Metallography and Biomimetics – Or New Surfaces Without Chemistry?

2021 ◽  
Vol 58 (7) ◽  
pp. 446-459
Author(s):  
T. Fox ◽  
S. M. Lößlein ◽  
D. W. Müller ◽  
F. Mücklich

Abstract Fingerprints, a butterfly’s wings, or a lotus leaf: when it comes to surfaces, there is no such thing as coincidence in animated nature. Based on their surfaces, animals and plants control their wettability, their swimming resistance, their appearance, and much more. Evolution has optimized these surfaces and developed a microstructure that fits every need. It is all the more astonishing that, with regard to technical surfaces, man confines himself to random roughnesses or “smooth” surfaces. It is surely not a problem of a lack of incentives: structured surfaces have already provided evidence of optimizing friction and wear [1, 2, 3, 4], improving electrical contacts [5, 6], making implants biocompatible [7, 8], keeping away harmful bacteria [9], and much more. How come we continue counting on grinding, polishing, sandblasting, or etching? As so often, the problem can be found in economic cost effectiveness. It is possible to produce interesting structures such as those of the feather in Fig. 1. However, generating fine structures in the micro and nanometer range usually requires precise processing techniques. This is complex, time-consuming, and cannot readily be integrated into a manufacturing process. Things are different with Direct Laser Interference Patterning, DLIP) [10, 11]. This method makes use of the strong interference pattern of overlapped laser beams as a “stamp” to provide an entire surface area with dots, lines, or other patterns – in one shot. It thus saves time, allows for patterning speeds of up to 1 m2/min and does it without an elaborate pre- or post-treatment [10, 12]. The following article intends to outline how the method works, which structures can be generated, and how the complex multi-scale structures that nature developed over millions of years can be replicated in only one step.

Materials ◽  
2019 ◽  
Vol 12 (17) ◽  
pp. 2737 ◽  
Author(s):  
Alfredo I. Aguilar-Morales ◽  
Sabri Alamri ◽  
Bogdan Voisiat ◽  
Tim Kunze ◽  
Andrés F. Lasagni

Superhydrophobic natural surfaces usually have multiple levels of structure hierarchy, particularly microstructures covered with nano-roughness. The multi-scale nature of such a surface reduces the wetting of water and oils, and supports self-cleaning properties. In this work, in order to broaden our understanding of the wetting properties of technical surfaces, biomimetic surface patterns were fabricated on stainless steel with single and multi-scale periodic structures using direct laser interference patterning (DLIP). Micropillars with a spatial period of 5.5 µm and a structural depth of 4.2 µm were fabricated and covered by a sub-micro roughness by using ultrashort laser pulses, thus obtaining a hierarchical geometry. In order to distinguish the influence of the different features on the wettability behavior, a nanosecond laser source was used to melt the nano-roughness, and thus to obtain single-scale patterns. Then, a systematic comparison between the single- and multi-scale structures was performed. Although, the treated surfaces showed hydrophilic behavior directly after the laser treatment, over time they reached a steady-state hydrophobic condition. However, the multi-scale structured metal showed a contact angle 31° higher than the single-scale geometry when the steady-state conditions were reached. Furthermore, the impact of the surface chemistry was investigated by energy dispersive X-ray spectroscopy (EDX) and X-ray photoelectron spectroscopy (XPS) analyses. Finally, a hydrophobizing agent was applied to the laser treated samples in order to further enhance the water contact angles and to determine the pure contribution of the surface topography. In the latter case, the multi-scale periodic microstructures reached static contact angles of 152° ± 2° and a contact angle hysteresis of only 4° ± 2°, while the single-scale structures did not show superhydrophobic behavior. These results definitely suggest that multi-scale DLIP structures in conjunction with a surface chemistry modification can promote a superhydrophobic regime.


2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Yangxi Fu ◽  
Marcos Soldera ◽  
Wei Wang ◽  
Stephan Milles ◽  
Kangfa Deng ◽  
...  

AbstractIn this study, two-step approaches to fabricate periodic microstructures on polyethylene terephthalate (PET) and poly(methyl methacrylate) (PMMA) substrates are presented to control the wettability of polymeric surfaces. Micropillar arrays with periods between 1.6 and 4.6 µm are patterned by plate-to-plate hot embossing using chromium stamps structured by four-beam Direct Laser Interference Patterning (DLIP). By varying the laser parameters, the shape, spatial period, and structure height of the laser-induced topography on Cr stamps are controlled. After that, the wettability properties, namely the static, advancing/receding contact angles (CAs), and contact angle hysteresis were characterized on the patterned PET and PMMA surfaces. The results indicate that the micropillar arrays induced a hydrophobic state in both polymers with CAs up to 140° in the case of PET, without modifying the surface chemistry. However, the structured surfaces show high adhesion to water, as the droplets stick to the surfaces and do not roll down even upon turning the substrates upside down. To investigate the wetting state on the structured polymers, theoretical CAs predicted by Wenzel and Cassie-Baxter models for selected structured samples with different topographical characteristics are also calculated and compared with the experimental data.


2020 ◽  
Vol 72 (8) ◽  
pp. 1001-1005
Author(s):  
Theresa Jähnig ◽  
Andrés F. Lasagni

Purpose This study aims to introduce a strategy that permits well-defined contact areas in forming tools for improving both wear and friction properties by a selective laser treatment of a hydrogen-free diamond-like carbon layer (DLC), for substituting lubrication in forming processes. The need of lubricant substitution in forming processes is given because, besides the positive technological aspects, lubrication leads to numerous negative economic and ecological effects such as lubricant appliance and removal costs as well as its disposal. Design/methodology/approach Hydrogen-free DLCs with an sp³-ratio of 60-70 per cent are deposited on steel surfaces and subsequently micro-structured using direct laser interference patterning (DLIP). To find the optimal structure parameters for reducing friction and wear, line-like and cross-like patterns with three different structure sizes were fabricated onto the DLC layer. Tribological measurements are performed with a ball-on-disk tribometer on the differently DLIP-structured surfaces and compared to polished steel and unstructured DLC reference surfaces. Findings A reduction of the coefficient of friction, from 0.18 to 0.11, is observed for the laser-structured DLC surfaces, reaching values comparable to lubricated and polished steel surfaces, with a friction coefficient of 0.10. Originality/value Using DLIP, it was possible to show how this method can reduce friction on DLC-coated specimens. The observed characteristics are relevant to improve the tribological performance of forming processes, without usage of lubrication.


2007 ◽  
Vol 9 (1-2) ◽  
pp. 99-103 ◽  
Author(s):  
A. F. Lasagni ◽  
D. F. Acevedo ◽  
C. A. Barbero ◽  
F. Mücklich

Materials ◽  
2021 ◽  
Vol 14 (1) ◽  
pp. 184
Author(s):  
Stephan Milles ◽  
Johannes Dahms ◽  
Marcos Soldera ◽  
Andrés F. Lasagni

Laser-microtextured surfaces have gained an increasing interest due to their enormous spectrum of applications and industrial scalability. Direct laser interference patterning (DLIP) and the well-established direct laser writing (DLW) methods are suitable as a powerful combination for the fabrication of single (DLW or DLIP) and multi-scale (DLW+DLIP) textures. In this work, four-beam DLIP and DLW were used independently and combined to produce functional textures on aluminum. The influence of the laser processing parameters, such as the applied laser fluence and the number of pulses, on the resulting topography was analyzed by confocal microscopy and scanning electron microscopy. The static long-term and dynamic wettability characteristics of the laser-textured surfaces were determined through water contact angle and hysteresis measurements, revealing superhydrophobic properties with static contact angles up to 163° and hysteresis as low as 9°. The classical Cassie–Baxter and Wenzel models were applied, permitting a deeper understanding of the observed wetting behaviors. Finally, mechanical stability tests revealed that the DLW elements in the multi-scale structure protects the smaller DLIP features under tribological conditions.


2018 ◽  
Vol 20 (7) ◽  
pp. 1800160 ◽  
Author(s):  
Christoph Zwahr ◽  
Bogdan Voisiat ◽  
Alexander Welle ◽  
Denise Günther ◽  
Andrés Fabián Lasagni

Langmuir ◽  
2020 ◽  
Vol 36 (45) ◽  
pp. 13415-13425 ◽  
Author(s):  
Daniel W. Müller ◽  
Anne Holtsch ◽  
Sarah Lößlein ◽  
Christoph Pauly ◽  
Christian Spengler ◽  
...  

Polymers ◽  
2021 ◽  
Vol 13 (5) ◽  
pp. 679
Author(s):  
Daniel Sola ◽  
Stephan Milles ◽  
Andrés F. Lasagni

Refractive index modification by laser micro-structuration of diffractive optical devices in ophthalmic polymers has recently been applied for refractive correction in the fields of optics and ophthalmology. In this work, Safrofilcon-A hydrogel, used as soft contact lenses, was processed by direct laser interference patterning (DLIP) to fabricate linear periodic patterns on the surface of the samples. Periodic modulation of the surface was attained under two-beam interference by using a Q-switched laser source with emission at 263 nm and 4 ns pulse duration. Features of processed areas were studied as a function of both the interference spatial period and the laser fluence. Optical confocal microscopy used to evaluate the topography of the processed samples showed that both structured height and surface roughness increased with laser fluence. Static water contact angle (WCA) measurements were carried out with deionized water droplets on the structured areas to evaluate the hydration properties of DLIP structures. It was observed that the laser structured areas induced a delay in the hydration process. Finally, microstructural changes induced in the structured areas were assessed by confocal micro-Raman spectroscopy showing that at low laser fluences the polymer structure remained almost unaltered. In addition, Raman spectra of hydrated samples recovered the original shape of areas structured at low laser fluence.


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