scholarly journals Bio-based rigid polyurethane foam prepared from apricot stone shell-based polyol for thermal insulation application – Part 2: Morphological, mechanical, and thermal properties

BioResources ◽  
2020 ◽  
Vol 15 (3) ◽  
pp. 6080-6094
Author(s):  
Muhammed Said Fidan ◽  
Murat Ertaş
Keyword(s):  
Thermal Conductivity ◽  
Compressive Strength ◽  
Thermal Properties ◽  
Thermogravimetric Analysis ◽  
Polyurethane Foam ◽  
Flame Retardants ◽  
Compressive Modulus ◽  
Cell Diameter ◽  
Mechanical And Thermal Properties ◽  
Rigid Polyurethane Foam

The procedure for the liquefaction of apricot stone shells was reported in Part 1. Part 2 of this work determines the morphological, mechanical, and thermal properties of the bio-based rigid polyurethane foam composites (RPUFc). In this study, the thermal conductivity, compressive strength, compressive modulus, thermogravimetric analysis, flammability tests (horizontal burning and limited oxygen index (LOI)) in the flame retardants), and scanning electron microscope (SEM) (cell diameter in the SEM) tests of the RPUFc were performed and compared with control samples. The results showed the thermal conductivity (0.0342 to 0.0362 mW/mK), compressive strength (10.5 to 14.9 kPa), compressive modulus (179.9 to 180.3 kPa), decomposition and residue in the thermogravimetric analysis (230 to 491 °C, 15.31 to 21.61%), UL-94 and LOI in the flame retardants (539.5 to 591.1 mm/min, 17.8 to 18.5%), and cell diameter in the SEM (50.6 to 347.5 μm) of RPUFc attained from liquefied biomass. The results were similar to those of foams obtained from industrial RPUFs, and demonstrated that bio-based RPUFc obtained from liquefied apricot stone shells could be used as a reinforcement filler in the preparation of RPUFs, specifically in construction and insulation materials. Moreover, liquefied apricot stone shell products have potential to be fabricated into rigid polyurethane foam composites.

scholarly journals Physical Properties of Soy-Phosphate Polyol-Based Rigid Polyurethane Foams

2012 ◽  
Vol 2012 ◽  
pp. 1-8 ◽  
Author(s):  
Hongyu Fan ◽  
Ali Tekeei ◽  
Galen J. Suppes ◽  
Fu-Hung Hsieh
Keyword(s):  
Thermal Conductivity ◽  
Compressive Strength ◽  
Thermal Properties ◽  
Water Content ◽  
Polyurethane Foams ◽  
Solid Polymer ◽  
Mechanical And Thermal Properties ◽  
Blowing Agent ◽  
Isocyanate Index ◽  
Pu Foams

Water-blown rigid polyurethane (PU) foams were made from 0–50% soy-phosphate polyol (SPP) and 2–4% water as the blowing agent. The mechanical and thermal properties of these SPP-based PU foams (SPP PU foams) were investigated. SPP PU foams with higher water content had greater volume, lower density, and compressive strength. SPP PU foams with 3% water content and 20% SPP had the lowest thermal conductivity. The thermal conductivity of SPP PU foams decreased and then increased with increasing SPP percentage, resulting from the combined effects of thermal properties of the gas and solid polymer phases. Higher isocyanate density led to higher compressive strength. At the same isocyanate index, the compressive strength of some 20% SPP foams was close or similar to the control foams made from VORANOL 490.

scholarly journals Evaluation of the Performance of Bio-Based Rigid Polyurethane Foam with High Amounts of Sunflower Press Cake Particles

Materials ◽  
2021 ◽  
Vol 14 (19) ◽  
pp. 5475
Author(s):  
Agnė Kairytė ◽  
Sylwia Członka ◽  
Renata Boris ◽  
Sigitas Vėjelis
Keyword(s):  
Thermal Conductivity ◽  
Tensile Strength ◽  
Compressive Strength ◽  
Water Absorption ◽  
Polyurethane Foam ◽  
Mechanical Performance ◽  
Positive Impact ◽  
Press Cake ◽  
Rigid Polyurethane Foam ◽  
Average Cell

In the current study, rigid polyurethane foam (PUR) was modified with 10–30 wt.% sunflower press cake (SFP) filler, and its effect on performance characteristics—i.e., rheology, characteristic foaming times, apparent density, thermal conductivity, compressive strength parallel and perpendicular to the foaming directions, tensile strength, and short-term water absorption by partial immersion—was evaluated. Microstructural and statistical analyses were implemented as well. During the study, it was determined that 10–20 wt.% SFP filler showed the greatest positive impact. For instance, the thermal conductivity value improved by 9% and 17%, respectively, while mechanical performance, i.e., compressive strength, increased by 11% and 28% in the perpendicular direction and by 43% and 67% in the parallel direction. Moreover, tensile strength showed 49% and 61% increments, respectively, at 10 wt.% and 20 wt.% SFP filler. Most importantly, SFP filler-modified PUR foams were characterised by two times lower water absorption values and improved microstructures with a reduced average cell size and increased content in closed cells.

Effect of Nanosilica on Mechanical and Thermal Properties of Cement Composites for Thermal Energy Storage Materials

2015 ◽  
Vol 1131 ◽  
pp. 182-185
Author(s):  
Pongsak Jittabut
Keyword(s):  
Thermal Conductivity ◽  
Particle Size ◽  
Heat Capacity ◽  
Compressive Strength ◽  
Thermal Properties ◽  
Thermal Energy ◽  
Energy Storage Materials ◽  
Mechanical And Thermal Properties ◽  
Storage Materials ◽  
Nanosilica Particle

This research article presents the mechanical and thermal properties of cement-based composite for thermal energy storage materials. The effects of nanosilica particle size and concentration determined by mixing nanosilica particle size of 50 nm, using nanosilica were of 1-5 wt%. Thermal properties coefficients were tested using a direct measuring instrument with surface probe (ISOMET2114). The influence of nanosilica on the performance, such as compressive strength, bulk density, thermal conductivity, volume heat capacity and thermal diffusivity of hardened composite cement pastes were studied for future solar thermal energy materials with better performance. According to the development of thermal storage materials and their application environment requirement in solar thermal power, the specimens were subjected to heat at 350, and 900°C. It were observed that, before heating, the compressive strength is optimized at nanosilica amount of 4wt% at the age of 28 days. Moreover, after heating at 350 oC and 900°C, the thermal conductivity and volume heat capacity of the cement paste enriched with nanosilica were significantly lesser than that of the before heating one.

Study of the Impact of Rice Straw Particle Size on the Mechanical and Thermal Properties of Straw Lime Concretes

2022 ◽  
Author(s):  
Youssef El Moussi ◽  
Laurent Clerc ◽  
Jean-Charles Benezet
Keyword(s):  
Thermal Conductivity ◽  
Particle Size ◽  
Compressive Strength ◽  
Thermal Properties ◽  
Water Absorption ◽  
Rice Straw ◽  
Absorption Capacity ◽  
Mechanical And Thermal Properties ◽  
Water Absorption Capacity ◽  
The Impact

The use of bio-based concretes performed with lignocellulosic aggregates constitute an interesting solution for reducing the energy consumption, greenhouse gas emissions and CO2 generated by the building sector. Indeed, bio-based materials could be used as an alternative of traditional materials such as expended polystyrene and mineral resources (e.g. glass and rock wools) for insulation. Furthermore, these bio-based concretes are known for their interesting insulation properties, indeed they allow to enhance thermal properties of buildings and enables moisture management which lead to design efficient building materials. For this purpose, bio-based concrete using rice straw as aggregate are studied in this present work. The impact of the characteristics of rice straw particle (particle size distribution, bulk density, and water absorption capacity, etc.) on both the mechanical and thermal properties of the bio-based concrete are investigated. Five formulations of rice straw concrete are examined, compared and then classified in terms of insulation properties and mechanical properties. The assessments are based on the measurement of density and thermal conductivity. The variation of compressive strength in function of the characteristics (mean particle length) of rice straw particle are assessed and discussed. The investigation covers also the porosity and density. Tests are also carried out on agricultural by-products with a view to highlight their chemical, physical and structural proprieties. The results show that the use of large particles with low water absorption capacity induce lighter concretes with the density between 339 and 505 kg/m3 and lead to a high compressive strength with a high mechanical deformability. Furthermore, it appears that an increase in the average length of rice straw particle lead to decrease of thermal conductivity of bio-based concretes. It varies from 0.062 to 0.085 W/(m.K).

Mechanical and Thermal Properties of PCM Wallboards Based on Gypsum and Paraffin

2011 ◽  
Vol 71-78 ◽  
pp. 3553-3557
Author(s):  
Xiao Peng Wang ◽  
Zhen Qiu Shen ◽  
Yi Zhang ◽  
Dong Xu Li
Keyword(s):  
Thermal Conductivity ◽  
Compressive Strength ◽  
Thermal Properties ◽  
Energy Consumption ◽  
Building Energy ◽  
Building Envelope ◽  
Mechanical And Thermal Properties ◽  
Building Energy Consumption

This paper studied on preparation, mechanical and thermal properties of two PCM wallboards made of gypsum and paraffin composite, PCM particles wallboard and PCM bag packed wallboard. Density, flexural and compressive strength and thermal conductivity of PCM particles wallboards deceased as PCM particles dosage increasing. Only PCM particles wallboard with PCM particles dosage 30% is suitable. Thermal comparison between PCM wallboards and pure gypsum wallboard shows that two PCM wallboards have better thermal properties and PCM wallboards can be used in building envelope to cut down building energy-consumption.

Effect of Nano-TiO2 on Mechanical and Thermal Properties of Cement Composites for Thermal Energy Storage Materials

2015 ◽  
Vol 804 ◽  
pp. 115-118
Author(s):  
Pongsak Jittabut
Keyword(s):  
Thermal Conductivity ◽  
Heat Capacity ◽  
Compressive Strength ◽  
Thermal Properties ◽  
Energy Storage ◽  
Thermal Energy ◽  
Thermal Energy Storage ◽  
Energy Storage Materials ◽  
Mechanical And Thermal Properties ◽  
Storage Materials

This research article presents the mechanical and thermal properties of cement-based composite for thermal energy storage materials enriched with containing nanoTiO2 particle size (25 nm) and concentration (1-5 wt.%) were systematically investigated. Thermal properties coefficients were tested using a direct measuring instrument with surface probe (ISOMET2114). The influence of nanoTiO2 on the performance, such as compressive strength, bulk density, thermal conductivity, volume heat capacity and thermal diffusivity of hardened composite cement pastes were studied for future solar thermal energy materials with better performance. According to the development of thermal storage materials and their application environment requirement in solar thermal power, the specimens were subjected to heat at 350°C and 900°C. It was observed that, before heating, the compressive strength is optimized at nanoTiO2 amount of 2 wt%. Moreover, after heating at 350 °C and 900°C, the thermal conductivity and volume heat capacity of the cement paste enriched with nanoTiO2 were significantly lesser than that of the before heating one.

Effect of ZrO2 and MgO Addition on Structure, Mechanical and Thermal Properties of Metakaolin-Based Geopolymer Composites

2019 ◽  
Vol 798 ◽  
pp. 298-303 ◽  
Author(s):  
Rewadee Wongmaneerung
Keyword(s):  
Thermal Conductivity ◽  
Compressive Strength ◽  
Thermal Properties ◽  
Phase Formation ◽  
Sodium Hydroxide Solution ◽  
Conductivity Measurement ◽  
Green Building ◽  
Sodium Silicate Solution ◽  
Mechanical And Thermal Properties ◽  
Geopolymer Composites

This research studies the fabrication and properties of reinforced-geopolymer composites for Green Building. The study comprises of phase formation, microstructure, mechanical and thermal properties. Metakaolin-based geopolymer has been fabricated from calcined kaolin at 750 °C for 6 h. Sodium hydroxide solution with 10 M and sodium silicate solution were used as alkaline activators. The ratio between metakaolin and solution was 1:1.25. Two reinforcements; ZrO2 and MgO at the composition of 0, 1, 3, 5, 7 and 9 wt% were added, then well-mixed together. After casting in acrylic mold, samples were cured at 50 °C for 72 h and then stored in air for 7 and 28 days. Phase formation, microstructure, compressive strength and thermal conductivity were determined by XRD, SEM, universal testing and thermal conductivity measurement, respectively. The results revealed that after stored for 28 days, XRD patterns of geopolymer with and without reinforcements show typical amorphous characteristic. Microstructure observation revealed the dense and heterogenous. The addition both of reinforcements has no effect on the geopolymerization reaction. Compressive strength tends to increase with increasing the amount of MgO content. Moreover, thermal conductivity slightly increased with the amounts of ZrO2 and MgO increase.

Lightweight Gypsum-Based Material, Foamed by Lime Dust and Acid Agent

2015 ◽  
Vol 729 ◽  
pp. 3-8
Author(s):  
Mst Nazmunnahar ◽  
Alena Vimmrova
Keyword(s):  
Thermal Conductivity ◽  
Compressive Strength ◽  
Thermal Properties ◽  
Bulk Density ◽  
Mechanical And Thermal Properties ◽  
Lightweight Material ◽  
Acid Agent ◽  
Stone Dust

Lightweight gypsum materials foamed by the help of stone dust were investigated. Lightweight material prepared from the gypsum as a main binder and foamed by stone dust and acid agent. The materials with the bulk density are 607 kg/m3, compressive strength about 1.3 MPa and thermal conductivity was prepared. Basic physical, mechanical and thermal properties were investigated.

scholarly journals The Effect of Multiwalled Carbon Nanotubes on the Thermal Conductivity and Cellular Size of Polyurethane Foam

2021 ◽  
Vol 2021 ◽  
pp. 1-8
Author(s):  
Huynh Mai Duc ◽  
Dat Nguyen Huu ◽  
Trung Tran Huu ◽  
Lu Le Trong ◽  
Hai Luong Nhu ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Carbon Nanotubes ◽  
Compressive Strength ◽  
Fourier Transform ◽  
Thermal Properties ◽  
Multiwalled Carbon Nanotubes ◽  
Mechanical And Thermal Properties ◽  
Multiwalled Carbon ◽  
Sem Images ◽  
Pu Foam

Polyurethane (PU) foam is known as the popular material for the applications in many fields of industry and life. To improve the mechanical and thermal properties of this material, in this research, PU foam was reinforced with aniline-modified multiwalled carbon nanotubes (MWCNTs). Fourier transform infrared FTIR spectrum of modified MWCNTs showed the aniline was grafted on the surface of MWCNTs through the appearance of –NH2 stretches. The effect of MWCNTs with and without modification on the density, porosity, compressive strength, and heat conductivity of PU/MWCNT foam nanocomposites was investigated. The dispersibility of MWCNTs in the PU matrix was enhanced after modification with aniline. Compressive strength of PU nanocomposite reached the highest value after adding 3 wt.% of modified MWCNTs into PU foam. Besides, the water uptake of PU nanocomposites using 3 wt.% of MWCNTs was decreased to 13.4% as compared to that using unmodified MWCNTs. The improvement in thermal conductivity of PU/aniline-modified MWCNT nanocomposite was observed due to the change in the cellular size of PU foam in the presence of MWCNTs as shown by SEM images.

scholarly journals Mechanical and thermal properties of cockles shell cementing material

2019 ◽  
Vol 13 (26) ◽  
pp. 107-111
Author(s):  
Aseel Basim Al-Zubaidi
Keyword(s):  
Thermal Conductivity ◽  
Compressive Strength ◽  
Thermal Properties ◽  
Portland Cement ◽  
Ordinary Portland Cement ◽  
Mechanical And Thermal Properties ◽  
Cementing Material ◽  
Shell Powder

Mortar of ordinary Portland cement was blended with cockles shellpowder at different weight ratios to investigate the effect of powderadmixture on their strength and thermal conductivity. Results showedthat addition of cockles shell powder at 50% of mortar weightimproves hardness and compressive strength notably and reduces thethermal conductivity of the end product. Results suggest thepossibility to incorporate cockles shell powders as constituents incement mortars for construction and plastering applications.

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