Evaluation of stearic acid modified industrial lime sludge waste as a filler in high density polyethylene composites

2018 ◽  
Vol 38 (4) ◽  
pp. 333-341 ◽  
Author(s):  
Satadru Kashyap ◽  
Dilip Datta
Keyword(s):  
Stearic Acid ◽  
High Density Polyethylene ◽  
Low Cost ◽  
Filler Loading ◽  
Particle Dispersion ◽  
High Density ◽  
Morphological Properties ◽  
Sludge Waste ◽  
Lime Sludge ◽  
Surface Modified

AbstractIndustrial lime sludge (LS), an environmental hazard, is surface modified by stearic acid (SA) in order to reinforce high density polyethylene (HDPE) composites. Uncoated and SA-coated LS-reinforced HDPE composites are prepared and their mechanical, thermal, and morphological properties are studied and compared with each other. FTIR spectroscopy revealed successful grafting of SA onto LS particles while SEM morphology showed that SA coating hinders particle agglomeration in the HDPE matrix at higher filler loading. Mechanical properties such as tensile and flexural strength and modulus, elongation at break, and impact strength increased significantly for SA-coated LS composites due to uniform particle dispersion and effective filler-matrix interfacial interaction. The SA coating increased the entanglement at the filler-matrix interface thereby increasing the thermal decomposition of the coated composites from 500°C to 600°C. Additionally, it also reduced the water absorption rate of the coated composites in comparison with its uncoated counterpart. Thus, SA proves to be an efficient surface modifier for LS to produce HDPE composites with superior properties at a low cost. Needless to say, this study also suggests an alternative LS waste management route which offers benefits of reusing an industrial waste, decreasing the pollution, and developing fresh polymeric products.

scholarly journals Enhanced Water Resistance of Recycled Newspaper/High Density Polyethylene Composite Laminates via Hydrophobic Modification of Newspaper Laminas

Polymers ◽  
2021 ◽  
Vol 13 (3) ◽  
pp. 421
Author(s):  
Binwei Zheng ◽  
Weiwei Zhang ◽  
Litao Guan ◽  
Jin Gu ◽  
Dengyun Tu ◽  
...  
Keyword(s):  
Stearic Acid ◽  
Photoelectron Spectroscopy ◽  
Composite Laminates ◽  
High Density Polyethylene ◽  
Water Resistance ◽  
Laminated Composite ◽  
High Strength ◽  
High Water ◽  
High Density ◽  
X Ray

A high strength recycled newspaper (NP)/high density polyethylene (HDPE) laminated composite was developed using NP laminas as reinforcement and HDPE film as matrix. Herein, NP fiber was modified with stearic acid (SA) to enhance the water resistance of the NP laminas and NP/HDPE composite. The effects of heat treatment and SA concentration on the water resistance and tensile property of NP and composite samples were investigated. The chemical structure of the NP was characterized with X-ray diffractometer, X-ray photoelectron spectroscopy and attenuated total reflectance Fourier transform infrared spectra techniques. The surface and microstructure of the NP sheets were observed by scanning electron microscopy. An expected high-water resistance of NP sheets was achieved due to a chemical bonding that low surface energy SA were grafted onto the modified NP fibers. Results showed that the hydrophobicity of NP increased with increasing the stearic acid concentration. The water resistance of the composite laminates was depended on the hydrophobicity of the NP sheets. The lowest value of 2 h water absorption rate (3.3% ± 0.3%) and thickness swelling rate (2.2% ± 0.4%) of composite were obtained when the SA concentration was 0.15 M. In addition, the introduction of SA can not only enhance the water resistance of the composite laminates, but also reduce the loss of tensile strength in wet conditions, which shows potential in outdoor applications.

Graphite reinforced silane crosslinked high density polyethylene: The effect of filler loading on the thermal and mechanical properties

2020 ◽  
Author(s):  
Dimitra Kourtidou ◽  
Elli Symeou ◽  
Zoi Terzopoulou ◽  
Isaak Vasileiadis ◽  
Thomas Kehagias ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
High Density Polyethylene ◽  
Filler Loading ◽  
High Density ◽  
Thermal And Mechanical Properties

Effect of particulate fillers on natural rubber/high-density polyethylene blends for roofing application

2020 ◽  
pp. 096739112093461
Author(s):  
WVWH Wickramaarachchi ◽  
S Walpalage ◽  
SM Egodage
Keyword(s):  
Impact Strength ◽  
Natural Rubber ◽  
High Density Polyethylene ◽  
Thermoplastic Elastomer ◽  
Cost Effective ◽  
Barium Sulphate ◽  
Filler Loading ◽  
High Density ◽  
Melt Mixing ◽  
Excellent Property

Blending of two or more polymers generates a new material, which is more cost-effective than a newly synthesised material. Blending-type thermoplastic elastomer (TPE) is produced by melt-mixing of a thermoplastic with a rubber. These blends have high demands associated with excellent property combinations of the parent materials. Particulate fillers are used in the rubber and plastic industry for property modification and cost reduction. In this work, six particulate fillers, namely, calcium carbonate, barium sulphate (BaSO4), kaolin, talc, Snobrite clay and dolomite were used to develop natural rubber (NR)/high-density polyethylene (HDPE) TPE blends, and the most suitable filler for roofing application was identified. A series of NR/HDPE 20/80 blends were prepared by varying filler loading from 10 phr to 30 phr at 10 phr intervals using a Plasticorder. Mechanical properties, such as tensile strength, hardness, impact strength and tear strength, and gel content of the blends were investigated. The addition of talc, dolomite and kaolin to NR/HDPE blend showed reduced impact strength, which is the most important property for a roofing application. The other three fillers showed improved impact strength at specific loadings. The blend with 30 phr of BaSO4 was identified as the best blend, as per the overall performance.

Sepiolite as a nanofiller to improve mechanical and thermal behavior of recycled high-density polyethylene

2020 ◽  
Vol 36 (3) ◽  
pp. 185-195 ◽  
Author(s):  
Negin Farshchi ◽  
Yalda K Ostad
Keyword(s):  
Thermal Behavior ◽  
High Density Polyethylene ◽  
Low Cost ◽  
Process Condition ◽  
Softening Temperature ◽  
High Density ◽  
Plastic Pollution ◽  
Scanning Calorimetry ◽  
Melt Flow Rate ◽  
Recycled Hdpe

Regarding the current demand for controlling plastic pollution, recycling of polymer sounds a promising solution. However, recycling causes mechanical and thermal shortcomings in polymers. Addition of nanoparticles to recycled materials may overcome these shortcomings. Nanocomposites can be achieved either by blending or through polymerization. Sepiolite as a nanoparticle enhances the thermal properties of polymers. In this study, the effect of sepiolite as a nanoparticle has been investigated on the thermal and mechanical behavior of recycled high-density polyethylene (HDPE). Hardness, density, Vicat softening temperature, melt flow rate (MFR), and differential scanning calorimetry has been investigated on recycled HDPE containing different amount of sepiolite. Results showed that both the amount of recycled HDPE and the sepiolite content affect the mechanical and thermal behavior of samples. Increasing the amount of recycled component resulted in increasing of MFR, a slight increase in density, and decrease in Vicat softening point, hardness, melting temperature, and degree of crystallization. As an opposite effect of these to factors on crystallinity of HDPE, sepiolite content has better effects to be considered separately for each recycle content. Sepiolite can be introduced as a low-cost reinforcement filler in recycling industry for tuning new compositions based on process condition, or vice versa.

Effects of conductive graphite filler loading on physical properties of high-density polyethylene composite

2012 ◽  
Vol 33 (7) ◽  
pp. 1071-1076 ◽  
Author(s):  
I. Tavman ◽  
I. Krupa ◽  
M. Omastova ◽  
M. Sarikanat ◽  
I. Novak ◽  
...  
Keyword(s):  
Physical Properties ◽  
High Density Polyethylene ◽  
Filler Loading ◽  
High Density ◽  
Polyethylene Composite

Palm Kernel Shell Filled Recycled High-Density Polyethylene: Effect of Filler Loading

2016 ◽  
Vol 857 ◽  
pp. 191-195 ◽  
Author(s):  
A. Nadiatul Husna ◽  
Bee Ying Lim ◽  
H. Salmah ◽  
Chun Hong Voon
Keyword(s):  
Thermal Stability ◽  
High Density Polyethylene ◽  
Thermo Gravimetric Analysis ◽  
Palm Kernel ◽  
Filler Loading ◽  
High Density ◽  
Gravimetric Analysis ◽  
Melt Mixing ◽  
Palm Kernel Shell ◽  
Thermal Stability Of

Palm kernel shells (PKS) filled recycled high density polyethylene (rHDPE) biocomposites were produced using melt mixing. The biocomposites were prepared on Brabender Plasticorder at temperature of 185 °C and rotor speed of 50 rpm by varying filler loading (0 to 40 phr). In this study, the effect of PKS loading on rheological properties and thermal stability of rHDPE/PKS were investigated. Rheological study of the biocomposites was carried out by means of capillary rheometer under temperature of 190 °C, 200 °C and 210 °C. Thermal properties of biocomposites were studied by using thermo gravimetric analysis (TGA). The rheological results showed that the flowability of the composite increased with increasing temperature. Meanwhile, the result of TGA showed that at higher PKS loading, rHDPE/PKS biocomposites had lower total weight loss. The thermal stability of the biocomposites was reduced due to the addition of filler loading.

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