Thermodynamic Behavior of Very Stable Solid Binary Compounds with a Wide Homogeneity Range: Their Influence in the Liquid Phase and in Ternary and Higher Component Systems in the Solid State / Das thermodynamische Verhalten sehr stabiler, binärer, fester Verbindungen mit weitem Homogenitätsbereich: Ihr Einfluß auf die flüssige Phase und auf den festen Zustand ternärer und höherkomponentiger Systeme

1988 ◽  
Vol 79 (7) ◽  
pp. 426-434
Author(s):  
Michael Hoch
Keyword(s):  
Solid State ◽  
Liquid Phase ◽  
Homogeneity Range ◽  
Thermodynamic Behavior ◽  
Wide Homogeneity Range ◽  
Component Systems ◽  
Binary Compounds

Phase equilibria of the Cu–Dy–Ti ternary system at 973 K

2015 ◽  
Vol 30 (3) ◽  
pp. 218-223
Author(s):  
Yanfang Pan ◽  
Hao Liu ◽  
Wenchao Yang ◽  
Bo Zhang ◽  
Hongqun Tang ◽  
...  
Keyword(s):  
Solid State ◽  
Ternary System ◽  
Phase Equilibria ◽  
Homogeneity Range ◽  
Solid Solubility ◽  
Ternary Phase ◽  
Single Phase ◽  
Phase Relations ◽  
The Other ◽  
Binary Compounds

The solid-state phase equilibria of the copper (Cu)–dysprosium (Dy)–titanium (Ti) ternary system at 973 K has been experimentally investigated. The existence of nine binary compounds, Cu4Ti, Cu3Ti2, Cu4Ti3, CuTi, CuTi2, CuTi3, CuDy, Cu2Dy, and Cu5Dy was confirmed. The controversial phase of CuTi3 was found in this work. The temperature range of Cu7Dy was determined to be from 1112 to 1183 K. The phase relations at 973 K are governed by ten ternary phase regions, 21 binary phase regions, and 12 single-phase regions. The solid solubility of Cu in Dy is undetectable. None of the other phase in this system reveals a remarkable homogeneity range at 973 K.

scholarly journals Synthesis and Na+ Ion Conductivity of Stoichiometric Na3Zr2Si2PO12 by Liquid-Phase Sintering with NaPO3 Glass

Materials ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 3790
Author(s):  
Yongzheng Ji ◽  
Tsuyoshi Honma ◽  
Takayuki Komatsu
Keyword(s):  
Solid State ◽  
Liquid Phase ◽  
Sintering Temperature ◽  
Liquid Phase Sintering ◽  
Ion Conductivity ◽  
X Ray Diffraction ◽  
Conventional Solid State Reaction ◽  
X Ray ◽  
Sintering Time ◽  
Lower Activation

Sodium super ionic conductor (NASICON)-type Na3Zr2Si2PO12 (NZSP) with the advantages of the high ionic conductivity, stability and safety is one of the most famous solid-state electrolytes. NZSP, however, requires the high sintering temperature about 1200 °C and long sintering time in the conventional solid-state reaction (SSR) method. In this study, the liquid-phase sintering (LPS) method was applied to synthesize NZSP with the use of NaPO3 glass with a low glass transition temperature of 292 °C. The formation of NZSP was confirmed by X-ray diffraction analyses in the samples obtained by the LPS method for the mixture of Na2ZrSi2O7, ZrO2, and NaPO3 glass. The sample sintered at 1000 °C for 10 h exhibited a higher Na+ ion conductivity of 1.81 mS/cm at 100 °C and a lower activation energy of 0.18 eV compared with the samples prepared by the SSR method. It is proposed that a new LPE method is effective for the synthesis of NZSP and the NaPO3 glass has a great contribution to the Na+ diffusion at the grain boundaries.

scholarly journals Preparation of Li3PS4–Li3PO4 Solid Electrolytes by Liquid-Phase Shaking for All-Solid-State Batteries

2021 ◽  
Vol 2 (1) ◽  
pp. 39-48
Author(s):  
Nguyen H. H. Phuc ◽  
Takaki Maeda ◽  
Tokoharu Yamamoto ◽  
Hiroyuki Muto ◽  
Atsunori Matsuda
Keyword(s):  
Solid Solution ◽  
Solid State ◽  
Liquid Phase ◽  
Room Temperature ◽  
Reaction Medium ◽  
Magic Angle Spinning ◽  
Resonance Spectroscopy ◽  
Synthesis Methods ◽  
Magic Angle ◽  
Angle Spinning

A solid solution of a 100Li3PS4·xLi3PO4 solid electrolyte was easily prepared by liquid-phase synthesis. Instead of the conventional solid-state synthesis methods, ethyl propionate was used as the reaction medium. The initial stage of the reaction among Li2S, P2S5 and Li3PO4 was proved by ultraviolet-visible spectroscopy. The powder X-ray diffraction (XRD) results showed that the solid solution was formed up to x = 6. At x = 20, XRD peaks of Li3PO4 were detected in the prepared sample after heat treatment at 170 °C. However, the samples obtained at room temperature showed no evidence of Li3PO4 remaining for x = 20. Solid phosphorus-31 magic angle spinning nuclear magnetic resonance spectroscopy results proved the formation of a POS33− unit in the sample with x = 6. Improvements of ionic conductivity at room temperature and activation energy were obtained with the formation of the solid solution. The sample with x = 6 exhibited a better stability against Li metal than that with x = 0. The all-solid-state half-cell employing the sample with x = 6 at the positive electrode exhibited a better charge–discharge capacity than that employing the sample with x = 0.

scholarly journals Production of ceramics from coal fly ash

2012 ◽  
Vol 18 (2) ◽  
pp. 245-254 ◽  
Author(s):  
Biljana Angjusheva ◽  
Emilija Fidancevska ◽  
Vojo Jovanov
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Solid State ◽  
Liquid Phase ◽  
Bending Strength ◽  
Coal Fly Ash ◽  
Liquid Phase Sintering ◽  
Heating Rates ◽  
Republic Of Macedonia ◽  
The Subject

Dense ceramics are produced from fly ash from REK Bitola, Republic of Macedonia. Four types of fly ash from electro filters and one from the collected zone with particles < 0.063 mm were the subject of this research. Consolidation was achieved by pressing (P= 133 MPa) and sintering (950, 1000, 1050 and 11000C and heating rates of 3 and 100/min). Densification was realized by liquid phase sintering and solid state reaction where diopside [Ca(Mg,Al)(Si,Al)2O6] was formed. Ceramics with optimal properties (porosity 2.96?0.5%, bending strength - 47.01?2 MPa, compressive strength - 170 ?5 MPa) was produced at 1100?C using the heating rate of 10?C/min.

Technological Features of the Liquid-Solid State of the Boundary Layer in the Processes of Bimetallic Products

2022 ◽  
Vol 1049 ◽  
pp. 53-61
Author(s):  
Valeriy Lykhoshva ◽  
Dmitry Glushkov ◽  
Elena Reintal ◽  
Valeriy V. Savin ◽  
Ludmila Alexeyevna Savina ◽  
...  
Keyword(s):  
Mathematical Modeling ◽  
Experimental Data ◽  
Boundary Layer ◽  
Solid State ◽  
Liquid Phase ◽  
Contact Zone ◽  
Thermal Field ◽  
Thermal State ◽  
Existence Time ◽  
Modeling Data

The hydrodynamic and thermal state in the contact zone of the layers of a bimetallic product obtained by pouring liquid iron onto a solid steel billet, which changes in time and is responsible for the strength of the diffusion joint and the geometric parameters of the transition layer, has been investigated. Simplified analytical dependences, mathematical modeling data and experimental results of the liquid phase existence time in the contact zone based on research of the melt velocities during pouring and changes in the thermal field are presented. It is shown that simplified calculations data coincide in order and are close in values ​​to the calculations of mathematical modeling and experimental data, which makes it possible to use them for preliminary rough estimates by technologists and metallurgists.

Research on Combined Processing Technology of Superficial Layers Hardened Steel

2016 ◽  
Vol 841 ◽  
pp. 21-28
Author(s):  
Petrică Corabieru ◽  
Stefan Velicu ◽  
Anişoara Corabieru ◽  
Dan Dragos Vasilescu ◽  
Ionel Păunescu
Keyword(s):  
Solid State ◽  
Liquid Phase ◽  
Cooling Rate ◽  
Hold Time ◽  
Hardened Steel ◽  
Operating Conditions ◽  
Technological Parameters ◽  
Surface Layers ◽  
Durability Analysis ◽  
Machined Parts

The novelty technology lies in the fact that the hardening of the surface layers is carried out both in liquid phase and in the solid state. Technology comprises three main stages with 12 technological phases.Experimentation highlights the viability of the technological procedure. The results of tests and verifications are the basis of the analysis of combined machined parts behavior in conditions similar to the operating conditions and of the analysis of the dependence between operation behavior and durability. Analysis of the results revealed the fact that failure to technological parameters: casting temperature; hold time at high temperatures; cooling rate after microalloying in liquid phase, gives rise to possible faults of the combined treated parts.

scholarly journals Superionic Solid Electrolyte Li7La3Zr2O12 Synthesis and Thermodynamics for Application in All-Solid-State Lithium-Ion Batteries

Materials ◽  
2021 ◽  
Vol 15 (1) ◽  
pp. 281
Author(s):  
Daniil Aleksandrov ◽  
Pavel Novikov ◽  
Anatoliy Popovich ◽  
Qingsheng Wang
Keyword(s):  
Free Energy ◽  
Solid State ◽  
Lithium Ion Batteries ◽  
Gibbs Free Energy ◽  
Thermodynamic Characteristics ◽  
Lithium Ion ◽  
Standard Enthalpy Of Formation ◽  
X Ray Diffraction ◽  
X Ray ◽  
Binary Compounds

Solid-state reaction was used for Li7La3Zr2O12 material synthesis from Li2CO3, La2O3 and ZrO2 powders. Phase investigation of Li7La3Zr2O12 was carried out by x-ray diffraction (XRD), scanning electron microscopy (SEM) and energy-dispersive x-ray spectroscopy (EDS) methods. The thermodynamic characteristics were investigated by calorimetry measurements. The molar heat capacity (Cp,m), the standard enthalpy of formation from binary compounds (ΔoxHLLZO) and from elements (ΔfHLLZO), entropy (S0298), the Gibbs free energy of the Li7La3Zr2O12 formation (∆f G0298) and the Gibbs free energy of the LLZO reaction with metallic Li (∆rGLLZO/Li) were determined. The corresponding values are Cp,m = 518.135 + 0.599 × T − 8.339 × T−2, (temperature range is 298–800 K), ΔoxHLLZO = −186.4 kJ·mol−1, ΔfHLLZO = −9327.65 ± 7.9 kJ·mol−1, S0298 = 362.3 J·mol−1·K−1, ∆f G0298 = −9435.6 kJ·mol−1, and ∆rGLLZO/Li = 8.2 kJ·mol−1, respectively. Thermodynamic performance shows the possibility of Li7La3Zr2O12 usage in lithium-ion batteries.

Thermal Conductivity Enhancement in a Latent Heat Storage Device

2013 ◽  
Vol 860-863 ◽  
pp. 590-593
Author(s):  
Cha Xiu Guo ◽  
Ding Bao Wang ◽  
Gao Lin Hu
Keyword(s):  
Heat Transfer ◽  
Thermal Conductivity ◽  
Solid State ◽  
Liquid Phase ◽  
Phase Change ◽  
Latent Heat ◽  
Heat Storage ◽  
Storage Device ◽  
Latent Heat Storage ◽  
Conductivity Enhancement

High conductivity porosity materials are proposed to enhance the phase change materials (PCM) in order to solve the problem of low conductivity of PCM in the latent heat storage device (LHSD), and two-dimensional numerical simulation is conducted to predict the performance of the PCM by CFD software. During the phase change process, the PCM is heated from the solid state to the liquid phase in the process of melting and from the liquid phase to the solid state in the solidification process. The results show that porosity materials can improve heat transfer rate effectively, but the effect of heat transfer of Al foam is superior to that of graphite foam although the heat storage capacity is almost the same for both. The heat transfer is enhanced and the solidification time of PCM is decreased since the effective thermal conductivity of composite PCM is increased.

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