These grasslands host a great amount of diversity, thus their conservation is a top priority. This work studies whether the kind of management has an influence on the soil properties and the foliar content in macronutrients in 25 hay meadows located in Picos de Europa (10 in Asturias, 10 in Castilla y León and 5 in Cantabria). Soils at a 0–20 cm depth showed a high content of organic matter and a low C/N ratio. Effective cation exchange capacity was adequate for a texture, which varied from sandy clay loam to loam, with an average clay content of 17%. Mean values of foliar nutrient concentrations showed a deficiency in K. In this study, management practices were shown to affect some properties of the soils, namely pH, sand percentage and exchangeable K and Ca, to different extents. The highest values of pH and exchangeable Ca were significantly correlated with the least intensive management.


2011 ◽  
Vol 3 (3) ◽  
pp. 683-688
Author(s):  
M. N. Islam ◽  
A. F. M. Sanaullah

Bangladesh is one of the tea producing countries of the world. It has 163 tea estates. Rangapani is a low yielding tea estate relative to other neighboring tea estates of Chittagong district in Bangladesh. A total 54 soil samples were collected from six different hills and three topographic positions having different depths of Rnagapanni Tea-Estate. Physico-Chemical properties of soils such as active acidity, reserve acidity, cation exchange capacity and clay content of the collected soil samples were determined. The measured parameters of the soil samples were plotted and analyzed with reference to site and topography. The parameters have been found to vary with sampling sites, depths and topography. Active acidity and reserve acidity were very low, with some exceptions compared to the optimum range for tea cultivation. Sand, silt, clay and cation exchange capacity (CEC) were found in reasonable range Keywords:  Soil; Active acidity; Reserve acidity; Cation exchange capacity; Clay content. © 2011 JSR Publications. ISSN: 2070-0237 (Print); 2070-0245 (Online). All rights reserved. doi: 10.3329/jsr.v3i3.7503               J. Sci. Res. 3 (3), 683-688 (2011)


2017 ◽  
Vol 38 (1) ◽  
pp. 143
Author(s):  
Liane Barreto Alves Pinheiro ◽  
Rodrigo Camara ◽  
Marcos Gervasio Pereira ◽  
Eduardo Lima ◽  
Maria Elizabeth Fernandes Correia ◽  
...  

Mound-building termites are important agents of soil bioperturbation, but these species have not been extensively studied thus far. The present study aimed to evaluate the soil particle-size and the chemical attributes of termite mounds and the surrounding soil under different land use strategies. A one-hectare plot was defined for an unmanaged degraded pasture, planted pasture, and for a eucalyptus Corymbia citriodora plantation. In each plot, the top, center, and base sections of five Cornitermes cumulans mounds, and the surrounding soil at the depths of 0-5; 5-10; 10-20 cm, were sampled in the Pinheiral, Rio de Janeiro state. In the three areas, the center of the mounds contained higher clay content, organic carbon, phosphorous, calcium and magnesium, total bases, and cation exchangeable capacity, when compared to the top, base, and the surrounding soils. However, the center had lower values of exchangeable acidity and potassium, of the three areas. In the eucalyptus plantation, the values of pH, total bases, calcium, and magnesium were lower, whereas aluminum, exchangeable acidity, sodium, and cation exchange capacity were higher both in the mounds and in the surrounding soil, in relation to the pastures. There were no differences among the three areas in terms of organic carbon, potassium, phosphorous, and total bases, in the mounds and adjacent soil. Thus, the termite activity altered the clay content and most of the soil chemical properties in all of the studied areas, but only for the center of the mounds. However, the effect of these organisms was different in the eucalyptus plantation in relation to the pasture areas.


Author(s):  
Vítězslav Vlček ◽  
Miroslav Pohanka

Soil samples (n = 11) were collected in the chernozem areas of the Czech Republic (the Central Europe) from the topsoil and used as representative samples. All sampling areas have been used for agricultural purposes (arable soil) and they were selected as typical representatives of agricultural soil. These samples represented the soil with same genesis (to reduction differencies between soil types) but with different soil properties (physical and chemical). Complete chemical and physical analyses were made for confirmation of copper adsorption on solid phase: we analysed the particle size distribution, content of oxidizable carbon (Cox), the cation exchange capacity (CEC), supply of exchange calcium, magnesium, sodium, phosphorus and potassium, soil reaction and the total supply of Fe, Al, Mn, Ca, Mg, K, P and N. The strongest simple correlation between analysed soil properties and copper concentration had content of available magnesium (r = 0.44) and available phosphorus (r = −0.51). In the case of multiple correlations (i. e. collective influence of multiple soil properties) had the strongest influence combination of clay, soil reaction, total content of phosphorus, available magnesium and available phosphorus. The main influence of phosphorus and magnesium is evident. We suppose that copper and phosphorus enter into specific complex. Influence of these five soil properties can explain 92.7 % (r = 0.927) changes in the content of copper changes in the experiment.


2017 ◽  
Vol 2 (1) ◽  
Author(s):  
M. M. Nasef ◽  
H. Saidi ◽  
A. H. Yahaya

Crosslinked cation exchange membranes bearing sulfonic acid groups (PE-g-PSSA/DVB) were prepared by radiationinduced grafting of styrene/divinylbenzene (DVB) mixtures onto low density polyethylene (PE) films followed by sulfonation reactions. The effect of addition of DVB (2 and 4%) on the grafting behavior and the physico-chemical properties of the membranes such as ion exchange capacity, swelling and ionic conductivity were evaluated incorrelation with grafting yield (Y%). The structural and thermal properties of the membranes were also studied using differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA), respectively. Crosslinking with DVB was found to considerably affect the properties of the membranes in a way that reduces the swelling properties and enhances the chemical stability. The ion conductivity of the crosslinked membranes recorded a level of 10–2 S/cm at sufficient grafting yield (28%) despite the reduction caused by the formation of crosslinking structure. The results of this work suggest that membranes prepared in this study are potential alternatives for various electrochemical applications.


2020 ◽  
Vol 34 (3) ◽  
pp. 275-284
Author(s):  
Ricardo Antonio Ferreira da Silva ◽  
Danilo Brito da Costa ◽  
William de Paiva ◽  
Márcio Camargo de Melo ◽  
Veruschka Escarião Dessoles Monteiro

The adsorption of heavy metals by sanitary landfill liners represents a measure of protection of surface and groundwaters against contamination by metals, mitigating risks to public health. Hence, this research aimed to identify, from correlations, the influence of physico-chemical properties of soils applied in landfill liners using nickel adsorption parameters. Batch equilibrium tests with initial nickel concentrations of 45 to 1440 mg.L-1 were performed in clayey sand and bentonite clay soil, as well as in mixtures. Nickel adsorption parameters from Freundlich and Langmuir isotherm models were obtained, exhibiting a better adjustment in the Freundlich model based on R² and RMSE criteria. Thus, the addition of bentonite clay improved the adsorption to nickel, and the cationic exchange capacity (CEC) was the property that considerably influenced the metal retention in the studied soils.


2008 ◽  
Vol 53 (No. 5) ◽  
pp. 225-238 ◽  
Author(s):  
N. Finžgar ◽  
P. Tlustoš ◽  
D. Leštan

Sequential extractions, metal uptake by <i>Taraxacum officinale</i>, Ruby&rsquo;s physiologically based extraction test (PBET) and toxicity characteristic leaching procedure (TCLP), were used to assess the risk of Pb and Zn in contaminated soils, and to determine relationships among soil characteristics, heavy metals soil fractionation, bioavailability and leachability. Regression analysis using linear and 2nd order polynomial models indicated relationships between Pb and Zn contamination and soil properties, although of small significance (<i>P</i> < 0.05). Statistically highly significant correlations (<i>P</i> < 0.001) were obtained using multiple regression analysis. A correlation between soil cation exchange capacity (CEC) and soil organic matter and clay content was expected. The proportion of Pb in the PBET intestinal phase correlated with total soil Pb and Pb bound to soil oxides and the organic matter fraction. The leachable Pb, extracted with TCLP, correlated with the Pb bound to carbonates and soil organic matter content (<i>R</i><sup>2</sup> = 69%). No highly significant correlations (<i>P</i> < 0.001) for Zn with soil properties or Zn fractionation were obtained using multiple regression.


1970 ◽  
Vol 19 (1) ◽  
pp. 63-72 ◽  
Author(s):  
Mohammad Zabed Hossain ◽  
Mihir Lal Saha ◽  
Chaman Binta Aziz ◽  
Sirajul Hoque

This study examined the effect of deforestation on the soil properties (physico-chemical and bacterial) of the Sal (Shorea robusta Roxb. Ex Gaertn.) forests in Bangladesh. Physico-chemical properties and the bacterial colony counts of soil were studied by comparing a natural Sal forest site with deforested and planted with Menjium site, deforested and planted with Mahogoni site, as well as deforested but not planted but covered with profuse growth of Axonopus compressus grass species site. Moisture content was significantly lower in the deforested and planted with Menjium site and deforested and planted with Mahogoni site than the natural forest site and the deforested but not planted site. Total organic carbon, total nitrogen and available nitrogen contents were significantly lower in the natural forest site. Significantly higher number of bacterial colony and higher organic carbon and moisture contents were found in the deforested but not planted site indicating that both organic carbon and moisture content were important for microbial growth. The present study clearly showed that deforestation significantly altered the soil physico-chemical and bacterial communities of the Sal forests. It was also revealed that plantation with different exotic plants were found to be different in influencing soil properties. Key words: Bacterial colony; Deforestation effects; Sal forest; Soil physico-chemical properties DOI: http://dx.doi.org/10.3329/dujbs.v19i1.8945 DUJBS 2010; 19(1): 63-72


2013 ◽  
Vol 59 (No. 8) ◽  
pp. 372-377 ◽  
Author(s):  
W. Szulc ◽  
B. Rutkowska

The determination of a range of boron concentration in the soil solution, evaluation of the effect of physico-chemical soil properties on boron concentration in the soil solution as well verification whether boron quantity in the soil solution is sufficient for nutritional needs of selected plants cultivated in Poland were comprised. Average boron concentration in the soil solution of Poland&rsquo;s cultivated soils ranges from 0.59 to 5.07 &micro;mol/L and is differentiated by physico-chemical properties of soil. Taking into account decreasing effects of soil properties on the increase of boron concentration in the soil solution, the soil properties can be arranged as follows: organic C &gt;<br />soil abundance in available boron &gt; soil texture &gt; soil pH. The minimum boron quantity observed in the soil solution of Poland&rsquo;s cultivated soils was not sufficient to fulfil nutritional needs of the plants. The maximum boron quantity observed secured nutritional needs of cereals and potatoes but not those of rape plants and sugar beets. Based on the study it can be concluded that the measurement of the concentration of boron in the soil solution can be used in the diagnosis of deficiency of this element for crops.


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