Transparent silica gel–PMMA composites

1989 ◽  
Vol 4 (4) ◽  
pp. 1018-1026 ◽  
Author(s):  
E. J. A. Pope ◽  
M. Asami ◽  
J. D. Mackenzie
Keyword(s):  
Compressive Strength ◽  
Refractive Index ◽  
Polymer Composites ◽  
Silica Gel ◽  
Vickers Hardness ◽  
Modulus Of Rupture ◽  
New Class ◽  
Abrasion Rate ◽  
Organic Monomer

Transparent silica gel–polymer composites have been prepared by the impregnation of porous gels with organic monomer and polymerization in situ. The relative amount of each phase was adjusted by varying the porosity of the silica gel prior to impregnation. These materials constitute a new class of transparent composites. Properties, such as density, refractive index, modulus of rupture, compressive strength, abrasion rate, and Vickers hardness, have been measured over the compositional range of 100% silica to 100% polymethyl methacrylate (PMMA).

Properties of Transparent Silica Gel - Pmma Composites

1988 ◽  
Vol 132 ◽  
Author(s):  
Edward J. A. Pope ◽  
Minuo Asami ◽  
John D. Mackenzie
Keyword(s):  
Polymer Composites ◽  
Silica Gel ◽  
Porous Silica ◽  
Silica Gels ◽  
New Class ◽  
Transparent Composites ◽  
Organic Monomer

ABSTRACTTransparent silica gel - polymer composites have been prepared by the impregnation of porous silica gels with fluid organic monomer followed by in situ polymerization. These materials constitute an entirely new class of transparent composites.

scholarly journals Maleimide Functionalized Siloxane Resins

1999 ◽  
Vol 576 ◽  
Author(s):  
R. M. Shaltout ◽  
D. A. Loy ◽  
D. R. Wheeler
Keyword(s):  
Diels Alder ◽  
Inorganic Filler ◽  
Side Reactions ◽  
Inorganic Component ◽  
New Class ◽  
Silicon Alkoxides ◽  
Filler Phase ◽  
Alder Adduct ◽  
Organic Monomer

ABSTRACTIn-situ filling through hydrolysis and condensation of silicon alkoxides dissolved into polymers has been utilized to generate nanocomposites in which the filler phase can be intimately associated with the polymer on relatively small length scales. One problem of the method has been achieving useful fill volumes without bulk phase separation of the growing inorganic component from the polymer. In this paper, we describe the preparation of a new class of nanocomposite materials in which the inorganic filler phase is pre-assembled before copolymerization with an organic monomer. Maleimide monomers, prepared from alkoxysilylpropyl amines and maleic anhydride, were protected against side reactions by forming the oxonorbornene Diels-Alder adduct with furan. The monomers were then reacted under solgel conditions to form oligomers or polymers making up the filler phase. The material was activated by thermal deprotection of the maleimide and reacted with organic monomers or polymers to form the filled nanocomposite.

scholarly journals In-Situ Synthesis, Microstructure, and Mechanical Properties of TiB2-Reinforced Fe-Cr-Mn-Al Steel Matrix Composites Prepared by Spark Plasma Sintering

Materials ◽  
2021 ◽  
Vol 14 (9) ◽  
pp. 2346
Author(s):  
Jian Liu ◽  
Min Wu ◽  
Jian Chen ◽  
Zibo Ye ◽  
Cheng Lin ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Compressive Strength ◽  
Vickers Hardness ◽  
Volume Fraction ◽  
In Situ Synthesis ◽  
Steel Matrix ◽  
Matrix Composites ◽  
Plasma Sintering ◽  
Spark Plasma

In-situ synthesis, microstructure, and mechanical properties of four TiB2-Reinforced Fe-Cr-Mn-Al Steel Matrix Composites have been researched in this work. The microstructure and phases of the prepared specimens have been characterized by using scanning electron microscopy (SEM), X-ray diffraction technique, and transmission electron microscopy (TEM). The sintered specimens consisted of Fe2AlCr, CrFeB-type boride, and TiB2. The mechanical properties, such as hardness and compression strength at room temperature (RT) and at elevated temperatures (600 °C and 800 °C) have been evaluated. The compressive strength and Vickers hardness of the sintered specimens increase with the volume fraction of TiB2 in the matrix, which are all much higher than those of the ex-situ TiB2/Fe-15Cr-20Mn-8Al composites and the reported TiB2/Fe-Cr composites with the same volume fraction of TiB2. The highest Vickers hardness and compressive strength at room temperature are 1213 ± 35 HV and 3500 ± 20 MPa, respectively. As the testing temperature increases to 600 °C, or even 800 °C, these composites still show relatively high compressive strength. Precipitation strengthening of CrFeB and in-situ synthesis of TiB2 as well as nanocrystalline microstructure produced by the combination of mechanical alloying (MA) and spark plasma sintering (SPS) can account for the high Vickers hardness and compressive strength.

scholarly journals Polymer Composites with 0.98 Transparencies and Small Optical Energy Band Gap Using a Promising Green Methodology: Structural and Optical Properties

Polymers ◽  
2021 ◽  
Vol 13 (10) ◽  
pp. 1648
Author(s):  
Muaffaq M. Nofal ◽  
Shujahadeen B. Aziz ◽  
Jihad M. Hadi ◽  
Wrya O. Karim ◽  
Elham M. A. Dannoun ◽  
...  
Keyword(s):  
Refractive Index ◽  
Optical Properties ◽  
Polymer Composites ◽  
Amorphous Phase ◽  
Absorption Edge ◽  
Complex Form ◽  
Bandgap Energy ◽  
Optical Parameters ◽  
Visible Spectroscopy ◽  
Uv Visible

In this work, a green approach was implemented to prepare polymer composites using polyvinyl alcohol polymer and the extract of black tea leaves (polyphenols) in a complex form with Co2+ ions. A range of techniques was used to characterize the Co2+ complex and polymer composite, such as Ultraviolet–visible (UV-Visible) spectroscopy, Fourier transform infrared spectroscopy (FTIR), and X-ray diffraction (XRD). The optical parameters of absorption edge, refractive index (n), dielectric properties including real and imaginary parts (εr, and εi) were also investigated. The FRIR and XRD spectra were used to examine the compatibility between the PVA polymer and Co2+-polyphenol complex. The extent of interaction was evidenced from the shifts and change in the intensity of the peaks. The relatively wide amorphous phase in PVA polymer increased upon insertion of the Co2+-polyphenol complex. The amorphous character of the Co2+ complex was emphasized with the appearance of a hump in the XRD pattern. From UV-Visible spectroscopy, the optical properties, such as absorption edge, refractive index (n), (εr), (εi), and bandgap energy (Eg) of parent PVA and composite films were specified. The Eg of PVA was lowered from 5.8 to 1.82 eV upon addition of 45 mL of Co2+-polyphenol complex. The N/m* was calculated from the optical dielectric function. Ultimately, various types of electronic transitions within the polymer composites were specified using Tauc’s method. The direct bandgap (DBG) treatment of polymer composites with a developed amorphous phase is fundamental for commercialization in optoelectronic devices.

Mechanical Properties and Decay Resistance of Wood Polymer Composites (WPC)

2011 ◽  
Vol 264-265 ◽  
pp. 819-824 ◽  
Author(s):  
Md. Rezaur Rahman ◽  
Sinin Hamdan ◽  
M. Saiful Islam ◽  
Md. Shahjahan Mondol
Keyword(s):  
Polymer Composites ◽  
Young’S Modulus ◽  
Modulus Of Elasticity ◽  
Young's Modulus ◽  
Decay Resistance ◽  
Modulus Of Rupture ◽  
Wood Polymer ◽  
Static Young’S Modulus ◽  
Wood Polymer Composites ◽  
Wood Polymer Composite

In Malaysia, especially Borneo Island Sarawak has a large scale of tropical wood species. In this study, selected raw tropical wood species namely Artocarpus Elasticus, Artocarpus Rigidus, Xylopia Spp, Koompassia Malaccensis and Eugenia Spp were chemically treated with sodium meta periodate to convert them into wood polymer composites. Manufactured wood polymer composites were characterized using mechanical testing (modulus of elasticity (MOE), modulus of rupture (MOR), static Young’s modulus) and decay resistance test. Modulus of elasticity and modulus of rupture were calculated using three point bending test. Static Young’s modulus and decay resistance were calculated using compression parallel to gain test and natural laboratory decay test respectively. The manufactured wood polymer composites yielded higher modulus of elasticity, modulus of rupture and static Young’s modulus. Wood polymer composite had high resistant to decay exposure, while Eugenia Spp wood polymer composite had highly resistant compared to the other ones.

scholarly journals Identifying Spatial and Temporal Variations in Concrete Bridges with Ground Penetrating Radar Attributes

2021 ◽  
Vol 13 (9) ◽  
pp. 1846
Author(s):  
Vivek Kumar ◽  
Isabel M. Morris ◽  
Santiago A. Lopez ◽  
Branko Glisic
Keyword(s):  
Compressive Strength ◽  
Ground Penetrating Radar ◽  
Material Properties ◽  
Temporal Variations ◽  
Concrete Bridges ◽  
Spatial And Temporal Variation ◽  
Reflected Waves ◽  
Ground Penetrating ◽  
Over Time

Estimating variations in material properties over space and time is essential for the purposes of structural health monitoring (SHM), mandated inspection, and insurance of civil infrastructure. Properties such as compressive strength evolve over time and are reflective of the overall condition of the aging infrastructure. Concrete structures pose an additional challenge due to the inherent spatial variability of material properties over large length scales. In recent years, nondestructive approaches such as rebound hammer and ultrasonic velocity have been used to determine the in situ material properties of concrete with a focus on the compressive strength. However, these methods require personnel expertise, careful data collection, and high investment. This paper presents a novel approach using ground penetrating radar (GPR) to estimate the variability of in situ material properties over time and space for assessment of concrete bridges. The results show that attributes (or features) of the GPR data such as raw average amplitudes can be used to identify differences in compressive strength across the deck of a concrete bridge. Attributes such as instantaneous amplitudes and intensity of reflected waves are useful in predicting the material properties such as compressive strength, porosity, and density. For compressive strength, one alternative approach of the Maturity Index (MI) was used to estimate the present values and compare with GPR estimated values. The results show that GPR attributes could be successfully used for identifying spatial and temporal variation of concrete properties. Finally, discussions are presented regarding their suitability and limitations for field applications.

Selected Properties of Parallel Strand Lumber Made from Southern Pine and Yellow-Poplar

Holzforschung ◽  
2003 ◽  
Vol 57 (2) ◽  
pp. 207-212 ◽  
Author(s):  
Y. Liu ◽  
A.W.C. Lee
Keyword(s):  
Compressive Strength ◽  
Shear Strength ◽  
Specific Gravity ◽  
Moisture Content ◽  
Dimensional Stability ◽  
Modulus Of Rupture ◽  
Southern Pine ◽  
Yellow Poplar ◽  
Average Modulus ◽  
Parallel Strand Lumber

Summary This study was conducted to explore basic physical and mechanical properties of parallel strand lumber (PSL) made exclusively from southern pine and yellow-poplar, respectively, and to examine their relationships using statistical analysis. Small specimens were prepared from commercial southern pine PSL and yellow-poplar PSL billets and tested for specific gravity, moisture content, dimensional stability, bending properties, shear strength and compressive strength. Results indicate average specific gravity of southern pine PSL is higher than that of yellow-poplar PSL, while their average moisture content and dimensional stability are very similar. Southern pine PSL has higher average modulus of elasticity but lower average modulus of rupture than yellow-poplar PSL. While average longitudinal shear strength does not exhibit differences between southern pine PSL and yellow-poplar PSL, average compressive strength of southern pine PSL is higher than that of yellow-poplar PSL. There are positive correlations among modulus of elasticity, modulus of rupture and specific gravity. PSL improves some properties of solid wood from which PSL is made.

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