scholarly journals Carbon nanostructure-based superhydrophobic surfaces and coatings

2021 ◽  
Vol 10 (1) ◽  
pp. 518-571
Author(s):  
Viswanathan S. Saji

Abstract Research and development on superhydrophobic carbon nanostructures and their nanocomposites have high industrial significance. Here, a comprehensive review of the topic is provided. Reported works on superhydrophobic surfaces and coatings of carbon nanotubes, nanofibres, nanospheres/nanothorns/others, nanodiamond, fullerene and their various nanocomposites with metals, ceramics, and polymers are described. Superhydrophobic nanostructured carbon soot, graphitic carbon, and others are also presented. The section on superhydrophobic graphene is presented concisely at the end. Reports in different application areas, including anti-corrosion, anti-icing, oil separation, anti-biofouling, and sensors, are discussed separately. Superoleophobic and superamphiphobic surfaces are also discussed.

Materials ◽  
2021 ◽  
Vol 14 (21) ◽  
pp. 6707
Author(s):  
Mohamed Rahamathulla ◽  
Rohit R. Bhosale ◽  
Riyaz A. M. Osmani ◽  
Kasturi C. Mahima ◽  
Asha P. Johnson ◽  
...  

Current discoveries as well as research findings on various types of carbon nanostructures have inspired research into their utilization in a number of fields. These carbon nanostructures offer uses in pharmacy, medicine and different therapies. One such unique carbon nanostructure includes carbon nanotubes (CNTs), which are one-dimensional allotropes of carbon nanostructure that can have a length-to-diameter ratio greater than 1,000,000. After their discovery, CNTs have drawn extensive research attention due to their excellent material properties. Their physical, chemical and electronic properties are excellent and their composites provide great possibilities for enormous nanometer applications. The current study provides a systematic review based on prior literature review and data gathered from various sources. The various research studies from many research labs and organizations were systematically retrieved, collected, compiled and written. The entire collection and compilation of this review concluded the use of CNT approaches and their efficacy and safety for the treatment of various diseases such as brain tumors or cancer via nanotechnology-based drug delivery, phototherapy, gene therapy, antiviral therapy, antifungal therapy, antibacterial therapy and other biomedical applications. The current review covers diverse applications of CNTs in designing a range of targeted drug delivery systems and application for various therapies. It concludes with a discussion on how CNTs based medicines can expand in the future.


Actuators ◽  
2019 ◽  
Vol 8 (2) ◽  
pp. 46 ◽  
Author(s):  
Mauro Giorcelli ◽  
Mattia Bartoli

In recent decades, micro and nanoscale technologies have become cutting-edge frontiers in material science and device developments. This worldwide trend has induced further improvements in actuator production with enhanced performance. A main role has been played by nanostructured carbon-based materials, i.e., carbon nanotubes and graphene, due to their intrinsic properties and easy functionalization. Moreover, the nanoscale decoration of these materials has led to the design of doped and decorated carbon-based devices effectively used as actuators incorporating metals and metal-based structures. This review provides an overview and discussion of the overall process for producing AC actuators using nanostructured, doped, and decorated carbon materials. It highlights the differences and common aspects that make carbon materials one of the most promising resources in the field of actuators.


2020 ◽  
Vol 4 (1) ◽  
pp. 4 ◽  
Author(s):  
Panagiotis Loginos ◽  
Anastasios Patsidis ◽  
Vasilios Georgakilas

Carbon nanoallotropes such as carbon nanotubes, graphene, and their derivatives have been combined with a plethora of polymers in the last years to develop new composite materials with interesting properties and applications. However, the area of photopolymer composites with carbon nanostructures has not been analogously explored. In the present article, we study the photopolymerization of poly(ethylene glycol)diacrylate (PEGDA) enriched with different carbon nanoallotropes like graphene, pristine and chemically modified carbon nanotubes (CNTs and fCNTs), and a hybrid of graphene and CNTs. The products were characterized by several microscopic and spectroscopic techniques and the electrical conductivity was studied as a function of the concentrations of carbon nanoallotropes. In general, stable thin films were produced with a concentration of carbon nanostructures up to 8.5%, although the addition of carbon nanostructures in PEGDA decreases the degree of photopolymerization, and PEDGA/carbon nanostructure composites showed electrical conductivity at a relatively low percentage.


Molecules ◽  
2020 ◽  
Vol 25 (9) ◽  
pp. 2102 ◽  
Author(s):  
Manuela Curcio ◽  
Annafranca Farfalla ◽  
Federica Saletta ◽  
Emanuele Valli ◽  
Elvira Pantuso ◽  
...  

Carbon nanostructures (CN) are emerging valuable materials for the assembly of highly engineered multifunctional nanovehicles for cancer therapy, in particular for counteracting the insurgence of multi-drug resistance (MDR). In this regard, carbon nanotubes (CNT), graphene oxide (GO), and fullerenes (F) have been proposed as promising materials due to their superior physical, chemical, and biological features. The possibility to easily modify their surface, conferring tailored properties, allows different CN derivatives to be synthesized. Although many studies have explored this topic, a comprehensive review evaluating the beneficial use of functionalized CNT vs G or F is still missing. Within this paper, the most relevant examples of CN-based nanosystems proposed for MDR reversal are reviewed, taking into consideration the functionalization routes, as well as the biological mechanisms involved and the possible toxicity concerns. The main aim is to understand which functional CN represents the most promising strategy to be further investigated for overcoming MDR in cancer.


Author(s):  
Fahad Saleem Ahmed Khan ◽  
N. M. Mubarak ◽  
Mohammad Khalid ◽  
Mohammad Mansoob Khan ◽  
Yie Hua Tan ◽  
...  

2014 ◽  
Vol 93 ◽  
pp. 164-167 ◽  
Author(s):  
Joon Won Lim ◽  
Atta Ul Haq ◽  
Sang Ouk Kim

Polymer grafting from graphitic carbon materials has been explored for several decades. Currently existing methods mostly employ harsh chemical treatment to generate defect site in graphitic carbon plane, which are used as active site for polymerization of precursors. Unfortunately, the treatment cause serious degradation of chemical structure and material properties. Here, we present a straightforward route for growth of polyaniline chain from nitrogen (N)-sites of carbon nanotubes. N site in the CNT wall initiates the polymerization of aniline monomer, which generates seamless hybrids composed of polyaniline directly grafted onto the CNT walls. The synthesized hybrids show excellent synergistic electrochemical performance, and are employed for electrodes of pseudo-capacitor. This approach offers an efficient way to obtain hybrid system consisting of conducting polymers directly grafted from graphitic dopant sites.


2003 ◽  
Vol 02 (04n05) ◽  
pp. 307-317
Author(s):  
M. S. YU ◽  
S. Y. CHENG ◽  
Y. C. LIN ◽  
W. C. HO

We have synthesized a set of nanostructured carbon samples including a variety of carbon nanotubes and carbonaceous particles, by catalytic thermal decomposition of CH4 on catalyst LaNi 5 powder with different reaction temperatures. Products obtained at reaction temperatures 550~900°C were characterized by means of HR-TEM, SEM and Raman Scattering. In addition, electrochemical charge–discharge cycling method was carried out at room temperature to measure the reversible hydrogen capacity in pressed electrodes containing mixture of catalyst, nanostructured carbon samples and carbonaceous particles. Results showed that the abundance ratio of well-crystallized graphite to amorphous carbon in each product increases with increasing reaction temperatures. This preliminary study showed also that the hydrogen storage capacity of synthesis products measured in an electrochemical half-cell at room temperature correlates with the nanostructure and morphology of the variety of nanostructured carbon samples. Additionally, the hydrogen adsorption capacity against specific surface area (BET) for synthesis products produced at temperatures higher than 670°C is ranging from 14 to 25 wt.%/(1000 m2/g).


Carbon ◽  
2006 ◽  
Vol 44 (7) ◽  
pp. 1310-1313 ◽  
Author(s):  
Xiaowei Zhao ◽  
Peng Jiang ◽  
Weiguo Chu ◽  
Shicheng Mu ◽  
Dongfang Liu ◽  
...  

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