Factors influencing temporal changes in chemical composition of biogenic deposits in the middle Tążyna River Valley (Kuyavian Lakeland, central Poland)

Abstract The present paper discusses the influence of geochemical properties on biogenic deposits in the Wilkostowo mire near Toruń, central Poland. The analysed core has allowed the documentation of environmental changes between the older part of the Atlantic Period and the present day (probably interrupted at the turn of the Meso- and Neoholocene). In order to reconstruct the main stages in the sedimentation of biogenic deposits, we have used stratigraphic variability of selected litho-geochemical elements (organic matter, calcium carbonate, biogenic and terrigenous silica, macro- and micro-elements: Na, K, Mg, Ca, Fe, Mn, Cu, Zn, Pb, Cr and Ni). The main litho-geochemical component is CaCO3; its content ranges from 4.1 per cent to 92 per cent. The variability of CaCO3 content reflects mainly changes in hydrological and geomorphological conditions within the catchment area. The effects of prehistoric anthropogenic activities in the catchment of the River Tążyna, e.g., the use of saline water for economic purposes, are recorded in a change from calcareous gyttja into detritus-calcareous gyttja sedimentation and an increased content of lithophilous elements (Na, K, Mg and Ni) in the sediments. Principal component analysis (PCA) has enabled the distinction the most important factors that affected the chemical composition of sediments at the Wilkostowo site, i.e., mechanical and chemical denudation processes in the catchment, changes in redox conditions, bioaccumulation of selected elements and human activity. Sediments of the Wilkostowo mire are located in the direct vicinity of an archaeological site, where traces of intensive settlement dating back to the Neolithic have been documented. The settlement phase is recorded both in lithology and geochemical properties of biogenic deposits which fill the reservoir formed at the bottom of the Parchania Canal Valley.

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Hydrogeochemical Assessment of Groundwater and Suitability Analysis for Domestic and Agricultural Utility in Southern Punjab, Pakistan

Water ◽

10.3390/w13243589 ◽

2021 ◽

Vol 13 (24) ◽

pp. 3589

Author(s):

Javed Iqbal ◽

Chunli Su ◽

Abdur Rashid ◽

Nan Yang ◽

Muhammad Yousuf Jat Baloch ◽

...

Keyword(s):

Groundwater Quality ◽

Environmental Changes ◽

Anthropogenic Activities ◽

Exchange Process ◽

Management Strategies ◽

Principal Component ◽

Suitability Analysis ◽

Ion Exchange Process ◽

Reverse Ion Exchange ◽

Groundwater Samples

Groundwater is a critical water supply for safe drinking water, agriculture, and industry worldwide. In the Khanewal district of Punjab, Pakistan, groundwater has severely deteriorated during the last few decades due to environmental changes and anthropogenic activities. Therefore, 68 groundwater samples were collected and analyzed for their main ions and trace elements to investigate the suitability of groundwater sources for drinking and agricultural purposes. Principal component analysis (PCA) and cluster analysis (CA) were employed to determine the major factors influencing groundwater quality. To assess the groundwater’s appropriateness for drinking and irrigation, drinking and agricultural indices were used. The pH of the groundwater samples ranged from 6.9 to 9.2, indicating that the aquifers were slightly acidic to alkaline. The major cations were distributed as follows: Na+ > Ca2+ > Mg2+ > K+. Meanwhile, the anions are distributed as follows: HCO3− > SO42− > Cl− > F−. The main hydrochemical facies were identified as a mixed type; however, a mixed magnesium, calcium, and chloride pattern was observed. The reverse ion exchange process helps in exchanging Na+ with Ca2+ and Mg2+ ions in the groundwater system. Rock weathering processes, such as the dissolution of calcite, dolomite, and gypsum minerals, dominated the groundwater hydrochemistry. According to the Weight Arithmetic Water Quality Index (WAWQI), 50% of the water samples were unsafe for drinking. The Wilcox diagram, USSL diagram, and some other agricultural indices resulted in around 32% of the groundwater samples being unsuitable for irrigation purposes. The Khanewal’s groundwater quality was vulnerable due to geology and the influence of anthropogenic activities. For groundwater sustainability in Khanewal, management strategies and policies are required.

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Hydrogeochemical evolution processes and evaluation of groundwater suitability for domestic and agricultural utility in Southern Punjab, Pakistan

10.21203/rs.3.rs-536324/v1 ◽

2021 ◽

Author(s):

Javed Iqbal ◽

Chunli Su

Keyword(s):

Environmental Changes ◽

Major Ions ◽

Anthropogenic Activities ◽

Human Life ◽

Principal Component ◽

Weathering Processes ◽

Groundwater Samples ◽

Groundwater Hydrochemistry ◽

And Cluster Analysis ◽

Major Factors

Abstract Groundwater is a vital resource for human life and economic growth. In the Khanewal district of Punjab, Pakistan, environmental changes, and anthropogenic activities have made groundwater extremely vulnerable in the past forty years. Sixty-eight groundwater samples were collected from the study area, major ions and trace elements were analyzed. The Principal Component Analysis and Cluster Analysis were used to identify the major factors influencing groundwater quality, as well as to assess its suitability for drinking and irrigation in southern Punjab. The aquifers are slightly acidic to alkaline, according to the pH (6.9–9.2) of groundwater. Significant cations are distributed as follows: Na+ > Ca2+ > Mg2+ > K+, while anions are distributed as HCO3− > SO42− > Cl−. The main hydrochemical facies are mixed Na·Ca-HCO3 and Na·Ca (Mg)-HCO3·SO4. Rock weathering processes, such as the dissolution of calcite, dolomite, and gypsum minerals, governed groundwater hydrochemistry. The water quality index (WQI) indicates that 17.64% of the water samples are unsuitable to drink. However, according to the Wilcox diagram, the USSL diagram, and some other agricultural indices, approximately 68% of the groundwater samples are suitable for irrigation.

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Hydro-geochemical properties with respect to landuse in the southernmost river of Kerala

Journal of Traditional and Folk Practices ◽

10.25173/jtfp.2018.6.1.94 ◽

2018 ◽

Vol 6 (1) ◽

Author(s):

Badusha M. ◽

Santhosh S

Keyword(s):

Organic Carbon ◽

Drainage Basin ◽

Anthropogenic Activities ◽

Oxygen Demand ◽

Ion Concentration ◽

Total Hardness ◽

Hydrogen Ion Concentration ◽

Geochemical Properties ◽

Quality Of Water

The hydro geochemical features of Neyyar River for a period of one year from May 2015 to April 2016 were analyzed. Six sampling sites were fixed considering physiography and present landuse pattern of the river basin. The residents in the drainage basin are primarily responsible for framing a better landuse and thereby maintain a good water and sediment regime. Geospatial pattern of the present landuse of the study area indicated that the sustainability of this river ecosystem is in danger due to unscientific landuse practices, which is reflected in the river quality as well. The parameters such as hydrogen ion concentration, electrical conductivity, chloride, Biological Oxygen Demand, total hardness and sulphate of river water and Organic Carbon of river bed sediments were analyzed in this study. The overall analysis shows that the highland areas are characterized by better quality of water together with low organic carbon, which is mainly due to better landuse and minimal reclamation. The midland and lowland areas are characterized by poor quality of water with high organic carbon, which is due to high anthropogenic activities and maximum pollutants associated with the region together with the alteration in landuse from a traditional eco-friendly pattern to a severely polluted current pattern.

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Effect of irrigation with saline water on growth and chemical composition of celery

Al-Azhar Journal of Agricultural Research ◽

10.21608/ajar.2019.102834 ◽

2019 ◽

Vol 44 (2) ◽

pp. 165-171

Author(s):

A. Ashmawi

Keyword(s):

Chemical Composition ◽

Saline Water

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The chemical composition of Lessonia berteroana (ex L. nigrescens) in kelp harvest management and open access areas near Coquimbo, Chile

Latin American Journal of Aquatic Research ◽

10.3856/vol46-issue2-fulltext-2 ◽

2018 ◽

Vol 46 (2) ◽

pp. 258-267

Author(s):

J.M. Alonso Vega ◽

Pedro H. Toledo

Keyword(s):

Resource Management ◽

Chemical Composition ◽

Open Access ◽

Environmental Changes ◽

Chemical Components ◽

Optimal Harvesting ◽

Harvest Management ◽

Species Population ◽

Pressure Indicators ◽

Lessonia Berteroana

Lessonia berteroana (ex L. nigrescens) is kelp freely harvested from Open Access Areas (OAA), and to some extent controlled, from Management and Exploitation Areas for Benthic Resources (MEABR). Harvesting pressures can change population dynamics, mainly in OAAs. In particular, harvesting may alter the chemical components of plants. Therefore, the aim of this study was to determine the harvesting effects on the chemical composition of L. berteroana from MEABR and OAA sampled during different seasons (spring and fall) and at two sites (Talquilla and Lagunillas) near Coquimbo (30°S), Chile. The crude protein (13.5 ± 1.0%), total lipids (0.9 ± 0.2%), crude fiber (16.3 ± 1.6%), ash (30.1 ± 1.5%), and nitrogen-free extract (39.2 ± 2.0%) contents of L. berteroana were within reference values for Laminariales species. Population descriptors and chemical analyses showed that harvesting had local effects, rather than being affected by a resource management strategy (OAA vs MEABR). The seasonal anticipator nature of L. berteroana may explain the detected seasonality of it's chemical composition. Regarding functional morphological structures, chemical composition in the fronds was more variable than in the stipes and perennial holdfast, probably since leaves are ephemeral structures susceptible to environmental changes and that play a functional, rather than structural, role in kelp. In the context of Chilean kelp resource management, monitoring chemical composition is useful for determining optimal harvesting periods to local scale and for deciding when commercially valuable compounds, such as alginate, should be extracted. These data also complement harvesting pressure indicators based on L. berteroana demographic parameters.

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Ripening Changes of the Chemical Composition, Proteolysis, and Lipolysis of a Hair Sheep Milk Mexican Manchego-Style Cheese: Effect of Nano-Emulsified Curcumin

Foods ◽

10.3390/foods10071579 ◽

2021 ◽

Vol 10 (7) ◽

pp. 1579

Author(s):

Mariam Sardiñas-Valdés ◽

Hugo Sergio García-Galindo ◽

Alfonso Juventino Chay-Canul ◽

José Rodolfo Velázquez-Martínez ◽

Josafat Alberto Hernández-Becerra ◽

...

Keyword(s):

Principal Component Analysis ◽

Antioxidant Activity ◽

Chemical Composition ◽

Phenolic Content ◽

Principal Component ◽

Total Phenolic ◽

Hair Sheep ◽

Dairy Foods ◽

Ripening Time ◽

Sheep Milk

The influence of nano-emulsified curcumin (NEC) added to the hair sheep milk, prior to cheese-making, on the chemical composition, lipolysis, and proteolysis of manchego-style cheeses were evaluated throughout 80 days of ripening. The addition of NEC to the milk resulted in cheeses with the same moisture content (42.23%), total protein (23.16%), and water activity (0.969) (p > 0.05). However, it increased the fat and ash levels from 26.82% and 3.64% in B 10 ppm to 30.08% and 3.85% in C 10 ppm, respectively, at the end of the ripening (p < 0.05). The total phenolic content and antioxidant activity of experimental cheeses increased during ripening, and the fatty acid groups showed significant changes occurred to a greater extent in the first days of ripening (p < 0.05). The lipolysis increased consistently in all cheeses until day 40 of ripening, to decrease at the end, while proteolysis increased during all ripening time in all samples (p < 0.05); the addition of NEC did not alter the primary proteolysis of manchego-style cheeses, but it modified secondary proteolysis and lipolysis (p < 0.05). Principal component analysis was useful for discriminating cheeses according to their chemical composition and classified into four groups according to their ripening time. This research highlights the potential of CNE to fortify dairy foods to enhance their functionality.

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Multitemporal–Multispectral UAS Surveys for Archaeological Research: The Case Study of San Vincenzo Al Volturno (Molise, Italy)

Remote Sensing ◽

10.3390/rs13142719 ◽

2021 ◽

Vol 13 (14) ◽

pp. 2719

Author(s):

Nicodemo Abate ◽

Alessia Frisetti ◽

Federico Marazzi ◽

Nicola Masini ◽

Rosa Lasaponara

Keyword(s):

Middle Ages ◽

Principal Component ◽

Archaeological Site ◽

Archaeological Sites ◽

Medieval Art ◽

Archaeological Data ◽

History Of ◽

Close Range ◽

Low Altitude

Unmanned aerial vehicles are currently the most used solution for cultural heritage in the field of close range and low altitude acquisitions. This work shows data acquired by multitemporal and multispectral aerial surveys in the archaeological site of San Vincenzo al Volturno (Molise, Italy). The site is one of the most important medieval archaeological sites in the world. It is a monastic settlement that was particularly rich during the early Middle Ages, and is famous for its two full-frescoed crypts which represent a milestone in the history of medieval art. Thanks to the use of multispectral aerial photography at different times of the year, an area not accessible to archaeological excavation has been investigated. To avoid redundancy of information and reduce the number of data to be analysed, a method based on spectral and radiometric enhancement techniques combined with a selective principal component analysis was used for the identification of useful information. The combination of already published archaeological data and new remote sensing discoveries, has allowed to better define the situation of the abbey during the building phases of the 8th/9th century and 11th century, confirming and adding new data to the assumptions made by archaeologists.

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Multi-domain probiotic consortium as an alternative to chemical remediation of oil spills at coral reefs and adjacent sites

Microbiome ◽

10.1186/s40168-021-01041-w ◽

2021 ◽

Vol 9 (1) ◽

Author(s):

Denise P. Silva ◽

Helena D. M. Villela ◽

Henrique F. Santos ◽

Gustavo A. S. Duarte ◽

José Roberto Ribeiro ◽

...

Keyword(s):

Microbial Community ◽

Coral Reefs ◽

Environmental Changes ◽

Oil Spills ◽

Anthropogenic Activities ◽

Oil Contamination ◽

Negative Effects ◽

Corexit 9500 ◽

Coral Health ◽

The Impact

Abstract Background Beginning in the last century, coral reefs have suffered the consequences of anthropogenic activities, including oil contamination. Chemical remediation methods, such as dispersants, can cause substantial harm to corals and reduce their resilience to stressors. To evaluate the impacts of oil contamination and find potential alternative solutions to chemical dispersants, we conducted a mesocosm experiment with the fire coral Millepora alcicornis, which is sensitive to environmental changes. We exposed M. alcicornis to a realistic oil-spill scenario in which we applied an innovative multi-domain bioremediator consortium (bacteria, filamentous fungi, and yeast) and a chemical dispersant (Corexit® 9500, one of the most widely used dispersants), to assess the effects on host health and host-associated microbial communities. Results The selected multi-domain microbial consortium helped to mitigate the impacts of the oil, substantially degrading the polycyclic aromatic and n-alkane fractions and maintaining the physiological integrity of the corals. Exposure to Corexit 9500 negatively impacted the host physiology and altered the coral-associated microbial community. After exposure, the abundances of certain bacterial genera such as Rugeria and Roseovarius increased, as previously reported in stressed or diseased corals. We also identified several bioindicators of Corexit 9500 in the microbiome. The impact of Corexit 9500 on the coral health and microbial community was far greater than oil alone, killing corals after only 4 days of exposure in the flow-through system. In the treatments with Corexit 9500, the action of the bioremediator consortium could not be observed directly because of the extreme toxicity of the dispersant to M. alcicornis and its associated microbiome. Conclusions Our results emphasize the importance of investigating the host-associated microbiome in order to detect and mitigate the effects of oil contamination on corals and the potential role of microbial mitigation and bioindicators as conservation tools. Chemical dispersants were far more damaging to corals and their associated microbiome than oil, and should not be used close to coral reefs. This study can aid in decision-making to minimize the negative effects of oil and dispersants on coral reefs.

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