Oxy-fuel Combustion Power Cycles: A Sustainable Way to Reduce Carbon Dioxide Emission

Author(s):  
Anand Pavithran ◽  
Meeta Sharma ◽  
Anoop Kumar Shukla

The energy generation from the fossil fuels results to emit a tremendous amount of carbon dioxide into the atmosphere. The rise in the atmospheric carbon dioxide level is the primary reason for global warming and other climate change problems for which energy generation from renewable sources is an alternative solution to overcome this problem. However, the renewables sources are not as reliable for the higher amount of energy production and cannot fulfil the world’s energy demand; fossil fuels will continue to be consumed heavily for the energy generation requirements in the immediate future. The only possible solution to overcome the greenhouse gas emission from the power plant is by capturing and storing the carbon dioxide within the power plants instead of emitting it into the atmosphere. The oxy-fuel combustion power cycle with a carbon capture and storage system is an effective way to minimize emissions from the energy sectors. The oxy-fuel power cycle can reduce 90–99% of carbon dioxide emissions from the atmosphere. Moreover, the oxy-fuel power cycles have several advantages over the conventional power plants, these include high efficiency, lesser plant footprint, much easier carbon-capturing processes, etc. Because of these advantages, the oxy-fuel combustion power cycles capture more attention. In the last decades, the number of studies has risen exponentially, leading to many experimental and demonstrational projects under development today. This paper reviews the works related to oxy-fuel combustion power generation technologies with carbon capture and storage system. The cycle concepts and the advancements in this technology have been briefly discussed in this paper.

Author(s):  
Naimish Agarwal

Abstract: More than ever, the fate of anthropogenic CO2 emissions is in our hands. Since the advent of industrialization, there has been an increase in the use of fossil fuels to fulfil rising energy demands. The usage of such fuels results in the release of carbon dioxide (CO2) and other greenhouse gases, which result in increased temperature. Such warming is extremely harmful to life on Earth. The development of technology to counter the climate change and spreading it for widespread adoptions. We need to establish a framework to provide overarching guidance for the well-functioning of technology and mechanism development of Carbon Capture and Storage. Carbon capture and storage (CCS) is widely regarded as a critical approach for achieving the desired CO2 emission reduction. Various elements of CCS, such as state-of-the-art technology for CO2 collection, separation, transport, storage, politics, opportunities, and innovations, are examined and explored in this paper. Carbon capture and storage is the process of capturing and storing carbon dioxide (CO2) before it is discharged into the environment (CCS). The technology can capture high amounts of CO2 produced by fossil fuel combustion in power plants and industrial processes. CO2 is compressed and transferred by pipeline, ship, or road tanker once it has been captured. CO2 can then be piped underground, usually to depths of 1km or more, and stored in depleted oil and gas reservoirs, coalbeds, or deep saline aquifers, depending on the geology. CO2 could also be used to produce commercially marketable products. With the goal of keeping world average temperatures below 1.5°C (2.7°F) and preventing global average temperature rises of more than 2°C (3.6°F) over pre-industrial levels, CCS model should be our priority to be implemented with the proper economical map


Author(s):  
Jacob Delimont ◽  
Aaron McClung ◽  
Marc Portnoff

Direct fired oxy-fuel combustion as a heat source for supercritical carbon dioxide (sCO2) power cycles is a promising method for providing the needed thermal energy input. The method of combustion has the potential to provide efficient power generation with integrated carbon capture at up to 99% of generated CO2. One of the highest efficiency power cycles being considered for sCO2 cycles in the recompression cycle. In the recompression sCO2 power cycle, the amount of energy recovered from the recuperation is roughly five times the energy added via the combustor. Because of this high degree of recuperation in sCO2 power cycles, the inlet temperature of the combustor is much higher than a more traditional combustor design. This elevated combustor temperature leads to some unique design challenges and approaches which are quite different from a traditional combustion system. A combustor designed for these conditions has never been built, and thus the design of the combustor discussed in this paper started from a clean slate. This necessitates a large degree of fundamental research which might not be necessary for a more well understood traditional combustor design process. Building on previous thermodynamic and chemical kinetics studies, a reduced order reaction kinetics model was used with ANSYS CFX software to explore various auto-ignition type combustor geometries. A discussion of some geometries and the modelling techniques used is presented. Various injector configurations were examined and metrics were used to compare the various configurations. By utilizing the CFD flow field results, a preliminary design for a 1MW-class oxy-fuel combustor was developed. In the past, little experimental research has been conducted on combustion within carbon dioxide at pressures above 200 bar. In order to confirm the validity of the auto-ignition style combustor a small bench top test rig was constructed to test the oxy-fuel combustion at the full pressure and temperature. This system was designed to validate some of the fundamental properties of the combustion. This includes a gas sampling system and a measurement of auto-ignition delay. Preliminary, data from a bench top scale, sCO2 oxy-fuel combustor experiment will be presented. The results from this work will enable future development of sCO2 power cycles which enable 99% carbon capture, while maintaining overall cycle efficiency which is competitive with natural gas combined cycle power plants.


2021 ◽  
Vol 2119 (1) ◽  
pp. 012101
Author(s):  
I G Donskoy

Abstract One of the main problems in the use of solid fuels is inevitable formation of significant amounts of carbon dioxide. The prospects for reducing CO2 emissions (carbon capture and storage, CCS) are opening up with the use of new coal technologies, such as thermal power plants with integrated gasification (IGCC) and transition to oxygen-enriched combustion (oxyfuel). In order to study the efficiency of solid fuel conversion processes using carbon dioxide, thermodynamic modeling was carried out. Results show that difference between efficiency of fuel conversion in O2/N2 and O2/CO2 mixtures increases with an increase in the volatile content and a decrease in the carbon content. The effect of using CO2 as a gasification agent depends on the oxygen concentration: at low oxygen concentrations, the process temperature turns out to be low due to dilution; at high oxygen concentrations, the CO2 concentration is not high enough for efficient carbon conversion.


Author(s):  
G. Hachem ◽  
J. Salazar ◽  
U. Dixekar

Carbon capture and storage (CCS) constitutes an extremely important technology that is constantly being improved to minimize the amounts of carbon dioxide (CO2) entering the atmosphere. According to the Global CCS Institute, there are more than 320 worldwide CCS projects at different phases of progress. However, current CCS processes are accompanied with a large energy and efficiency penalty. This paper models and simulates a post-combustion carbon capture system, that uses absorption as a method of separation, in Aspen Plus V7.2. Moreover, the CAPE-OPEN Simulated Annealing (SA) Capability is implemented to minimize the energy consumed by this system, and allow coal-fired power plants to use similar carbon capture systems without losing 20 to 40 % of the plant's output.


2007 ◽  
Vol 25 (5) ◽  
pp. 357-392 ◽  
Author(s):  
Havva Balat ◽  
Cahide Öz

This article deals with review of technical and economic aspects of Carbon Capture and Storage. Since the late 1980s a new concept is being developed which enables to make use of fossil fuels with a considerably reduced emission of carbon dioxide to the atmosphere. The concept is often called ‘Carbon Capture and Storage’ (CCS). CCS technologies are receiving increasing attention, mainly for their potential contribution to the optimal mitigation of carbon dioxide emissions that is intended to avoid future, dangerous climate change. CCS technologies attract a lot of attention because they could allow “to reduce our carbon dioxide emissions to the atmosphere whilst continuing to use fossil fuels”. CCS is not a completely new technology, e.g., the United States alone is sequestering about 8.5 MtC for enhanced oil recovery each year. Today, CCS technologies are widely recognised as an important means of progress in industrialized countries.


Subject Carbon capture and storage technology. Significance Carbon capture and storage (CCS) is considered critical to achieving the ambitious reductions in greenhouse gas emissions set out in the 2015 Paris Agreement. CCS technology would allow power plants and industrial facilities to continue burning fossil fuels without pumping climate change-inducing gases into the atmosphere. However, deployment of CCS has been slow and the prospect of meeting the expectations placed upon it by the Paris climate negotiators is moving further out of scope. The recent cancellation of the Kemper CCS project in the United States is a bad sign for the future of the technology. Impacts Without faster deployment of CCS, many countries will struggle to meet their Paris Agreement emissions reduction pledges. If the rollout of CCS continues to falter, more wind and solar power will be needed to reduce carbon emissions. Absent a viable CCS model, it will be even more difficult to replace aged coal plants in the United States and other developed economies.


Author(s):  
Patricia N. Seevam ◽  
Julia M. Race ◽  
Martin J. Downie ◽  
Phil Hopkins

Climate change has been attributed to greenhouse gases with carbon dioxide (CO2) being the major contributor. Most of these CO2 emissions originate from the burning of fossil fuels (e.g. power plants). Governments and industry worldwide are now proposing to capture CO2 from their power plants and either store it in depleted reservoirs or saline aquifers (‘Carbon Capture and Storage’, CCS), or use it for ‘Enhanced Oil Recovery’ (EOR) in depleting oil and gas fields. The capture of this anthropogenic (man made sources of CO2) CO2 will mitigate global warming, and possibly reduce the impact of climate change. The United States has over 30 years experience with the transportation of carbon dioxide by pipeline, mainly from naturally occurring, relatively pure CO2 sources for onshore EOR. CCS projects differ significantly from this past experience as they will be focusing on anthropogenic sources from major polluters such as fossil fuel power plants, and the necessary CO2 transport infrastructure will involve both long distance onshore and offshore pipelines. Also, the fossil fuel power plants will produce CO2 with varying combinations of impurities depending on the capture technology used. CO2 pipelines have never been designed for these differing conditions; therefore, CCS will introduce a new generation of CO2 for transport. Application of current design procedures to the new generation pipelines is likely to yield an over-designed pipeline facility, with excessive investment and operating cost. In particular, the presence of impurities has a significant impact on the physical properties of the transported CO2 which affects: pipeline design; compressor/pump power; repressurisation distance; pipeline capacity. These impurities could also have implications in the fracture control of the pipeline. All these effects have direct implications for both the technical and economic feasibility of developing a carbon dioxide transport infrastructure onshore and offshore. This paper compares and contrasts the current experience of transporting CO2 onshore with the proposed transport onshore and offshore for CCS. It covers studies on the effect of physical and transport properties (hydraulics) on key technical aspects of pipeline transportation, and the implications for designing and operating a pipeline for CO2 containing impurities. The studies reported in the paper have significant implications for future CO2 transportation, and highlight a number of knowledge gaps that will have to be filled to allow for the efficient and economic design of pipelines for this ‘next’ generation of anthropogenic CO2.


Nukleonika ◽  
2014 ◽  
Vol 59 (1) ◽  
pp. 3-7
Author(s):  
Stanisław Chałupnik ◽  
Małgorzata Wysocka

Abstract Poland, due to the ratification of the Kioto Protocol, is obliged to diminish the emission of greenhouse gases. One of the possible solutions of this problem is CO2 sequestration (CCS - carbon capture and storage). Such an option is a priority in the European Union. On the other hand, CO2 sequestration may be potentially risky in the case of gas leakage from underground reservoirs. The most dangerous event may be a sudden release of the gas onto the surface. Therefore, it is very important to know if there is any escape of CO2 from underground gas reservoirs, created as a result of sequestration. Such information is crucial to ensure safety of the population in areas located above geological reservoirs. It is possible to assess the origin of carbon dioxide, if the measurement of radiocarbon 14C concentration in this gas is done. If CO2 contains no 14C, it means, that the origin of the gas is either geological or the gas has been produced as a result of combustion of fossil fuels, like coal. A lot of efforts are focused on the development of monitoring methods to ensure safety of CO2 sequestration in geological formations. A radiometric method has been tested for such a purpose. The main goal of the investigations was to check the application possibility of such a method. The technique is based on the liquid scintillation counting of samples. The gas sample is at first bubbled through the carbon dioxide adsorbent, afterwards the adsorbent is mixed with a dedicated cocktail and measured in a low-background liquid scintillation spectrometer Quantulus. The described method enables measurements of 14C in mine and soil gas samples.


Author(s):  
Jacob Delimont ◽  
Nathan Andrews ◽  
Lalit Chordia

Direct fired oxy-fuel combustion provides a promising method for heat addition into a supercritical carbon dioxide (sCO2) power cycle. Using this method of thermal energy input into the cycle allows for potentially higher fuel to bus bar cycle efficiency. In addition, the nature of the sCO2 power cycle lends itself to easy and efficient capture of 99% of the CO2 generated in the combustion process. sCO2 power cycles typically operate at pressures above 200 bar, and due to the high degree of recuperation found in these cycles, have a very high combustor inlet temperature. Past works have explored combustor inlet temperatures high enough to be in the autoignition regime. The inlet temperatures which will be explored in this work will be limited to 700°C, which will allows for very different combustor geometry than that which has been studied in the past. While this combustor inlet temperature is lower than that previously studied, when combined with the extremely high pressure, this poses several unique and difficult design challenges. In order to explore these unique design conditions a reliable and robust CFD solution method was developed. This reliable CFD solution methodology enables rapid iteration on various geometries. This paper will explore the CFD modeling setup and the assumptions which were made in the absence of well experimental data in this combustor regime. Exploration of methodology to account for possible variations in chemical kinetics due to the lack of validated kinetic models in the current literature will also be discussed. The results from the CFD runs will be discussed and the combustor design, and next steps to complete a detailed combustor design will also be discussed. This work will enable future work in the development of oxy-fuel combustors for direct fired sCO2 power. This promising technology enables the use of fossil fuels with up to 99% carbon capture, while maintaining an overall cycle efficiency competitive with natural gas combined cycle power plants.


2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Sa’d Shannak ◽  
Artem Malov

Purpose This paper aims to discuss opportunities for pairing the carbon dioxide (CO2) points of supply from stationary sources such as power plants, steel and cement production, coal to liquid plants and refineries, with potential oil reservoirs in China. Design/methodology/approach This study builds a linear optimization model to analyze the tradeoffs in developing CO2-enhance oil recovery (EOR) projects in China for a range of policy options to match points of supply with the points of demand (oil fields). The model works on optimizing CO2 application costs by meeting four principal components; CO2 storage, CO2 capture, transport costs and additional oil recovery. Findings This study reveals new opportunities and economic sources to feed CO2-EOR applications and offers reasonable options to supply CO2 for potential points of demand. Furthermore, power plants and coal to liquid industries had the most significant and economic contributions to potential CO2-EOR projects in China. Total annual emission reduction is expected to be 10% (based on 10 Gton annual emissions). The emission reductions and potential CO2 storage from the different industries as follow; 94% from power plants, 4% from biofuel and 2% from coal to liquid plants. Social implications Carbon capture and storage (CCS) is one practice aiming to reduce the amounts of anthropogenic emissions of carbon dioxide emitted into the atmosphere and reduce the related social costs. However, given the relatively high cost associated with this practice, coupling it with EOR could offer a significant financial incentive to facilitate the development of CCS projects and meet climate change objectives. Originality/value The model used in this study can be straightforwardly adapted to any geographic location where industry and policymakers are looking to simultaneously reduce CO2 emissions while increasing hydrocarbon recovery. The model is highly adaptable to local values in the parameters considered and to include additional local considerations such as geographic variation in capture costs, taxes and premiums to be placed on CO2 capture in so-called “non-attainment zones” where pollution capture make could make a project politically and economically viable. Regardless of how and where this model is applied, it is apparent that CO2 from industrial sources has substantial potential value as a coproduct that offsets its sequestration costs using existing, commercially available CO2-EOR technology, once sources and sinks are optimally paired.


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