The Preparation Approaches of Polymer/graphene Nanocomposites and their Appilcation Research Progress as Electrochemical Sensors

2017 ◽  
Vol 20 (4) ◽  
pp. 205-221 ◽  
Author(s):  
Weifeng Chen ◽  
Shaona Chen ◽  
Weimin Hu ◽  
Dejiang Li ◽  
Zhongxu Dai
Keyword(s):  
Electrochemical Sensors ◽  
Synergetic Effect ◽  
Research Progress ◽  
Honeycomb Lattice ◽  
Electrochemical Performances ◽  
Preparation Methods ◽  
Graphene Nanocomposites ◽  
Advantages And Disadvantages ◽  
Solution Blending

Graphene, a two-dimensional sheet of sp2-hybridized carbon atoms packed into a honeycomb lattice, can be combined with various polymers through different methods and techniques. Polymer/graphene nanocomposites are expected to not only preserve the fa-vorable properties of graphene and polymers, but also greatly enhance the intrinsic properties due to the synergetic effect between them. In this review, the preparation approaches of graphene/polymer nanocomposites, including melt blending, solution blending, in-situ polymeri-zation and in-situ synthesis, were presented comprehensively in order to study the relationship between these approaches and the final characteristics and performances. Each approach had different influences on the final properties of the nanocomposites. The advantages and disadvantages of the preparation methods were discussed respectively. Additionally, the application researches of the polymer/graphene nanocomposites as electrochemical sensors, were introduced in detail. With regard to some important or novel sensors, the mechanisms were proposed for reference. Finally, conclusions were given and the issues waiting to be settled for further development were pointed out. The current review demonstrates that polymer/graphene nanocomposites exhibit superior electrochemical performances and will be applied practically in the field of sensor devices.

scholarly journals A critical review on the development and performance of polymer/graphene nanocomposites

2018 ◽  
Vol 25 (6) ◽  
pp. 1059-1073 ◽  
Author(s):  
Weifeng Chen ◽  
Hu Weimin ◽  
Dejiang Li ◽  
Shaona Chen ◽  
Zhongxu Dai
Keyword(s):  
Polymer Nanocomposites ◽  
Electronic Conductivity ◽  
Future Research ◽  
Preparation Methods ◽  
Graphene Nanocomposites ◽  
Advantages And Disadvantages ◽  
Solution Blending ◽  
Potential Applications ◽  
New Type ◽  
And Performance

AbstractGraphene (graphene) is a new type of two-dimensional inorganic nanomaterial developed in recent years. It can be used as an ideal inorganic nanofiller for the preparation of polymer nanocomposites because of its high mechanical strength, excellent electrical conductivity and plentiful availability (from graphite). In this review, the preparation methods of graphene/polymer nanocomposites, including solution blending, melt blending and in situ polymerization, are introduced in order to study the relationship between these methods and the final characteristics and properties. Each method has an influence on the final characteristics and properties of the nanocomposites. The advantages and disadvantages of these methods are discussed. In addition, a variety of nanocomposites with different properties, such as mechanical properties, electronic conductivity, thermal conductivity and thermal properties, are summarized comprehensively. The potential applications of these nanocomposites in conductive materials, electromagnetic shielding materials, photocatalytic materials and so on, are briefly presented. This review demonstrates that polymer/graphene nanocomposites exhibit superior comprehensive performance and will be applied in the fields of new materials and novel devices. Future research directions of the nanocomposites are also presented.

scholarly journals Research Progress of NiMn Layered Double Hydroxides for Supercapacitors: A Review

Nanomaterials ◽  
2018 ◽  
Vol 8 (10) ◽  
pp. 747 ◽  
Author(s):  
Ai-Lan Yan ◽  
Xin-Chang Wang ◽  
Ji-Peng Cheng
Keyword(s):  
Layered Double Hydroxides ◽  
Electrode Materials ◽  
Low Cost ◽  
Specific Capacity ◽  
Research Progress ◽  
Electrochemical Performances ◽  
Preparation Methods ◽  
Large Power ◽  
Supercapacitor Application ◽  
Double Hydroxides

The research on supercapacitors has been attractive due to their large power density, fast charge/discharge speed and long lifespan. The electrode materials for supercapacitors are thus intensively investigated to improve the electrochemical performances. Various transition metal layered double hydroxides (LDHs) with a hydrotalcite-like structure have been developed to be promising electrode materials. Earth-abundant metal hydroxides are very suitable electrode materials due to the low cost and high specific capacity. This is a review paper on NiMn LDHs for supercapacitor application. We focus particularly on the recent published papers using NiMn LDHs as electrode materials for supercapacitors. The preparation methods for NiMn LDHs are introduced first. Then, the structural design and chemical modification of NiMn LDH materials, as well as the composites and films derived from NiMn LDHs are discussed. These approaches are proven to be effective to enhance the performance of supercapacitor. Finally, the reports related to NiMn LDH-based asymmetric supercapacitors are summarized. A brief discussion of the future development of NiMn LDHs is also provided.

Research progress over Cu2O/n-type semiconductor composites in photocatalysis

2021 ◽  
Vol 02 ◽  
Author(s):  
Yonghui Zhang ◽  
Yatong Shi ◽  
Shiyu Xie ◽  
Mingming Liu ◽  
Junli Chen ◽  
...  
Keyword(s):  
Catalytic Mechanism ◽  
Low Cost ◽  
Co2 Reduction ◽  
Research Progress ◽  
Environmental Friendliness ◽  
Preparation Methods ◽  
Photocatalytic Application ◽  
Narrow Bandgap ◽  
Type Semiconductor

: Photocatalysis is a feasible technology to solve energy shortage and environmental pollution by using solar energy. Semiconductor photocatalysts with low cost, high stability and environmental friendliness are demonstrated advantages for the production of solar fuel, CO2 reduction, and degradation of pollutants. Among them, Cu2O presents numerous potential for photocatalysis because of its narrow bandgap and high activity under visible light. However, the rapid recombination of photoinduced electron-hole pairs and the instability of Cu2O under light irradiation limit its photocatalytic performance. In order to solve the above issues, researchers prefer to incorporate Cu2O with n-type semiconductors to design p-n heterojunction composites, thus regulating the band structure, promoting the separation and transfer of electrons and holes, and accelerating the redox reaction onto the surface. In this manuscript, the preparation methods of Cu2O/n-type semiconductor composites such as hydrothermal method, electrodeposition method, and in situ method are concluded, the photocatalytic applications including CO2 reduction, hydrogen production, and degradation are presented, and the catalytic mechanism like Z-scheme, p-n heterojunction, etc. are discussed, respectively. This review also proposes that there are still challenges in broadening the photocatalytic application of Cu2O/n-type semiconductor composites.

Research Progress on Preparation of SiC/Al for Electronic Packaging by Liquid Infiltration

2021 ◽  
Vol 1035 ◽  
pp. 906-917
Author(s):  
Meng Qin Chen ◽  
Yue Long Bai ◽  
Zhi Feng Zhang
Keyword(s):  
Electronic Packaging ◽  
Volume Fraction ◽  
High Volume ◽  
Development Trend ◽  
Research Progress ◽  
Preparation Methods ◽  
Advantages And Disadvantages ◽  
Liquid Infiltration ◽  
Al Composite ◽  
The Development Trend

High volume fraction SiC/Al composite material, with its excellent thermal properties and flexible preparation process, has been widely used in the field of electronic packaging. In the paprer, the development of SiC/Al materials for electronic packaging and their preparation methods are reviewed. The preparation processes for preparing SiC/Al by liquid infiltration are mainly introduced. The advantages and disadvantages of several important processes are analyzed. Finally, the development trend of SiC/Al for electronic packaging prepared by liquid infiltration is prospected.

scholarly journals In situ syntheses of semiconducting nanoparticles in conjugated polymer matrices and their application in photovoltaics.

2014 ◽  
Vol 1 (1) ◽  
Author(s):  
Thomas Rath ◽  
Gregor Trimmel
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Conjugated Polymers ◽  
Conjugated Polymer ◽  
Hybrid Solar Cells ◽  
Preparation Methods ◽  
Solar Cell Performance ◽  
Semiconducting Nanoparticles ◽  
Advantages And Disadvantages

AbstractHybrid solar cells based on conjugated polymers and inorganic semiconducting nanoparticles combine beneficial properties of organic and inorganic semiconductors and are, therefore, an exciting alternative to pure organic or inorganic solar cell technologies. Several approaches for the fabrication of hybrid solar cells are already elaborated and explored. In the last years routes have emerged, where the nanoparticles are prepared directly in the matrix of the conjugated polymer. Here, the conjugated polymer prevents the nanoparticles from excessive growth and thereby makes additional capping agents obsolete. This review focuses on in situ preparation methods of inorganic semiconducting nanoparticles in conjugated polymers in view of applications in hybrid solar cells. The details, advantages and disadvantages of the different in situ methods are critically examined and put in comparison to the classical route where pre-synthesized nanoparticles are used. Various key factors influencing the solar cell performance as well as future strategies for increasing the overall efficiency of hybrid solar cells prepared via in situ routes are discussed.

Research Progress of the Counter Electrode in Dye-Sensitized Solar Cells

2010 ◽  
Vol 451 ◽  
pp. 63-78 ◽  
Author(s):  
Ying Tong Tang ◽  
Xu Pan ◽  
Song Yuan Dai ◽  
Chang Neng Zhang ◽  
Huan Jun Tian
Keyword(s):  
Counter Electrode ◽  
Dye Sensitized Solar Cells ◽  
Precious Metals ◽  
Research Progress ◽  
Counter Electrodes ◽  
Preparation Methods ◽  
Advantages And Disadvantages ◽  
Dye Sensitized ◽  
Different Types ◽  
Sensitized Solar Cells

This review covers recent research on counter electrodes using platinum (Pt), carbon and conducting polymers as catalysts for the reduction of triiodide in the dye-sensitized solar cell. Different types of counter electrode preparation methods and their advantages and disadvantages are compared. The inadequacy of the counter electrode with the precious metals and the advantages of the non-metallic-type counter electrode are pointed out. Especially, recent research on the Pt counter electrode in our group is discussed concerning with the reaction mechanism of the triiodide (I3-)/ iodide (I-) redox couple on the Pt counter electrode.

scholarly journals Technical Characteristics and Wear-Resistant Mechanism of Nano Coatings: A Review

Coatings ◽  
2020 ◽  
Vol 10 (3) ◽  
pp. 233 ◽  
Author(s):  
Yunqing Gu ◽  
Ke Xia ◽  
Denghao Wu ◽  
Jiegang Mou ◽  
Shuihua Zheng
Keyword(s):  
Wear Resistance ◽  
Vapor Deposition ◽  
Surface Effect ◽  
Research Progress ◽  
Material Surface ◽  
Preparation Methods ◽  
Wear Resistant ◽  
Advantages And Disadvantages ◽  
Nano Coating ◽  
Developed Surface

Nano-coating has been a hot issue in recent years. It has good volume effect and surface effect, and can effectively improve the mechanical properties, corrosion resistance and wear resistance of the coatings. It is important to improve the wear resistance of the material surface. The successful preparation of nano-coatings directly affects the application of nano-coatings. Firstly, the preparation methods of conventional surface coatings such as chemical vapor deposition and physical vapor deposition, as well as the newly developed surface coating preparation methods such as sol-gel method, laser cladding and thermal spraying are reviewed in detail. The preparation principle, advantages and disadvantages and the application of each preparation method in nano-coating are analyzed and summarized. Secondly, the types of nano-coating materials are summarized and analyzed by inorganic/inorganic nanomaterial coatings and organic/inorganic nanomaterial coatings, and their research progress is summarized. Finally, the wear-resistant mechanism of nano-coatings is revealed from three aspects: grain refinement, phase transformation toughening mechanism and nano-effects. The application prospects of nano-coatings and the development potential combined with 3D technology are prospected.

Recent Patents on Preparation Methods and Mechanical Stability of Superhydrophobic Surface

2021 ◽  
Vol 15 ◽  
Author(s):  
Zhaolong Li ◽  
Yingtao Liu
Keyword(s):  
Superhydrophobic Surface ◽  
Mechanical Stability ◽  
Sol Gel ◽  
Mechanical Action ◽  
Superhydrophobic Surfaces ◽  
Research Progress ◽  
Step Method ◽  
Preparation Methods ◽  
Advantages And Disadvantages ◽  
Application Fields

Background: Superhydrophobic surfaces have unique wettability and have shown broad application prospects in many fields, such as self-cleaning and lubrication drag reduction. However, the superhydrophobic surfaces are severely restricted by their poor mechanical stability in practical application, and the mechanical stability of the superhydrophobic surface is always affected by different preparation methods. Therefore, people pay more attention to the preparation methods of superhydrophobic surfaces. Objective: The study aims to improve the mechanical stability of the superhydrophobic surface and expand the application fields of the superhydrophobic surfaces; preparation methods of the superhydrophobic surface have been continuously improved. Methods: This paper reviews various representative patents and papers on preparation methods of the superhydrophobic surface at home and abroad. Results: In this review, the basic methods of preparing superhydrophobic surfaces were introduced, and three typical methods were summarized, such as etching method, coating method, and sol-gel method, then their advantages and disadvantages were discussed. In combination with the latest research progress, it is proposed that the use of environmentally friendly low surface energy modifiers and the use of the one-step method to prepare superhydrophobic surfaces are the future development trends. Aiming at the problem of the mechanical stability of superhydrophobic surfaces, the instability mechanism and stability evaluation methods of superhydrophobic surfaces under mechanical action are reviewed, and three basic methods to improve the mechanical stability of superhydrophobic surfaces are proposed. Conclusion: The optimization of the preparation method of the superhydrophobic surface is beneficial to improve the mechanical stability of the superhydrophobic surface and expand the application prospect of the superhydrophobic surfaces in various fields. More patents and papers on the superhydrophobic surface will be invented later.

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