Anomalous Behaviour of the Mean Dipole Polarizability α of Neopentane C(CH3)4 in the Temperature Range between 250 K and 360 K

1991 ◽  
Vol 46 (11) ◽  
pp. 983-988 ◽  
Author(s):  
Uwe Hohm ◽  
Klaus Kerl
Keyword(s):  
Absorption Band ◽  
Temperature Dependence ◽  
Anomalous Behaviour ◽  
Dipole Polarizability ◽  
Gaseous State ◽  
Temperature Range ◽  
Physico Chemical ◽  
The Mean ◽  
Solid Liquid

Abstract The temperature dependence of the dynamic dipole polarizability α(λ) of gaseous neopentane has been re-examined in the temperature range between T = 250 K and T - 360 K at the four HeNelaser wavelengths λ = 543.51 nm, 594.11 nm, 611.97 nm, and 632.99 nm. These interferometric measurements are compared with former determinations of the dynamic as well as the static dipole polarizability in the solid, liquid and gaseous state. In all cases, a shape of α(T) in the range between 290 K and 310 K has been observed which is similar to the shape of α (λ) in an absorption band. This observation is connected with other physico-chemical quantities of neopentane.

scholarly journals EVOLUTION OF OVER-CONDUCTIVITY OF YВа2Сu3О7-δ SINGLE CRYSTALS UNDER THE EXPOSURE OF IRRADIATION BY HIGH-ENERGY ELECTRONS

2020 ◽  
pp. 9-15
Author(s):  
N.A. Azarenkov ◽  
V.N. Voyevodin ◽  
R.V. Vovk ◽  
N.R. Vovk ◽  
G.Ya. Khadzhai ◽  
...  
Keyword(s):  
Temperature Dependence ◽  
Single Crystals ◽  
Electron Irradiation ◽  
Mean Field Theory ◽  
Mean Field ◽  
High Energy ◽  
Excess Conductivity ◽  
Crossover Point ◽  
Temperature Range ◽  
The Mean

The evolution of the excess conductivity of YВа2Сu3О7-δ single crystals upon electron irradiation is investigated. It was shown that electron irradiation leads to a significant expansion of the temperature range for the existence of excess conductivity, thereby narrowing the region of the linear dependence of ρ(Т) in the ab plane. It was found that the excess conductivity ∆σ(Т) of YВа2Сu3О7-δ single crystals in a wide temperature range Tf<Т<T* (Тf – the transition temperature from the PG to the FP mode) is subject to exponential temperature dependence. Moreover, the description of excess conductivity using the relation ∆σ ~ (1-Т/Т*)exp( ∆*ab/T) (Δ*ab – the pseudogap in ab-plane) can be interpreted in terms of the mean-field theory, where T* is presented as the mean-field temperature of the transition to the PG state, and the temperature dependence of the pseudogap is satisfactorily described in the framework of the BCS-BEC crossover theory. In this case, the value of the transverse coherence length ξс(0) increases 1.4 times and the 2D-3D crossover point shifts in temperature.

Density and Compressibility of Liquid Li-Pb Alloys

1976 ◽  
Vol 31 (1) ◽  
pp. 47-52 ◽  
Author(s):  
Henner Ruppersberg ◽  
Walter Speicher
Keyword(s):  
Temperature Dependence ◽  
Excess Volume ◽  
Adiabatic Compressibility ◽  
Ideal Solution ◽  
Velocity Of Sound ◽  
Absolute Value ◽  
Temperature Range ◽  
The Mean ◽  
The Absolute

The density and the velocity of sound of liquid Li-Pb alloys have been measured in the composition ranges 0 - 17, 30 - 100 at % Pb and 0-10, 40 - 100 at % Pb, respectively. The temperature dependence of these properties has been determined for each sample in a temperature range of at least 130 K. The excess volume is negative and has a minimum at about 20at%Pb, where the volume per atom at 800 °C is about 19% smaller than the volume of an ideal solution. The absolute value of the excess volume rises with the temperature, as does the absolute value of the deviation of the adiabatic compressibility from the mean compressibility.

Temperature Dependences in the O + OH → O2 + H Reaction. Quasiclassical Trajectory Calculation

1993 ◽  
Vol 58 (2) ◽  
pp. 234-243 ◽  
Author(s):  
Viliam Klimo ◽  
Martina Bittererová ◽  
Stanislav Biskupič ◽  
Ján Urban ◽  
Miroslav Micov
Keyword(s):  
Temperature Dependence ◽  
Energy Surface ◽  
Analytical Form ◽  
Mean Values ◽  
Quantum Numbers ◽  
Mean Lifetime ◽  
Temperature Dependences ◽  
Quasiclassical Trajectory Calculation ◽  
The Mean ◽  
Combustion Processes

The reaction O + OH → O2 + H in conditions of combustion of hydrocarbons and polymers was modelled by using the method of quasiclassical trajectories. The potential energy surface was determined by the multiconfiguration interaction method and fitted with the analytical form of the extended LEPS function. Attention was paid to the mean values of the vibrational and rotational quantum numbers of O2 molecules and their temperature dependence. The temperature dependence of the mean lifetime of the OOH collision complex was also examined. The calculated rate constants were analyzed and compared with the experimental data over the temperature region of the combustion processes.

Non-isothermal crystallization behavior of spinel crystals in FeO-SiO2-TiO2-V2O3-Cr2O3 slag

2018 ◽  
Vol 116 (1) ◽  
pp. 110
Author(s):  
Lixiong Shao ◽  
Jiang Diao ◽  
Wang Zhou ◽  
Tao Zhang ◽  
Bing Xie
Keyword(s):  
Cooling Rate ◽  
Crystallization Behavior ◽  
Crystal Size ◽  
Growth Mechanisms ◽  
Vanadium Slag ◽  
Growth Behaviour ◽  
Temperature Range ◽  
Chromium Spinel ◽  
Mean Diameter ◽  
The Mean

The growth behaviour of spinel crystals in vanadium slag with high Cr2O3 content was investigated and clarified by statistical analyses based on the Crystal Size Distribution (CSD) theory. The results indicate that low cooling rate and Cr2O3 content benefit the growth of spinel crystals. The chromium spinel crystals firstly precipitated and then acted as the heterogeneous nuclei of vanadium and titanium spinel crystals. The growth mechanisms of the spinel crystals at the cooling rate of 5 K/min consist two regimes: firstly, nucleation control in the temperature range of 1873 to 1773 K, in which the shapes of CSD curves are asymptotic; secondly, surface and supply control within the temperature range of 1773 to 1473 K, in which the shapes of CSD curves are lognormal. The mean diameter of spinel crystals increases from 3.97 to 52.21 µm with the decrease of temperature from 1873 to 1473 K.

Specific features of the temperature dependence of tryptophan fluorescence lifetime in the temperature range of −170–20 °C

2020 ◽  
Vol 393 ◽  
pp. 112435
Author(s):  
Peter P. Knox ◽  
Vladimir V. Gorokhov ◽  
Boris N. Korvatovsky ◽  
Nadezhda P. Grishanova ◽  
Sergey N. Goryachev ◽  
...  
Keyword(s):  
Temperature Dependence ◽  
Fluorescence Lifetime ◽  
Tryptophan Fluorescence ◽  
Temperature Range

35Cl NQR Spectroscopy on Salts and Molecular Compounds of Trichloroacetic Acid

1986 ◽  
Vol 41 (1-2) ◽  
pp. 215-224 ◽  
Author(s):  
Winfried Fichtner ◽  
Axel Markworth ◽  
Norbert Weiden ◽  
Alarich Weiss
Keyword(s):  
Frequency Shift ◽  
Temperature Dependence ◽  
Linear Relation ◽  
Trichloroacetic Acid ◽  
Mean Frequency ◽  
35Cl Nqr ◽  
The Mean ◽  
Molecular Compounds

The temperature dependence of salts M(1)H(Cl3CCOO)2 and molecular compounds of trichloroacetic acid with amines and benzaldehydes, TCA · X, was studied,The data fit rather well to the known dependence of the mean frequency shift Δ <v(35Cl)> on the pkadifference of X with respect to TCA. A linear relation is observed between the bleaching out temperature Tb of the 35Cl NQR lines and Δ <v(35Cl)> for M(1)H(Cl3CCOO)2 and for TCA · X, X = benzaldehydes.

scholarly journals Temperature dependence of the mean magnon collision time in a spin Seebeck device

2021 ◽  
pp. 168289
Author(s):  
Vittorio Basso ◽  
Alessandro Sola ◽  
Patrizio Ansalone ◽  
Michaela Kuepferling
Keyword(s):  
Temperature Dependence ◽  
Collision Time ◽  
The Mean

Temperature dependence of chlorine-35 N.Q.R. in 2,6-Dichlorophenol

1978 ◽  
Vol 31 (4) ◽  
pp. 791 ◽  
Author(s):  
R Chandramani ◽  
SP Basavaraju ◽  
N Devaraj
Keyword(s):  
Temperature Dependence ◽  
Room Temperature ◽  
Temperature Range ◽  
Temperature Coefficients ◽  
Brown's Method

Chlorine n.q.r, in 2,6-dichlorophenol has been investigated at temperatures from 77 K to room temperature. Two resonance lines due to chemically inequivalent sites have been observed throughout this temperature range. Torsional frequencies of the molecule have been calculated at temperatures from 77 to 300 K according to Bayer's theory and Brown's method. Also the temperature coefficients of the torsional frequencies have been calculated.

scholarly journals PSEUDO-GAP FEATURES OF INTRINSIC TUNNELING IN (HgBr2)-Bi2212 SINGLE CRYSTALS

1999 ◽  
Vol 13 (29n31) ◽  
pp. 3758-3763 ◽  
Author(s):  
AUGUST YURGENS ◽  
DAG WINKLER ◽  
TORD CLAESON ◽  
SEONG-JU HWANG ◽  
JIN-HO CHOY
Keyword(s):  
Temperature Dependence ◽  
Single Crystals ◽  
Room Temperature ◽  
Unit Cell ◽  
Superconducting Gap ◽  
Axis Direction ◽  
Temperature Range ◽  
Dynamic Conductance

The c-axis tunneling properties of both pristine Bi2212 and its HgBr 2 intercalate have been measured in the temperature range 4.2-250 K. Lithographically patterned 7-10 unit-cell heigh mesa structures on the surfaces of these single crystals were investigated. Clear SIS-like tunneling curves for current applied in the c-axis direction have been observed. The dynamic conductance d I/ d V(V) shows both sharp peaks corresponding to a superconducting gap edge and a dip feature beyond the gap, followed by a wide maximum, which persists up to a room temperature. Shape of the temperature dependence of the c-axis resistance does not change after the intercalation suggesting that a coupling between CuO 2-bilayers has little effect on the pseudogap.

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