Microstructural Examinations of Copper Antimony Alloys

2021 ◽  
Vol 58 (10) ◽  
pp. 620-629
Author(s):  
R. Haubner ◽  
S. Strobl

Abstract Among other materials, fahlores were used in the Bronze Age copper ore smelting process. These contain, apart from sulfur, arsenic and antimony. Therefore, these elements can be found in Bronze Age copper casting ingots or artifacts. In order to study the behavior of Sb more closely, two copper alloys containing 10 and 30 wt. % Sb were melted and subjected to a metallographic examination. On the one hand, microstructures with copper dendrites and homogeneous interdendritic areas primarily composed of intermetallic phase could be found. On the other hand, at higher Sb concentrations, first Cu3Sb precipitated which, in turn, transformed to Cu10Sb3 upon cooling. The crystals in these microstructures were characterized by numerous parallel cracks. No further phases were observed by XRD.

2016 ◽  
Vol 3 (2) ◽  
Author(s):  
Magdalena Natuniewicz-Sekuła ◽  
Dagmara H. Werra

In the Bronze Age flint was still being used throughout Europe. In the early periods of that age flint continued to play an important role in the economy in many areas, as evidenced by the numerous flint mines in use at the time as well as flint tools. In the Late Bronze and Early Iron Ages, flint still had an important place in the economies of communities living in East Central Europe. At the same time, analysis of late flint industries suggests that some of those had no utilitarian significance. The presence of flint, especially in inhumation graves from the cemetery at Weklice (used by communities of the Wielbark culture during the Roman Period) potentially adds to the debate about its significance. The cemetery at Weklice is the one of the best-known sites from the Roman Period in Poland. The graves are mostly equipped with local finds of metals: gold, silver, copper alloys, iron and amber as well as Roman imports (glass beads, vessels: glass, copper alloys). The collections comprise over of 4000 finds, however this number may change, as excavations in 2012 and 2013 revealed 22 flint artefacts. The presence of flint materials in a Roman Period cemetery admits several possible interpretations: 1) Those may be remnants of older settlements, with graves being dug into older strata and thus some of the specimens of flint could be in their secondary filling on the site; 2) Those may be remains of flint knapping activity by the Wielbark culture community; 3) Those may have been placed in the graves deliberately by the Wielbark culture community as an instance of an older custom involving the placing of flint in graves.


Starinar ◽  
2016 ◽  
pp. 173-191
Author(s):  
Aleksandar Kapuran ◽  
Dragana Zivkovic ◽  
Nada Strbac

The last three years of archaeological investigations at the site Ru`ana in Banjsko Polje, in the immediate vicinity of Bor, have provided new evidence regarding the role of non-ferrous metallurgy in the economy of the prehistoric communities of north-eastern Serbia. The remains of metallurgical furnaces and a large amount of metallic slags at two neighbouring sites in the mentioned settlement reveal that locations with many installations for the thermal processing of copper ore existed in the Bronze Age. We believe, judging by the finds of material culture, that metallurgical activities in this area also continued into the Iron Age and, possibly, into the 4th century AD.


1941 ◽  
Vol 7 ◽  
pp. 73-113 ◽  
Author(s):  
L. V. Grinsell

The area covered by this survey, which epitomizes the writer's work on Wessex barrows since 1929, is limited on the west by a line drawn from Weston-super-Mare to Bridport, on the east by a line drawn from Dorking to Arundel, on the north roughly by the northern limit of the chalk downs south of the Thames, and on the south by the sea. It encloses the great majority of bell, disc, and saucer barrows, all of which appear to be expressions of Piggott's Wessex Bronze Age culture. It should be noted however that elements of this culture are found outside the area dealt with, notably at various places to the north-east. Nearly all of these are so close to the Icknield Way as to make it certain that this was the means of communication linking the one with the other. Another, though less important, extension of the Wessex Bronze Age culture is represented by a few sites, some of them doubtful, within a short distance of the course of the Upper Thames, and it is probable that the river was the means of communication used.Here it is well to point out the respects in which the boundaries of Bronze Age Wessex, as determined by my own distribution-maps of barrows, differ from those adopted in the O.S. Map of Neolithic Wessex, and by Mr Stuart Piggott in his recent paper, ‘The Early Bronze Age in Wessex.’


Author(s):  
O. I. Goriunova ◽  
◽  
A. G. Novikov ◽  
D. А. Markhaeva ◽  
◽  
...  

The analysis of pottery materials of Posolskaya site (excavations by E. A. Khamzina in 1959), which is located on the southeast coast of Lake Baikal (Kabansk district, the Republic of Buryatia), is carried out in this article. Based on morphological features, several groups of pottery with a set of characteristic features are identified. A comparison of them with the materials of supporting multilayer objects on the coast of Baikal and Cis-Baikal area, in general, made it possible to determine the relative and absolute chronology of these groups. It was determined that pottery complexes of layers 2 and 3 contain artifacts of different cultural and chronological periods from the Neolithic to the Bronze Age in a mixed state. They contain materials of the Middle and Late Neolithic (Posolskaya and Ust-Belaya ceramic types), the Early Bronze Age (pottery with pearls, with fingernails and Northern Baikal type) and the Late Bronze Age (Tyshkine-Senogdinsk type). Reticulated pottery, recorded in small quantities, was found in all complexes of the Neolithic era of the region. The pottery studies showed, on the one hand, its morpho-typological proximity with similar pottery in the south of Central Siberia as a whole. On the other hand, there were some regional differences (thickening of the corolla in bulk on Posolskaya type pottery in two versions: from the outside and from the inside; a variety of compositional structures on vessels with an external thickening of the corolla was revealed, expressed in simplification of the ornamental design; pottery combining features of Posolskaya and Ust-Belaya types was distinguished. A series of radiocarbon dates from stratified complexes of multilayer objects on the Baikal coast made it possible to determine chronological ranges for almost all pottery groups identified at Posolskaya site. Posolskaya type pottery in two of its variants corresponds to a chronological interval of 6750–6310 cal BP; Ust’-Belaia type (focusing on the dates of Ulan-Khada and the Gorelyi Les) – 5581–4420 cal BP; pottery with pearls and constructions from wide lines of the retreating spatula – 4500–3080 cal BP, pottery with finger pinches corresponds to 3370–3230 cal BP; Northern Baikal type – 3346–3077 cal BP; Tyshkine-Senogdinsk type – 2778–1998 cal BP.


Author(s):  
Darkhan Aitzhanuly Baitileu ◽  
Maksim Nikolaevich Ankushev

The subject of this research is the copper deposits, copper-ore resource, and sources of alloying raw materials for mining and smelting production of the Paleometal Epoch in Central Kazakhstan, namely within the Kazakhstan mining and smelting region and Zhezkazgan-Ulytau mining and smelting center. The article provides the interim results of comprehensive research of geoarchaeological production facilities in the territory of copper deposits within the Zhezkazgan-Ulytau mining and smelting center, which allow determining the peculiarities of metallogenic complexes that used to be potential objects of the development of copper-ore reserves during the establishment of copper metallurgy, as well as making a predictive assessment of mineral raw materials potential of the region. The initial premise of this research lies in the authors' pursuit to integrate natural scientific methods of research into the field of humanities to the maximum effect via studying smelting slags and ore relics from the ancient settlements of the region for the purpose of reconstructing the mining and smelting process of the Bronze Age in Central Kazakhstan. The authors offer the variants of localization of the mineral raw materials complex of Zhezkazgan-Ulytau mining and smelting center within the Kazakhstan mining and smelting region. Based on examination of the ores and smelting slags of Bronze Age settlements in Central Kazakhstan, the authors believe that the main copper raw materials in the Zhezkazgan-Ulytau region were the oxidized malachite-azurite and rich sulfide ores, as well as the zones of secondary sulfide enrichment of copper sandstones of the Zhezkazgan ore region. The conducted research allow to get closer to establishing patterns of localization of various types of copper deposits and development of copper-ore resources for mining and smelting production of Zhezkazgan-Ulytau region during the Paleometal Epoch.


Antiquity ◽  
1931 ◽  
Vol 5 (20) ◽  
pp. 415-426 ◽  
Author(s):  
J. G. D. Clark

In his classic work on the Bronze Age pottery of Britain the late Lord Abercromby adopted the old division of the class of beaker pottery into three types originally proposed by Dr Thurnam as far back as 1871. In order that Abercromby may not be misrepresented I propose to quote the essential portions of his definitions. In type A, the ‘ high-brimmed globose beaker ’, ‘ the body is more or less globular ; the upper part, separated from the body by a constriction, frequently very defined, spreads out like the calyx of a flower and forms a brim or neck that almost equals the body in height. The sides of the neck or rim . . . are straight and not recurved at the lip ’. In type B, the ‘ ovoid beaker with recurved rim ’, ‘ there is no distinct demarca- tion between the body and the rim, but the one glides into the other by a gradual curve ’. Finally type C, the ‘ low-brimmed beaker ’, ‘ may be regarded ’, in Abercromby's own words, ‘ as a debased variety of our first type ’.It should be clear already I think that in labelling his types A, B, and C Abercromby has given the false impression that we have three types of beákers, whereas what we really have are two types, of which one has a ‘debased variety’. We therefore suggest that a less misleading classification would be, for instance, A(x), A(Y), and B. This may seem a trifling point but we believe it has helped to obscure the proper recognition of the true dual character of the Beaker invasion of this country. We propose to substantiate the validity of our suggestion in the course of this short paper.


1998 ◽  
Vol 93 ◽  
pp. 91-102 ◽  
Author(s):  
Helen Mangou ◽  
Panayiotis V. Ioannou

110 copper-based objects from various sites on Crete, covering the whole of the Bronze Age, were analysed for their chemical content (12 elements) by Atomic Absorption Spectrometry. The results indicate that during the Early Bronze Age arsenical copper was mainly used while in the Middle Bronze Age copper, arsenical copper, and arsenical bronze were in use with about equal frequency. During the Late Bronze Age normal bronze was used when required. The copper technology in each era was the same at all of the sites examined. Metallographic examination of four triangular daggers of the Early Bronze Age showed that they had been cast. In the case of three Late Bronze Age hydriae, the component sheets had been hammered and annealed.


2020 ◽  
pp. 5-35
Author(s):  
Soohong Lee

Social stratification in the Bronze Age and the appearance and transition of chief tombs in the early Iron Age are reviewed based on the ancient tomb data in Yeongnam Province. Chief, which means a ruler of unequal societies, first appeared in the early Iron Age. Evidence to support the appearance is given as follows: the articles from , production and distribution of ironware, construction of tombs for not a community but an individual, and the beginning of trade between local regions. In the late Bronze Age, tomb clusters turned into a common cemetery, and huge dolmens with graveyards were built. With social stratification being intensified, communities would have been maintained by blood ties and regionalism. The construction of huge tombs was for a community, not for a single person. That is, it was the tomb of the leaders, not of a chief. The types of the leader tombs vary depending on the regions: huge dolmens with graveyards in South Gyeongsang Province, and tombs with long-sharpened daggers in Daegu. In the early Iron Age, chief tombs are categorized into a group of dolmens from the patternless earthenware culture and a group of wooden coffin tombs from the Koreanstyle bronze dagger culture. The former group of chief tombs can be seen in huge dolmen areas such as Gimhae Gusan-dong and Changwon Deokcheon-ri archeological sites, and it is more of an individual’s tomb rather than a community’s. The chiefdom of dolmens and the one of wooden coffin tombs coexisted only until the chiefdom of wooden coffin tombs took over the other. In Yeongnam Province, the wooden coffin tombs first appeared in the third century B.C., and the ironware began to be buried in the second century B.C. By the first century B.C., the wooden coffin tombs clustered and the Chinese Han relics began to be buried. This is when the chiefdom was formed and the Bronze Age came to an end. In South Gyeongsang Province, chief tombs are centered in Gimhae. In Daegu-North Gyeongsang Province, chief tombs are distributed by equal intervals on the road connecting Ulsan, Gyeongju, Yeongcheon, Gyeongsan, and Daegu; it is due to the consolidation of foreign negotiation command of a chief.


1994 ◽  
Vol 60 (1) ◽  
pp. 245-286 ◽  
Author(s):  
Andrew Dutton ◽  
Peter J. Fasham ◽  
D. A. Jenkins ◽  
A. E. Caseldine ◽  
S. Hamilton-Dyer

The discovery of evidence to suggest that copper ore was exploited at the Great Orme on a considerable scale in prehistory is of great significance in our understanding of the development of metalworking technology in the British Isles.In the past, the apparent absence from the archaeological record of a contemporaneous native mineral source for the production of copper and copper alloy artefacts during the Bronze Age has led to the assumption that raw materials, as well as metal technology, were imported from abroad. Alternatively, whilst accepting that local resources could have been exploited, it was assumed that these would have been obliterated by the mining operations of later centuries.There are now several sites on the British mainland and in Ireland which have been identified and dated as having been exploited for copper ores during the Bronze Age, of which a number, as on the Great Orme, had since seen intensive working during the 18th and 19th centuries AD. AS yet, much of the evidence has come essentially from surface excavations, but at the Great Orme surface excavation combined with underground exploration has revealed a system of workings of truly remarkable size. A series of 10 radiocarbon dates has been obtained from within the mine complex, indicating that working was carried out for over a thousand years spanning the Early to Late Bronze Age.The true extent of the surviving prehistoric workings is yet to be realized but present evidence indicates mining activity covering an area in excess of 24,000 square metres, incorporating passages totalling upwards of 5 km, penetrating to a vertical depth of 70 m.Much of the archaeological evidence contained within this report has been gained from detailed excavation carried out within surface workings, which in their own right constitute a sizeable part of the prehistoric mine. From the surface area presently exposed it is conservatively estimated that 40,000 cubic metres of material was removed during the Bronze Age. Much of the early technology represented within the surface workings reflects the technology employed in the deep workings, with the additional evidence of ancillary operations which would seem to relate solely to surface locations.Whilst the excavations reported in this paper relate to surface, or near surface, workings, they must be seen in the context of a labyrinthine complex of prehistoric workings recorded at depths of over yom (Jenkins & Lewis 1991; Lewis 1994). These deep workings are the subject of parallel studies to be reported elsewhere. The known underground and surface prehistoric workings are on a scale so far unparallelled in Britain and are of international significance. Elsewhere in Europe there is evidence for the mining of copper ores at Ai Bunar in Bulgaria dated to 5840 BC (Cernych 1978) and at Rudna Glava in former Yugoslavia dated to 4715 BC (Jovanovic 1979). Evidence for subsequent copper mining has been dated to 3785 BC in southern Spain (Rio Tinto area: Rothenburg & Blanco Freijeiro 1980) and to 3330 BC in Austria (Mitterberg; Pittioni 1951), marking an apparent development and extension westwards and northwards of copper technology. More recently, the dating of two sites in the south of France to around 3330 BC, at Cabrieres (Ambert et al. 1990) and Bouche Payrol, near Brusque (Barge 1985), has confirmed another area of Bronze Age working.


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