scholarly journals Cobalt(II) Chloride Complex of Propylene-1,3-diamine as CO2 Absorber

2019 ◽  
Vol 32 (1) ◽  
pp. 215-218
Author(s):  
E. Liu ◽  
Fangfang Jian
Keyword(s):  
Co2 Capture ◽  
Room Temperature ◽  
Ambient Pressure ◽  
Analysis Data ◽  
Cobalt Metal ◽  
Performance Study ◽  
Low Concentration ◽  
And Performance ◽  
Co2 Capture Capacity ◽  
Capture Capacity

A new CO2 absorber is reported in this paper. When CoCl3 is mixed with propylenediamine at room temperature and atmospheric ambient pressure, the extremely low concentration of CO2 in the air can be absorbed to form a stable metal complex [Co(PPD)2CO3]Cl·H2O (PPD = 1,3-propylenediamine). The CO2 capture capacity can reach 23.6 wt. %. Although Co is relatively expensive, the practical use of cobalt metal complexes produced still needs to be developed. This study provides an idea of capturing CO2 at low concentration under normal conditions. Through the structural characterization and performance study of complex [Co(PPD)2CO3]Cl·H2O, a new method for CO2 capture was explored. Thermogravimetric analysis data show that the compound [Co(PPD)2CO3]Cl·H2O has the ability to desorption CO2 and H2O at 160-220 ºC, and the ability to adsorb CO2 or regenerate CO2 is being explored. The electrochemical property of compound [Co(PPD)2CO3]Cl·H2O were also investigated.

Morphology and composition controllable synthesis of Mg–Al–CO3 hydrotalcites by tuning the synthesis pH and the CO2 capture capacity

2012 ◽  
Vol 55 ◽  
pp. 18-26 ◽  
Author(s):  
Qiang Wang ◽  
Hui Huang Tay ◽  
Zhanhu Guo ◽  
Luwei Chen ◽  
Yan Liu ◽  
...  
Keyword(s):  
Co2 Capture ◽  
Controllable Synthesis ◽  
Co2 Capture Capacity ◽  
Capture Capacity

Enhanced CO2 Capture Capacity of Nitrogen-Doped Biomass-Derived Porous Carbons

2016 ◽  
Vol 4 (3) ◽  
pp. 1439-1445 ◽  
Author(s):  
Jie Chen ◽  
Jie Yang ◽  
Gengshen Hu ◽  
Xin Hu ◽  
Zhiming Li ◽  
...  
Keyword(s):  
Co2 Capture ◽  
Porous Carbons ◽  
Nitrogen Doped ◽  
Co2 Capture Capacity ◽  
Capture Capacity

scholarly journals Multi-Metals CaMgAl Metal-Organic Framework as CaO-based Sorbent to Achieve Highly CO2 Capture Capacity and Cyclic Performance

Materials ◽  
2020 ◽  
Vol 13 (10) ◽  
pp. 2220 ◽  
Author(s):  
Szu-Chen Wu ◽  
Po-Hsueh Chang ◽  
Chieh-Yen Lin ◽  
Cheng-Hsiung Peng
Keyword(s):  
Metal Ions ◽  
Co2 Capture ◽  
Self Assembly ◽  
Metal Organic Framework ◽  
Hydrothermal Process ◽  
Gravimetric Analysis ◽  
Metal Organic ◽  
Co2 Capture Capacity ◽  
Capture Capacity ◽  
Organic Framework

In this study, Ca-based multi-metals metal-organic framework (CaMgAl-MOF) has been designed as precursor material for carbon dioxide (CO2) capture to enhance the CO2 capture capacity and stability during multiple carbonation-calcination cycles. The CaMgAl-MOFs were constructed from self-assembly of metal ions and organic ligands through hydrothermal process to make metal ions uniformly distributed through the whole structure. Upon heat treatment at 600 °C, the Ca-based multi-metals CaMgAl-MOF would gradually transform to CaO and MgO nanoparticles along with the amorphous aluminum oxide distributed in the CaO matrix. XRD, Fourier transform infrared (FTIR), and SEM were used to identify the structure and characterize the morphology. The CO2 capture capacity and multiple carbonation-calcination cyclic tests of calcined Ca-based metal-organic framework (MOF) (attached with O and indicated as Ca-MOF-O) were performed by thermal gravimetric analysis (TGA). The single metal component calcined Ca-MOF sorbent have the highest CO2 capture capacity up to 72 wt.%, but a lower stability of 61% due to severe particle aggregation. In contrast, a higher Ca-rich MOF oxide sorbent with tailoring the Mg/Al ratios, Ca0.97Mg0.025Al0.005-MOF-O, showed the best performance, not only having the high stability of ~97%, but also maintaining the highest capacity of 71 wt.%. The concept of using Ca-based MOF materials combined with mixed-metal ions for CO2 capture showed a potential route for achieving efficient multiple carbonation-calcination CO2 cycles.

scholarly journals Aluminophosphate monoliths with high CO2-over-N2 selectivity and CO2 capture capacity

RSC Advances ◽  
2014 ◽  
Vol 4 (99) ◽  
pp. 55877-55883 ◽  
Author(s):  
F. Akhtar ◽  
N. Keshavarzi ◽  
D. Shakarova ◽  
O. Cheung ◽  
N. Hedin ◽  
...  
Keyword(s):  
Co2 Capture ◽  
Pulsed Current ◽  
High Co2 ◽  
Binder Free ◽  
Co2 Capture Capacity ◽  
Capture Capacity

Monoliths of microporous aluminophosphates (AlPO4-17 and AlPO4-53) were structured by binder-free pulsed current processing.

scholarly journals Thermal degradation of monoethanolamine and its effect on CO2 capture capacity

2013 ◽  
Vol 17 ◽  
pp. 423-430 ◽  
Author(s):  
Kali-Stella Zoannou ◽  
Devin J. Sapsford ◽  
Anthony J. Griffiths
Keyword(s):  
Thermal Degradation ◽  
Co2 Capture ◽  
Co2 Capture Capacity ◽  
Capture Capacity
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