Graphical representation of stereochemical configuration (IUPAC Recommendations 2006)

2006 ◽  
Vol 78 (10) ◽  
pp. 1897-1970 ◽  
Author(s):  
Jonathan Brecher
Keyword(s):  
Graphical Representation ◽  
Dimensional Space ◽  
Three Dimensional ◽  
Two Dimensional ◽  
Wide Audience ◽  
Stereochemical Configuration ◽  
Stereogenic Centers ◽  
Relationship Of ◽  
Stereogenic Center ◽  
The Relationship

Stereochemical configuration is determined by the relationship of atoms in three-dimensional space, yet remains most commonly represented in two-dimensional media such as printed publications or computer screens. Recommendations are provided for the display of three-dimensional stereochemical information in two-dimensional diagrams in ways that avoid ambiguity and are likely to be understood correctly by all viewers. Examples are provided for all types of stereochemical configuration, with explanation of which styles are preferred and which should be avoided. Principal recommendations include:Know your audience: Diagrams that have a wide audience should be drawn as simply as possible.Avoid ambiguous drawing styles.Avoid the use of perspective diagrams and class-specific drawing styles (Fischer projections, Haworth projections, etc.) when structures are to be interpreted by computers.Use solid wedges to indicate bonds that project above the plane of the paper and hashed wedges to indicate bonds that project below the plane of the paper; in both cases, the bonds must be oriented with the narrow end at the stereogenic center.Avoid connecting stereogenic centers with a stereobond.

A Research on the Morphology and Composition of Flocs (Part 1: Floc Breaage Disregarded)

2013 ◽  
Vol 726-731 ◽  
pp. 1566-1572 ◽  
Author(s):  
Shi Qiang Ding ◽  
Qing Na Li ◽  
Xin Rong Pang ◽  
Ji Run Xu
Keyword(s):  
Dimensional Space ◽  
Three Dimensional ◽  
New Classification ◽  
Suspension Viscosity ◽  
Primary Particles ◽  
Long Time ◽  
Relationship Of ◽  
The Relationship ◽  
Three Dimensional Space ◽  
Floc Breakage

The characteristics of flocs aggregated in flocculation have been paid more and more attention for a long time. In this paper, a new classification and analyses method dealing with the flocs is developed. The flocs formed after flocculation is divided into four kinds, including the left primary particles, linear flocs with all component particles in a line, planar flocs with all component particles on a plane and volumetric flocs with all component particles in a three-dimensional space. By analyzing the formation approaches of different kind of flocs regardless of the floc breakage, the number of every kind of floc is analyzed to be related with the suspension concentration mathematically. After comparing the different items in the models describing the relationship of floc number and concentration, a series of simplified expressions are presented. Lastly, a mathematical equation relating the measurable suspension viscosity with the numbers of different flocs is obtained.

Relationship of the nanocrystal morphology and atomistic structure with respect to the superstructure ordering within PbS- and Gold-Mesocrystals

2014 ◽  
Vol 1705 ◽  
Author(s):  
Lydia Bahrig ◽  
Danny Haubold ◽  
Falk Röder ◽  
Stephen G. Hickey ◽  
Alexander Eychmüller
Keyword(s):  
Crystal Structure ◽  
Structure Formation ◽  
Three Dimensional ◽  
Two Dimensional ◽  
Relationship Of ◽  
The Relationship ◽  
Atomistic Structure

ABSTRACTThe relationship between nanoparticle geometry and their two dimensional assembly is investigated in order to provide insights into the three dimensional arrangement of mesocrystals. The crystal structure of the nanoparticles and their homogeneity are investigated during structure formation on the mesoscale whereby effects such as fibrillation have been observed.

Three-Dimensional Computed Tomographic Reconstructions of Intracranial Meningiomas

Neurosurgery ◽  
1988 ◽  
Vol 23 (5) ◽  
pp. 570-575 ◽  
Author(s):  
David J. Chalif ◽  
Craig R. Dufresne ◽  
Joseph Ransohoff ◽  
Joseph A. McCarthy
Keyword(s):  
Dimensional Space ◽  
Three Dimensional ◽  
Computer Software ◽  
Computed Tomographic ◽  
Intracranial Meningiomas ◽  
Three Dimensional Images ◽  
Ct Data ◽  
Surgical Adjunct ◽  
Relationship Of ◽  
The Relationship

Abstract In a series of four patients with intracranial meningiomas, three-dimensional computed tomographic (CT) reconstructions were a useful diagnostic and surgical adjunct. Three-dimensional images are created from standard CT data by a boundary-detecting computer software program. Three-dimensional images of tumor invading or adjacent to the bony calvarium are projected about the x, y, and z axes. Axial and sagittal sections delineate the lesions. The images created allow a surgical view of the meningiomas in three-dimensional space and demonstrate the relationship of these masses to the skull. The use of three-dimensional reconstructions in craniofacial surgery and in neurosurgery is reviewed.

scholarly journals Three-Dimensional Thematic Map Imaging of the Yacht Port on the Example of the Polish National Sailing Centre Marina in Gdańsk

2021 ◽  
Vol 11 (15) ◽  
pp. 7016
Author(s):  
Pawel S. Dabrowski ◽  
Cezary Specht ◽  
Mariusz Specht ◽  
Artur Makar
Keyword(s):  
Spatial Data ◽  
Convex Surface ◽  
Dimensional Space ◽  
Three Dimensional ◽  
Future Research ◽  
Two Dimensional ◽  
Thematic Maps ◽  
Research Directions ◽  
Future Research Directions ◽  
The Many

The theory of cartographic projections is a tool which can present the convex surface of the Earth on the plane. Of the many types of maps, thematic maps perform an important function due to the wide possibilities of adapting their content to current needs. The limitation of classic maps is their two-dimensional nature. In the era of rapidly growing methods of mass acquisition of spatial data, the use of flat images is often not enough to reveal the level of complexity of certain objects. In this case, it is necessary to use visualization in three-dimensional space. The motivation to conduct the study was the use of cartographic projections methods, spatial transformations, and the possibilities offered by thematic maps to create thematic three-dimensional map imaging (T3DMI). The authors presented a practical verification of the adopted methodology to create a T3DMI visualization of the marina of the National Sailing Centre of the Gdańsk University of Physical Education and Sport (Poland). The profiled characteristics of the object were used to emphasize the key elements of its function. The results confirmed the increase in the interpretative capabilities of the T3DMI method, relative to classic two-dimensional maps. Additionally, the study suggested future research directions of the presented solution.

“Beholding the Man”: Viewing (or is it Marking?) John’s Trial Scene alongside Kitsch Art

2016 ◽  
Vol 24 (2) ◽  
pp. 245-264
Author(s):  
Andrew P. Wilson
Keyword(s):  
Two Dimensional ◽  
Devotional Art ◽  
The People ◽  
Subject And Object ◽  
Ecce Homo ◽  
Small Stories ◽  
John's Gospel ◽  
Relationship Of ◽  
The Relationship ◽  
Point Of Departure

One of the grand scenes of the Passion narratives can be found in John’s Gospel where Pilate, presenting Jesus to the people, proclaims “Behold the man”: “Ecce Homo.” But what exactly does Pilate mean when he asks the reader to “Behold”? This paper takes as its point of departure a roughly drawn picture of Jesus in the “Ecce Homo” tradition and explores the relationship of this picture to its referent in John’s Gospel, via its capacity as kitsch devotional art. Contemporary scholarship on kitsch focuses on what kitsch does, or how it functions, rather than assessing what it is. From this perspective, when “beholding” is understood not for what it reveals but for what it does, John’s scene takes on a very different significance. It becomes a scene that breaks down traditional divisions between big and small stories, subject and object as well as text and context. A kitsch perspective opens up possibilities for locating John’s narrative in unexpected places and experiences. Rather than being a two-dimensional departure from the grandeur of John’s trial scene, kitsch “art” actually provides a lens through which the themes and dynamics of the narrative can be re-viewed with an expansiveness somewhat lacking from more traditional commentary.


Symbol recognition system based on 3D stereo vision

2020 ◽  
pp. 1-10
Author(s):  
Linlin Wang
Keyword(s):  
Camera Calibration ◽  
Stereo Vision ◽  
Stereo Matching ◽  
Dimensional Space ◽  
Three Dimensional ◽  
Recognition System ◽  
Symbol Recognition ◽  
Two Dimensional ◽  
Measuring Machine ◽  
Left And Right

With the continuous development of computer science and technology, symbol recognition systems may be converted from two-dimensional space to three-dimensional space. Therefore, this article mainly introduces the symbol recognition system based on 3D stereo vision. The three-dimensional image is taken by the visual coordinate measuring machine in two places on the left and right. Perform binocular stereo matching on the edge of the feature points of the two images. A corner detection algorithm combining SUSAN and Harris is used to detect the left and right camera calibration templates. The two-dimensional coordinate points of the object are determined by the image stereo matching module, and the three-dimensional discrete coordinate points of the object space can be obtained according to the transformation relationship between the image coordinates and the actual object coordinates. Then draw the three-dimensional model of the object through the three-dimensional drawing software. Experimental data shows that the logic resources and memory resources occupied by image preprocessing account for 30.4% and 27.4% of the entire system, respectively. The results show that the system can calibrate the internal and external parameters of the camera. In this way, the camera calibration result will be more accurate and the range will be wider. At the same time, it can effectively make up for the shortcomings of traditional modeling techniques to ensure the measurement accuracy of the detection system.

scholarly journals Estimation for Two-Dimensional Nonsymmetric Coherently Distributed Source in L-Shaped Arrays

2018 ◽  
Vol 2018 ◽  
pp. 1-16
Author(s):  
Tao Wu ◽  
Zhenghong Deng ◽  
Qingyue Gu ◽  
Jiwei Xu
Keyword(s):  
Expectation Maximization ◽  
Two Dimensional ◽  
Signal Distribution ◽  
Distributed Source ◽  
One Dimensional ◽  
Least Squares Estimators ◽  
Iterative Calculation ◽  
Symmetric Source ◽  
Relationship Of ◽  
The Relationship

We explore the estimation of a two-dimensional (2D) nonsymmetric coherently distributed (CD) source using L-shaped arrays. Compared with a symmetric source, the modeling and estimation of a nonsymmetric source are more practical. A nonsymmetric CD source is established through modeling the deterministic angular signal distribution function as a summation of Gaussian probability density functions. Parameter estimation of the nonsymmetric distributed source is proposed under an expectation maximization (EM) framework. The proposed EM iterative calculation contains three steps in each cycle. Firstly, the nominal azimuth angles and nominal elevation angles of Gaussian components in the nonsymmetric source are obtained from the relationship of rotational invariance matrices. Then, angular spreads can be solved through one-dimensional (1D) searching based on nominal angles. Finally, the powers of Gaussian components are obtained by solving least-squares estimators. Simulations are conducted to verify the effectiveness of the nonsymmetric CD model and estimation technique.

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