scholarly journals DETERMINING THE ROLE OF INDIVIDUAL FLY ASH PARTICLES IN INFLUENCING THE VARIATION IN THE OVERALL PHYSICAL, MORPHOLOGICAL, AND CHEMICAL PROPERTIES OF FLY ASH

2016 ◽  
Vol 56 (4) ◽  
pp. 265-282 ◽  
Author(s):  
Usman Haider ◽  
Zdenek Bittnar ◽  
Lubomír Kopecky ◽  
Vít Šmilauer ◽  
Jaroslav Pokorny ◽  
...  
Keyword(s):  
Fly Ash ◽  
Power Plants ◽  
Thermal Power ◽  
Chemical Properties ◽  
Cementitious Materials ◽  
Individual Particle ◽  
Particle Analysis ◽  
Fly Ashes ◽  
Alumino Silicate ◽  
Individual Particles

The properties of fly ashes vary because of the differences in the properties of their individual particles, and the determination of variation in these properties is of interest to the industries which use pulverized raw fly ash in applications, such as in cementitious materials and in the recovery of certain rare elements from raw fly ash. To investigate the differences in individual particles, four pulverized raw fly ashes from thermal power plants of the Czech Republic were used in this research. It was observed from FE-SEM that all four fly ashes consist of glassy hollow spherical, solid spherical, porous spherical, bright spherical, porous slaggy and compact slaggy particles. Box and whisker diagrams were plotted from the data of EDX individual particle analyses, which showed that the data of percentages for the Si, Al, and Fe elements is more scattered as compared to other elements. It was further observed from ternary phase diagrams and pseudo coloured images, that nature of fly ash particles changes from alumino silicate glassy to alumino silicate calcite metallic to pure ferro-metallic,where glassy particles showed high percentages and pure calcite particles were absent in fly ashes. Furthermore, a comparison between the XRF, the EDX total area analyses, showed that the EDX individual particle analysis gives more realistic and reliable data with median, mean, and the standard deviation for percentages of each element present in the fly ashes.

TRACE ELEMENT ANALYSIS OF FLY ASH BY PIXE

1999 ◽  
Vol 09 (03n04) ◽  
pp. 417-422 ◽  
Author(s):  
V. VIJAYAN ◽  
S. N. BEHERA
Keyword(s):  
Fly Ash ◽  
Trace Element ◽  
Power Plants ◽  
Building Materials ◽  
Thermal Power ◽  
Trace Element Analysis ◽  
Chemical Properties ◽  
Solid Material ◽  
Thermal Power Plants ◽  
Element Analysis

Fly ash is a major component of solid material generated by the coal-fired thermal power plants. In India the total amount of fly ash produced per annum is around 100 million tonnes. Fly ash has a great potential for utilization in making industrial products such as cement, bricks as well as building materials, besides being used as a soil conditioner and a provider of micro nutrients in agriculture. However, given the large amount of fly ash that accumulate at thermal power plants, their possible reuse and dispersion and mobilization into the environment of the various elements depend on climate, soils, indigenous vegetation and agriculture practices. Fly ash use in agriculture improved various physico-chemical properties of soil, particularly the water holding capacity, porosity and available plant nutrients. However it is generally apprehended that the application of large quantity of fly ash in fields may affect the plant growth and soil texture. Hence there is a need to characterize trace elements of fly ash. The results of trace element analysis of fly ash and pond ash samples collected from major thermal power plants of India by Particle Induced X-ray Emission (PIXE) have been discussed.

The Suitability of Fly Ash for Use in Concrete According to EN 450 Based on their Particle Size

2018 ◽  
Vol 276 ◽  
pp. 110-115
Author(s):  
Martin Ťažký ◽  
Martin Labaj ◽  
Rudolf Hela
Keyword(s):  
Fly Ash ◽  
Power Plants ◽  
Catalytic Reduction ◽  
Raw Materials ◽  
Thermal Power ◽  
Combustion Process ◽  
Thermal Power Plants ◽  
Mechanical Parameters ◽  
Fly Ashes ◽  
The Impact

The by-products of energy industry are nowadays often affected by new limits governing the production of harmful gases discharged into the air. These stricter and stricter criteria are often met by electricity producers by changing the combustion process in thermal power plants itself. Nowadays, the SNCR (selective non-catalytic reduction) application is quite common in the combustion process in order to help reduce the nitrogen oxide emission. This article deals with the primary measures of thermal power plants, which in particular consist of a modified treatment of raw materials (coal) entering the combustion process. These primary measures then often cause the formation of fly ash with unsuitable fineness for the use in concrete according to EN 450. The paper presents the comparison of the physico-mechanical parameters of several fly ashes with a different fineness values. The primary task is to assess the impact of non-suitable granulometry in terms of EN 450 on the other physico-mechanical parameters of fly ashes sampled within the same thermal power plant. Several fly ashes produced in the Czech Republic and surrounding countries were evaluated in this way.

scholarly journals Separation of Cenospheres from Fly Ashes by Floatation Method

2010 ◽  
Vol 13 (1-2) ◽  
pp. 89 ◽  
Author(s):  
L.M. Manоcha ◽  
K.A. Ram ◽  
S.M. Manocha
Keyword(s):  
Fly Ash ◽  
Power Plants ◽  
Thermal Power ◽  
Ceramic Particle ◽  
Composition Analysis ◽  
High Concentration ◽  
Fly Ashes ◽  
Power Station ◽  
Different Types ◽  
Chemical Composition Analysis

Fly-ashes are non-combustible mineral residues which are produced from coal in thermal power plants. Four different types of fly ashes were collected from different power station in Gujarat. Characterization through SEM shows that fly ash contains cenosphere i.e. gas bubble containing ceramic particle independent of their bulk density. Floatation technique was used for the separation of cenosphere from fly ash. Two solvents with extremely different densities were used for the separation of cenospheres. All methods gave approximately yield of less than 1 % cenosphere in fly ash. Color of cenospheres varied from gray to almost white and the value of density range from 0.4 – 0.8 g/cc. Further, chemical composition analysis revealed that cenospheres do not contain any high concentration of hazardous elements.

scholarly journals Stabilization of Indian Fly Ashes with Soils, Cement, and Randomly Oriented Fibers

2012 ◽  
Vol 3 ◽  
pp. 1-8
Author(s):  
Shenbaga R. Kaniraj ◽  
V. Gayathri ◽  
V.G. Havanagi
Keyword(s):  
Fly Ash ◽  
Power Plants ◽  
Thermal Power ◽  
Experimental Studies ◽  
Fly Ashes ◽  
Strength Criteria ◽  
Permeability Characteristics ◽  
Polyester Fibers ◽  
Soil Mixtures ◽  
Pavement Base

 Experimental studies were carried out on fly ashes from two Indian thermal power plants, namely Rajghat and Dadri, with the aim of improving the utilization of fly ash in geotechnical engineering applications. It was attempted to improve the engineering performance of fly ash by several means such as by mixing fly ash with soils, cement, and polyester fibers. The research program included the study of: a) physical properties, chemical composition and morphology of the fly ashes; b) compaction, strength, and permeability characteristics of the fly ashes and fly ash-soil mixtures; c) compaction and strength characteristics of fly ash-soil mixtures stabilized with fibers alone, with cement alone, and with both cement and fibers. Results showed that addition of fly ash to soils would result in lighter and stronger fills. Fiber inclusions increased the strength of fly ash-soil specimens significantly and altered their behaviour from brittle to ductile. Even small cement contents increased the strength of the fly ash-soil mixtures significantly. With higher cement contents of up to 18% it was possible to prepare fly ash-cement design mixes that satisfied the strength criteria for pavement base courses.

scholarly journals Influence of Activators on Mechanical Properties of Modified Fly Ash Based Geopolymer Mortars

Materials ◽  
2020 ◽  
Vol 13 (5) ◽  
pp. 1033 ◽  
Author(s):  
Piotr Prochon ◽  
Zengfeng Zhao ◽  
Luc Courard ◽  
Tomasz Piotrowski ◽  
Frédéric Michel ◽  
...  
Keyword(s):  
Fly Ash ◽  
Power Plants ◽  
Thermal Power ◽  
Biomass Combustion ◽  
Fly Ashes ◽  
Binding Properties ◽  
Alkali Activated ◽  
Modified Fly Ash ◽  
Scanning Electron ◽  
And Calorimetry

The aim of this work was to study the influence of the type of activator on the formulation of modified fly ash based geopolymer mortars. Geopolymer and alkali-activated materials (AAM) were made from fly ashes derived from coal and biomass combustion in thermal power plants. Basic activators (NaOH, CaO, and Na2SiO3) were mixed with fly ashes in order to develop binding properties other than those resulting from the use of Portland cement. The results showed that the mortars with 5 mol/dm3 of NaOH and 100 g of Na2SiO3 (N5-S22) gave a greater compressive strength than other mixes. The compressive strengths of analyzed fly ash mortars with activators N5-S22 and N5-C10 (5 mol/dm3 NaOH and 10% CaO) varied from 14.3 MPa to 5.9 MPa. The better properties of alkali-activated mortars with regular fly ash were influenced by a larger amount of amorphous silica and alumina phases. Scanning electron microscopy and calorimetry analysis provided a better understanding of the observed mechanisms.

Fly Ash-Based Geopolymer: Green Material in Carbon-Constrained Society

2021 ◽  
Vol 321 ◽  
pp. 65-71
Author(s):  
Hoc Thang Nguyen ◽  
Phong Thanh Dang
Keyword(s):  
Fly Ash ◽  
Power Plants ◽  
Thermal Power ◽  
Bottom Ash ◽  
Coal Ash ◽  
Raw Material ◽  
Engineering Properties ◽  
Gravimetric Analysis ◽  
Green Materials ◽  
Alumino Silicate

Climate change is recognized as a global problem and even the industrial and construction sectors are trying to reduce the green-house gas emissions, especially on CO2 emissions. In Vietnam, the coal-fired thermal power plants are discharging millions of tons of CO2 and coal ash annually. This coal ash is comprised of about 80% of fly ash and the rest is bottom ash. This study would like to introduce one of the potential solutions in a carbon-constrained society that would not only manage the fly ash but also utilized this as raw material for green materials through geopolymerization. The geopolymer-based material has lower energy consumption, minimal CO2 emissions and lower production cost as it valorizes industrial waste. The fly ash containing high alumino-silicate resources from a coal-fired power plant in Vietnam was mixed with sodium silicate and sodium hydroxide solutions to obtain the geopolymeric pastes. The pastes were molded in 10x10x20cm molds and then cured at room temperature for 28 days. The 28-day geopolymer specimens were carried out to test for engineering properties such as compressive strength (MPa), volumetric weight (kg/m3), and water absorption (kg/m3). The microstructure analysis was also conducted for this eco-friendly materials using X ray diffraction (XRD), and Fourier Transform Infrared Spectroscopy (FTIR), Scanning Electron Microscope (SEM), Differential Thermal Analysis - Thermal Gravimetric Analysis (DTA-TGA).

scholarly journals Leachability of Heavy Metals from Autoclaved Fly Ash-Lime Building Bricks

2021 ◽  
Vol 1 (1) ◽  
Author(s):  
Mehmet TANRIVERDI ◽  
Gül Akar ŞEN ◽  
Tayfun ÇIÇEK ◽  
Sezai ŞEN ◽  
Öznur ÖNEL
Keyword(s):  
Trace Elements ◽  
Fly Ash ◽  
Environmental Effect ◽  
Power Plants ◽  
Thermal Power ◽  
Leaching Tests ◽  
Application Area ◽  
Fly Ashes ◽  
Ecological Problems

The fly ash as a byproduct of coal-fired power plants constitutes vital ecological problems. In Turkey, approximately 15 million tons ofashes are generated via the combustion of 40 million tons of lignite yearly. Worldwide, a number of investigation and applications wereundertaken to utilize fly ash in order to overcome the environmental problems. One of the application area of fly ashes is the production of building bricks. Characterization of fly ash samples from Seyitomer and Yatagan coal-firing power plants were conducted inthis study. TCLP 1311, ASTM3987-85 and EN 12457-2 leaching tests on the cylindrical fly ash/lime brick (FA/LB) samples which wereproduced from Seyitömer and Yatagan thermal power plant fly ash-lime mixtures were performed to determine the leachability ofsome chosen trace elements. The results show that the release of all trace elements was lower than the hazardous material limit valuesof waste acceptance. Thus, non- fired fly ash bricks are an advantageous way to solving environmental effect of disposal of fly ashes.

Variability and Trends in Iowa Fly Ashes

1986 ◽  
Vol 86 ◽  
Author(s):  
Scott Schlorholtz ◽  
Ken Bergeson ◽  
Turgut Demirel
Keyword(s):  
Fly Ash ◽  
Chemical Composition ◽  
Power Plant ◽  
Coefficient Of Variation ◽  
Power Plants ◽  
Chemical Properties ◽  
Physical Analysis ◽  
Fly Ashes ◽  
High Calcium ◽  
Physical And Chemical

ABSTRACTAn investigation has been made of the variability of physical and chemical properties of high-calcium (Class C) fly ashes from four Iowa power plants. The investigation summarizes results obtained from three years (1983 through 1985) of monitoring of the various power plants. All four of the power plants burn low-sulfur, sub-bituminous coal from Wyoming. Fly ash samples were obtained from the power plants in accordance to the procedures described in ASTM C 311. Laboratory testing methods were similar to those specified by ASTM C 311. During the three year period, 102 samples were subjected to chemical and physical analysis while an additional 349 samples were subjected to physical analysis only. In general, the four power plants produce fly ashes of similar mineralogy and chemical composition. The observed time variation of the chemical composition of fly ash from a single power plant was quite small. The sulfur content consistently showed the largest coefficient of variation of the 10 elements studied. Physical characteristics of the fly ashes (as measured by ASTM tests) were also fairly uniform over long periods of time, when considered on an individual power plant basis. Fineness, when measured by wet washing using a 325 mesh sieve, consistently exhibited the largest coefficient of variation of any of the physical properties studied.

A Review on Utilization of Fly- Ash and Pond-Ash as a Partial Replacement of Cement in Concrete Mix Design

2018 ◽  
pp. 413-418
Author(s):  
Harshkumar Patel ◽  
Yogesh Patel
Keyword(s):  
Fly Ash ◽  
Electricity Generation ◽  
Power Plants ◽  
Renewable Energy Sources ◽  
Thermal Power ◽  
Strength Test ◽  
Partial Replacement ◽  
Pond Ash ◽  
Research Activities ◽  
Ash Disposal

Now-a-days energy planners are aiming to increase the use of renewable energy sources and nuclear to meet the electricity generation. But till now coal-based power plants are the major source of electricity generation. Disadvantages of coal-based thermal power plants is disposal problem of fly ash and pond ash. It was earlier considered as a total waste and environmental hazard thus its use was limited, but now its useful properties have been known as raw material for various application in construction field. Fly ash from the thermal plants is available in large quantities in fine and coarse form. Fine fly ash is used in construction industry in some amount and coarse fly ash is subsequently disposed over land in slurry forms. In India around 180 MT fly is produced and only around 45% of that is being utilized in different sectors. Balance fly ash is being disposed over land. It needs one acre of land for ash disposal to produce 1MW electricity from coal. Fly ash and pond ash utilization helps to reduce the consumption of natural resources. The fly ash became available in coal based thermal power station in the year 1930 in USA. For its gainful utilization, scientist started research activities and in the year 1937, R.E. Davis and his associates at university of California published research details on use of fly ash in cement concrete. This research had laid foundation for its specification, testing & usages. This study reports the potential use of pond-ash and fly-ash as cement in concrete mixes. In this present study of concrete produced using fly ash, pond ash and OPC 53 grade will be carried. An attempt will be made to investigate characteristics of OPC concrete with combined fly ash and pond ash mixed concrete for Compressive Strength test, Split Tensile Strength test, Flexural Strength test and Durability tests. This paper deals with the review of literature for fly-ash and pond-ash as partial replacement of cement in concrete.

scholarly journals Preparation of Synthetic Zeolites from Coal Fly Ash by Hydrothermal Synthesis

Materials ◽  
2021 ◽  
Vol 14 (5) ◽  
pp. 1267
Author(s):  
David Längauer ◽  
Vladimír Čablík ◽  
Slavomír Hredzák ◽  
Anton Zubrik ◽  
Marek Matik ◽  
...  
Keyword(s):  
Fly Ash ◽  
Coal Combustion ◽  
Power Plants ◽  
Coal Fly Ash ◽  
Thermal Power ◽  
Product Analysis ◽  
Coal Combustion Products ◽  
X Ray ◽  
Wide Range ◽  
Silica Alumina

Large amounts of coal combustion products (as solid products of thermal power plants) with different chemical and physical properties cause serious environmental problems. Even though coal fly ash is a coal combustion product, it has a wide range of applications (e.g., in construction, metallurgy, chemical production, reclamation etc.). One of its potential uses is in zeolitization to obtain a higher added value of the product. The aim of this paper is to produce a material with sufficient textural properties used, for example, for environmental purposes (an adsorbent) and/or storage material. In practice, the coal fly ash (No. 1 and No. 2) from Czech power plants was firstly characterized in detail (X-ray diffraction (XRD), X-ray fluorescence (XRF), scanning electron microscopy with energy dispersive X-ray analysis (SEM-EDX), particle size measurement, and textural analysis), and then it was hydrothermally treated to synthetize zeolites. Different concentrations of NaOH, LiCl, Al2O3, and aqueous glass; different temperature effects (90–120 °C); and different process lengths (6–48 h) were studied. Furthermore, most of the experiments were supplemented with a crystallization phase that was run for 16 h at 50 °C. After qualitative product analysis (SEM-EDX, XRD, and textural analytics), quantitative XRD evaluation with an internal standard was used for zeolitization process evaluation. Sodalite (SOD), phillipsite (PHI), chabazite (CHA), faujasite-Na (FAU-Na), and faujasite-Ca (FAU-Ca) were obtained as the zeolite phases. The content of these zeolite phases ranged from 2.09 to 43.79%. The best conditions for the zeolite phase formation were as follows: 4 M NaOH, 4 mL 10% LiCl, liquid/solid ratio of 30:1, silica/alumina ratio change from 2:1 to 1:1, temperature of 120 °C, process time of 24 h, and a crystallization phase for 16 h at 50 °C.

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