Ein weiteres Silicat-Anion: [Si(NCSe)6]2– / A Further Silicate Anion: [Si(NCSe)6]2–
Abstract Reaction of SiCl4 with NMe4NCSe or NEt4NCSe in cold acetonitrile leads to the corresponding crystalline salts of the new hexa-coordinate silicon complex anion [Si(NCSe)6]2- (1 ] ; . Their crystallographic data were determined: [NMe4]2[Si(NCSe)6]: rhombohedral. R3̄. a = 897 pm. a = 84.1°. Z = 1. [NEt4]2[Si(NCSe)6], tetragonal modification (from pure acetonitrile): P42/m, a = 1056 pm. c - 1580 pm. Z = 2. [NEt4]2[Si(NCSe)6]. orthorhombic modification (from acetonitrile containing NEt4Cl): a = 1704 pm. b = 1986 pm. c = 1028 pm. Z = 4. N-bonding of the NCSe groups in [Si(NCSe)6]2 is proved by the X-ray structure analysis of [NMe4]2[Si(NCSe)6] and by IR spectra. The concentration dependence of the molar conductance of an acetonitrile solution of [NMe4]2[Si(NCSe)6] was studied. At low concentrations partial dissociation of the hexa-isoselenocyanatosilicate ion is observed.