Experimental and Numerical Investigations of Thermal Ignition of a Phase Changing Energetic Material

2016 ◽  
Vol 66 (3) ◽  
pp. 228
Author(s):  
Priyanka Shukla ◽  
M. Deepu
Keyword(s):  
Energetic Materials ◽  
Numerical Study ◽  
Energetic Material ◽  
Transient Heat Conduction ◽  
Thermal Ignition ◽  
Explosive Material ◽  
Field Function ◽  
Precise Control ◽  
Numerical Investigations ◽  
Commercial Solver

Fortuitous exposure to high temperatures initiates reaction in energetic materials and possibilities of such event are of great concern in terms of the safe and controlled usage of explosive devices. Experimental and numerical investigations on time to explosion and location of ignition of a phase changing polymer bonded explosive material (80 per cent RDX and 20 per cent binder), contained in a metallic confinement subjected to controlled temperature build-up on its surface, are presented. An experimental setup was developed in which the polymer bonded explosive material filled in a cylindrical confinement was provided with a precise control of surface heating rate. Temperature at various radial locations was monitored till ignition. A computational model for solving two dimensional unsteady heat transfer with phase change and heat generation due to multi-step chemical reaction was developed. This model was implemented using a custom field function in the framework of a finite volume method based standard commercial solver. Numerical study could simulate the transient heat conduction, the melting pattern of the explosive within the charge and also the thermal runaway. Computed values of temperature evolution at various radial locations and the time to ignition were closely agreeing with those measured in experiment. Results are helpful both in predicting the possibility of thermal ignition during accidents as well as for the design of safety systems.

Introduction of the acylamino group to bridged bis(nitroamino-1,2,4-triazole): a strategy for tuning the sensitivity of energetic materials

2021 ◽  
Vol 45 (38) ◽  
pp. 18059-18064
Author(s):  
Dongxu Chen ◽  
Jiangshan Zhao ◽  
Hongwei Yang ◽  
Hao Gu ◽  
Guangbin Cheng
Keyword(s):  
Energetic Materials ◽  
Energetic Material

Introduction of the acylamino group into energetic material compounds will contribute to balancing the sensitivity and the energy.

Numerical Study on Control of Sunroof Buffeting

2021 ◽  
Vol 13 (2) ◽  
Author(s):  
K. Vijaykumar ◽  
S. Poonkodi ◽  
A.T. Sriram
Keyword(s):  
Numerical Study ◽  
Leading Edge ◽  
Dominant Frequency ◽  
Navier Stokes ◽  
Navier Stokes Equation ◽  
Ansys Fluent ◽  
Flow Modification ◽  
Numerical Result ◽  
Modification Technique ◽  
Commercial Solver

Sunroof has become one of the essential features of a luxury car, and it provides natural air circulation and good illumination into the car. But the primary problem associated with it is the buffeting noise which causes discomfort to the passengers. Though adequate studies were carried out on sunroof buffeting, efficient control techniques are needed to be developed from fundamental mechanism. To reduce the buffeting noise, flow modifications at the entrance of the sunroof is considered in this study. The internal portion of the car with sunroof is simplified into a shear driven open cavity, and two-dimensional numerical simulations are carried out using commercial solver, ANSYS Fluent. Reynolds averaged Navier-Stokes equation is used with the realizable k-? turbulence model. The unsteady numerical result obtained in this study is validated with the available experimental results for the dominant frequency. The prediction is good agreement with experiment. Flow modification technique is proposed to control the sunroof buffeting by implementing geometric modifications. A hump has been placed near the leading edge of the cavity which resulted in significant reduction of pressure oscillations. Parametric studies have been performed by varying the height of hump and the distance of hump from the leading edge. There is no prominent difference when the height of the hump is varied. As the distance of the hump from the leading edge is reduced, the sound pressure level decreases.

Experimental and Numerical Study of Mixing in a Hot-Water Storage Tank

2009 ◽  
Vol 131 (1) ◽  
Author(s):  
A. Aviv ◽  
Y. Blyakhman ◽  
O. Beeri ◽  
G. Ziskind ◽  
R. Letan
Keyword(s):  
Numerical Model ◽  
Storage Tank ◽  
Numerical Study ◽  
Tap Water ◽  
Three Dimensional ◽  
Hot Water ◽  
Software Validation ◽  
Water Storage Tank ◽  
Thermal Mixing ◽  
Numerical Investigations

Thermal mixing and stratification are explored numerically and experimentally in a cylindrical tank, which simulates a storage of water heated by a solar collector. The tank is 70cm in height and 24cm in diameter. The inlet and outlet are vertical and located off the centerline of the tank. The study is conducted in a transient mode, namely, the tank is filled with hot water, and as the hot water is being withdrawn, the tap water replaces it in a stratified way or by mixing. The flowrates of 2l∕min, 3l∕min, 5l∕min and 7l∕min, which correspond to superficial velocities of 4.35cm∕min, 6.52cm∕min, 10.87cm∕min, and 15.2cm∕min, are explored. Temperature of hot water ranges within 40–50°C, while the tap water is about 25–27°C. Installation of one and two horizontal baffles above the inlet is examined. Simultaneous experimental and numerical investigations are performed. In the experiment, both flow visualization and temperature measurements are used. Three-dimensional transient numerical simulations are done using the FLUENT 6 software. Validation of the numerical model is achieved by comparison with the experimental results. Then, the numerical model is applied to a study of various possible changes in the system. The results show that at low flowrates, up to a superficial velocity of about 11cm∕min through the tank, the baffles have no effect on tap water mixing with the stored hot water. At higher flowrates, a single horizontal baffle prevents the mixing and preserves the desired stratified temperature distribution in the storage tank.

Achieving tunable chemical reactivity through photo-initiation of energetic materials at metal oxide surfaces

2020 ◽  
Vol 22 (43) ◽  
pp. 25284-25296
Author(s):  
Maija M. Kuklja ◽  
Roman Tsyshevsky ◽  
Anton S. Zverev ◽  
Anatoly Mitrofanov ◽  
Natalya Ilyakova ◽  
...  
Keyword(s):  
Metal Oxide ◽  
Chemical Reactions ◽  
Energetic Materials ◽  
Chemical Reactivity ◽  
Energetic Material ◽  
Oxide Surfaces ◽  
Oxide Interfaces ◽  
Metal Oxide Surfaces

Photo-stimulated chemical reactions in energetic materials can be highly controlled by selectively designing energetic material – metal oxide interfaces with tailored properties.

Solidification Heat Transfer and Base Separation Analysis in the Casting of an Energetic Material in a Projectile

2005 ◽  
Author(s):  
Dawei Sun ◽  
S. Ravi Annapragada ◽  
Suresh V. Garimella ◽  
Sanjeev Sing
Keyword(s):  
Heat Transfer ◽  
Finite Element ◽  
Numerical Model ◽  
Residual Stresses ◽  
Energetic Materials ◽  
Energetic Material ◽  
Complex Geometries ◽  
Experimental Measurements ◽  
Linear Temperature ◽  
High Prandtl Number

This paper investigates the problem of base separation in the casting of energetic materials in a projectile. Special challenges that arise in casting high Prandtl number energetic materials in projectiles of complex geometries are addressed. A comprehensive numerical model is developed by integrating finite volume and finite element methods to analyze the thermal and flow fields as well as the residual stresses. The predictions, which are confirmed by experimental measurements, suggest that sustenance of a linear temperature profile along the projectile axis can eliminate base separation, and also reduce residual stresses in the final casting.

scholarly journals Nanostructured Energetic Materials with Sol-gel Methods

2003 ◽  
Vol 800 ◽  
Author(s):  
Alexander E. Gash ◽  
Joe H. Satcher ◽  
Randall L. Simpson ◽  
Brady J. Clapsaddle
Keyword(s):  
Thermal Properties ◽  
Energetic Materials ◽  
Energetic Material ◽  
Sol Gel ◽  
Small Scale ◽  
Fine Grained ◽  
Electron Microscopies ◽  
Burn Rate ◽  
Scanning Electron

AbstractThe utilization of sol-gel chemical methodology to prepare nanostructured energetic materials as well as the concepts of nanoenergetics is described. The preparation and characterization of two totally different compositions is detailed. In one example, nanostructured aerogel and xerogel composites of sol-gel iron (III) oxide and ultra fine grained aluminum (UFG Al) are prepared, characterized, and compared to a conventional micron-sized Fe2O3/Al thermite. The exquisite degree of mixing and intimate nanostructuring of this material is illustrated using transmission and scanning electron microscopies (TEM and SEM). The nanocomposite material has markedly different energy release (burn rate) and thermal properties compared to the conventional composite, results of which will be discussed. Small-scale safety characterization was performed on the nanostructured thermite. The second nanostructured energetic material consists of a nanostructured hydrocarbon resin fuel network with fine ammonium perchlorate (NH4ClO4) oxidizer present.

Kinetic Compensation Effect of Kinetic Parameters of Thermal Explosion Test

2012 ◽  
Vol 184-185 ◽  
pp. 1408-1417
Author(s):  
Ying Hui Shao ◽  
Zi Ru Liu ◽  
Xiao Ning Ren ◽  
Shu Yun Heng ◽  
Pu Yue ◽  
...  
Keyword(s):  
Kinetic Parameters ◽  
Thermal Explosion ◽  
Energetic Materials ◽  
Compensation Effect ◽  
Energetic Material ◽  
Regression Equation ◽  
Kinetic Temperature ◽  
Single Compound ◽  
Main Component ◽  
Explosion Test

The kinetic parameters of thermal explosion tests with five-second delay for 273 energetic materials were analyzed. The compensation effect exists between the two thermal explosion kinetic parameters of these energetic materials, e.g. lnA and Eb. The kinetic parameters of these energetic materials can be expressed by a single linear regression equation for the single compound or mixture under all conditions. The slopes of the regression equation for various systems are in the range from 0.1952 to 0.2413 (mol•kJ-1). The regression equation for single compound or mixture with one type of energetic material as main component has better linearity. Therefore, their “iso-kinetic temperature” Tik is close to their thermal explosion temperature Tb and the “iso-kinetic delay period”τik is also close to the 5 seconds.

Molecular Composition, Structure, and Sensitivity of Explosives

1992 ◽  
Vol 296 ◽  
Author(s):  
Carlyle B. Storm ◽  
James R. Travis
Keyword(s):  
Molecular Structure ◽  
Hot Spots ◽  
Energetic Materials ◽  
Physical State ◽  
Hot Spot ◽  
Energetic Material ◽  
Specific Situation ◽  
Reaction Products ◽  
Ambient Conditions ◽  
Delayed Reaction

AbstractHigh explosives, blasting agents, propellants, and pyrotechnics are all metastable relative to reaction products and are termed energetic materials. They are thermodynamically unstable but the kinetics of decomposition at ambient conditions are sufficiently slow that they can be handled safely under controlled conditions. The ease with which an energetic material can be caused to undergo a violent reaction or detonation is called its sensitivity. Sensitivity tests for energetic materials are aimed at defining the response of the material to a specific situation, usually prompt shock initiation or a delayed reaction in an accident. The observed response is always due to a combination of the physical state and the molecular structure of the material. Modeling of any initiation process must consider both factors. The physical state of the material determines how and where the energy is deposited in the material. The molecular structure in the solid state determines the mechanism of decomposition of the material and the rate of energy release. Slower inherent reaction chemistry leads to longer reaction zones in detonation and inherently safer materials. Slower chemistry also requires hot spots involved in initiation to be hotter and to survive for longer periods of time. High thermal conductivity also leads to quenching of small hot spots and makes a material more difficult to initiate. Early endothermic decomposition chemistry also delays initiation by delaying heat release to support hot spot growth. The growth to violent reaction or detonation also depends on the nature of the early reaction products. If chemical intermediates are produced that drive further accelerating autocatalytic decomposition the initiation will grow rapidly to a violent reaction.

Energetic materials: α-NTO crystallizes as a four-component triclinic twin

2005 ◽  
Vol 61 (5) ◽  
pp. 577-584 ◽  
Author(s):  
Nadezhda Bolotina ◽  
Kristin Kirschbaum ◽  
A. Alan Pinkerton
Keyword(s):  
Energetic Materials ◽  
Crystal Packing ◽  
Energetic Material ◽  
Data Sets ◽  
Flat Chain ◽  
Planar Molecules ◽  
Triclinic Unit Cell ◽  
Symmetry Space ◽  
Symmetry Space Group ◽  
Additional Hydrogen

The prevalent polymorph of the energetic material 5-nitro-2,4-dihydro-1,2,4,-triazol-3-one, α-NTO, crystallizes as a four-component twin with triclinic symmetry (space group P\bar 1). All crystals under investigation were fourlings, i.e. they contained each of the four possible twin components. Complete data sets were collected for two crystals, one with a predominant amount of one individual component (55%) and one with approximately equal volumes of each component. In both cases the fourling components are related by the twofold axes inherent in the holohedral symmetry of a pseudo-orthorhombic superlattice with a o = a t , b o = b t and c o = a t + b t + 2c t . The triclinic unit cell contains four crystallographically independent planar molecules in the asymmetric unit, each of which forms a hydrogen-bonded flat chain parallel to a t . Pairs of chains are combined into planar ribbons by additional hydrogen bonds. Thus, two independent ribbons extend parallel to a t , creating a dihedral angle of ∼ 70°. The origin of the twinning is derived from consideration of the crystal packing and the hydrogen-bonding scheme.

The thermochemistry and reaction pathways of energetic material decomposition and combustion

1992 ◽  
Vol 339 (1654) ◽  
pp. 365-376 ◽  
Keyword(s):  
Condensed Phase ◽  
Energetic Materials ◽  
Energetic Material ◽  
Theoretical Method ◽  
Chemical Processes ◽  
Reaction Pathways ◽  
Quantum Chemical Methods ◽  
Solvation Energies ◽  
Moller Plesset ◽  
Ignition And Combustion

The chemical processes involved in the decomposition and combustion of energetic materials have been investigated theoretically using quantum chemical methods to determine the thermochemistry and reaction pathways. The Bond-Additivity-Corrected Moller-Plesset fourth-order perturbation theory method (BAC-MP4) has been used to determine heats of formation and free energies of reaction intermediates of decomposition and combustion. In addition, the BAC-MP4 method has been used to determine reaction pathways involving these intermediates. A theoretical method for calculating solvation energies has been developed to treat the non-idealities of high pressure and the condensed phase. The resulting chemical processes involving decomposition, ignition and combustion are presented for nitramines and nitromethane. Differences in decomposition mechanisms for the condensed phase and gas phase are discussed. In addition, we discuss the effects that amines can have on the initial stages of condensed-phase nitromethane decomposition. Bond dissociation energies for nitro-triazoles are compared with those of other nitro compounds.

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