Phase equilibria and structural chemistry in the ternary systems M–Si–N and M–B–N (M = Al, Cu, Zn, Ag, Cd, In, Sn, Sb, Au, Tl, Pb, Bi)

1990 ◽  
Vol 5 (10) ◽  
pp. 2152-2159 ◽  
Author(s):  
F. Weitzer ◽  
K. Remschnig ◽  
J. C. Schuster ◽  
P. Rogl
Keyword(s):  
Melting Point ◽  
Phase Equilibria ◽  
Ternary Systems ◽  
Compound Formation ◽  
Isothermal Sections ◽  
X Ray ◽  
Cell Dimensions ◽  
Powder Analysis ◽  
Binary Compounds ◽  
Unit Cell Dimensions

Phase equilibria in the ternary systems M–Si–N and M–B–N (M = Cu, Ag, Au, Zn, Cd, Al, In, Tl, Sn, Pb, Sb, and Bi) at temperatures 50–100 °C below the melting point of the metal components were investigated by means of x-ray powder analysis and are represented in the form of isothermal sections. No ternary compound formation was observed in any of the combinations M–Si–N and M–B–N. Silicon nitride and boron nitride, respectively, coexist with all metals investigated and with all binary compounds stable at the chosen temperatures. From unit cell dimensions negligible mutual solid solubilities are indicated between Si3N4 or BN and the metal components.

Phase Equilibria in the Er-Cu-V and Dy-Cu-V at 773K

2013 ◽  
Vol 815 ◽  
pp. 3-7
Author(s):  
Shi Ping Guo ◽  
Wei He ◽  
Yun Hong Zhao ◽  
Ling Min Zeng
Keyword(s):  
Isothermal Section ◽  
Phase Equilibria ◽  
Ternary Compound ◽  
Single Phase ◽  
Ternary Systems ◽  
Two Phase ◽  
Isothermal Sections ◽  
Three Phase ◽  
Binary Compounds

The isothermal sections of the Er-Cu-V and Dy-Cu-V ternary systems at 773K were investigated by experiments. The isothermal section of Er-Cu-V consists of 8 single-phase regions, 13 two-phase regions and 6 three-phase regions. The binary compounds ErCu5, ErCu2, ErCu, Er2Cu9and Er2Cu7were observed at 773K. The isothermal section of Dy-Cu-V consists of 7 single-phase regions, 11 two-phase regions and 5 three-phase regions. The binary compounds DyCu5, DyCu2, DyCu and Dy2Cu9were confirmed at 773K. No ternary compound was found in the two sections. There is no solubility of V in the Er-Cu and Dy-Cu binary compounds observed.

scholarly journals Phase equilibria in the ternary Ag-Au-Ga system: Isothermal sections at 250°C and 450°C

2017 ◽  
Vol 53 (3) ◽  
pp. 215-222 ◽  
Author(s):  
D. Jendrzejczyk-Handzlik
Keyword(s):  
Phase Equilibria ◽  
Ternary Systems ◽  
X Ray Diffraction ◽  
Isothermal Sections ◽  
X Ray ◽  
Ternary Compounds ◽  
Literature Overview ◽  
Eds Analysis ◽  
Two Temperatures ◽  
Scanning Electron

The ternary Ag-Au-Ga system seems to be interesting in jeweller?s craft as a joint. Moreover, the ternary systems based on gold and silver have found applications in the dental industry. A literature overview of the Ag-Au-Ga system shows that the information about phase equilibria of this system does not exist. In the present work, phase equilibria in the Ag-Au-Ga ternary system have been studied by using scanning electron microscopy (SEM) with energy dispersive spectroscopy (EDS) analysis and X-ray diffraction analysis (XRD). Twenty two annealed alloys in the 10-70 at.% Ga region have been investigated. Obtained experimental results were compared with the predicted isothermal sections at two temperatures (250?C and 450?C). No ternary compounds are found.

The Crystal Structure of Vanillosmopsis-Derived (-) α-Bisabolol p-Phenylazophenylurethane

1989 ◽  
Vol 42 (11) ◽  
pp. 2041 ◽  
Author(s):  
RM Carman ◽  
WT Robinson ◽  
MD Sutherland
Keyword(s):  
Crystal Structure ◽  
Melting Point ◽  
Diffraction Pattern ◽  
Optical Rotation ◽  
Unit Cell ◽  
X Ray Diffraction ◽  
X Ray ◽  
Cell Dimensions ◽  
Unit Cell Dimensions

The p-phenylazophenylurethane of Vanillosmopsis-derived (-)-α-bisabolol has unit cell dimensions and an X-ray diffraction pattern identical with those reported for the p-phenylazophenylurethane of Matricaria-derived (-)-α-bisabolol, despite having a higher melting point and different optical rotation.

The External Shape of Human γ GI Immunoglobulin from Crystal Sections

1971 ◽  
Vol 29 ◽  
pp. 428-429
Author(s):  
L. W. Labaw
Keyword(s):  
Molecular Weight ◽  
Sodium Phosphate ◽  
Osmium Tetroxide ◽  
Unit Cell ◽  
Monoclinic Space Group ◽  
X Ray ◽  
Large Molecular Weight ◽  
Cell Dimensions ◽  
Unit Cell Dimensions ◽  
Crystallographic Axes

Crystals of a human γGl immunoglobulin have the external morphology of diamond shaped prisms. X-ray studies have shown them to be monoclinic, space group C2, with 2 molecules per unit cell. The unit cell dimensions are a = 194.1, b = 91.7, c = 51.6Å, 8 = 102°. The relatively large molecular weight of 151,000 and these unit cell dimensions made this a promising crystal to study in the EM.Crystals similar to those used in the x-ray studies were fixed at 5°C for three weeks in a solution of mother liquor containing 5 x 10-5M sodium phosphate, pH 7.0, and 0.03% glutaraldehyde. They were postfixed with 1% osmium tetroxide for 15 min. and embedded in Maraglas the usual way. Sections were cut perpendicular to the three crystallographic axes. Such a section cut with its plane perpendicular to the z direction is shown in Fig. 1.This projection of the crystal in the z direction shows periodicities in at least four different directions but these are only seen clearly by sighting obliquely along the micrograph.

The crystal and molecular structure of tris(pentamethylenedithiocarbamate) chromium(III)-chloroform (1 : 2)

1981 ◽  
Vol 46 (1) ◽  
pp. 6-19 ◽  
Author(s):  
Viktor Kettman ◽  
Ján Garaj ◽  
Jaroslav Majer
Keyword(s):  
Molecular Structure ◽  
Structural Analysis ◽  
Crystal And Molecular Structure ◽  
Analysis Method ◽  
Complex Molecules ◽  
Coordination Polyhedra ◽  
X Ray ◽  
Cell Dimensions ◽  
Crustal Density ◽  
Unit Cell Dimensions

The crystal and molecular structure of [Cr(S2CN(CH2)5)3].2 CHCl3 was found by the X-ray structural analysis method. The value R 0.090 was found for 1 131 observed independent reflections. The substance crystallizes in a space group of symmetry P212121 with the following unit cell dimensions: a = 0.8675 (6), b = 1.815(2), c = 2.155(3) nm. The experimentally observed crustal density was 1.48 Mgm-3 and the value calculated for Z = 4 was 1.51 Mgm-3. The CrS6 coordination polyhedron has the shape of a trigonally distorted octahedron, where the D3 symmetry is a approximately retained. The degree of trigonal distortion expressed as the projection of the chelate S-Cr-S angle onto the plane perpendicular to the C3 pseudo axis is Φ = 41.7° (Φ = 60° for an octahedron). The skeleton of the structure formed by the complex molecules contains channels filled with chloroform molecules. The specific type of complex-chloroform interaction consists of the formation of hydrogen bonds of the chloroform protons with the fully occupied pπ-orbitals of the sulphur atoms in the coordination polyhedra. The low stability and crystal decomposition can be explained by loss of chloroform from the channels.

Crystallization and preliminary X-ray diffraction studies of human catalase

1999 ◽  
Vol 55 (9) ◽  
pp. 1614-1615 ◽  
Author(s):  
R. A. P. Nagem ◽  
E. A. L. Martins ◽  
V. M. Gonçalves ◽  
R. Aparício ◽  
I. Polikarpov
Keyword(s):  
Search Model ◽  
Molecular Replacement ◽  
X Ray Diffraction ◽  
Beef Liver ◽  
X Ray ◽  
Diffusion Technique ◽  
Cell Dimensions ◽  
Synchrotron Radiation Diffraction ◽  
Replacement Solution ◽  
Unit Cell Dimensions

The enzyme catalase (H2O2–H2O2 oxidoreductase; E.C. 11.1.6) was purified from haemolysate of human placenta and crystallized using the vapour-diffusion technique. Synchrotron-radiation diffraction data have been collected to 1.76 Å resolution. The enzyme crystallized in the space group P212121, with unit-cell dimensions a = 83.6, b = 139.4, c = 227.5 Å. A molecular-replacement solution of the structure has been obtained using beef liver catalase (PDB code 4blc) as a search model.

The high-pressure cadmium borate Cd6B22O39·H2O

2015 ◽  
Vol 70 (3) ◽  
pp. 183-190 ◽  
Author(s):  
Gerhard Sohr ◽  
Nina Ciaghi ◽  
Klaus Wurst ◽  
Hubert Huppertz
Keyword(s):  
High Pressure ◽  
High Temperature ◽  
Structural Characteristics ◽  
X Ray Diffraction ◽  
X Ray ◽  
High Pressure High Temperature ◽  
Cell Dimensions ◽  
Temperature Experiment ◽  
Unit Cell Dimensions ◽  
Ir And Raman

AbstractSingle crystals of the hydrous cadmium borate Cd6B22O39·H2O were obtained through a high-pressure/high-temperature experiment at 4.7 GPa and 1000 °C using a Walker-type multianvil apparatus. CdO and partially hydrolyzed B2O3 were used as starting materials. A single crystal X-ray diffraction study has revealed that the structure of Cd6B22O39·H2O is similar to that of the type M6B22O39·H2O (M=Fe, Co). Layers of corner-sharing BO4 groups are interconnected by BO3 groups to form channels containing the metal cations, which are six- and eight-fold coordinated by oxygen atoms. The compound crystallizes in the space group Pnma (no. 62) [R1=0.0379, wR2=0.0552 (all data)] with the unit cell dimensions a=1837.79(5), b=777.92(2), c=819.08(3) pm, and V=1171.00(6) Å3. The IR and Raman spectra reflect the structural characteristics of Cd6B22O39·H2O.

X-Ray and Optical Data for a Rare Earth–Poor Eudialyte from the North–Central Alaska Range

1990 ◽  
Vol 5 (2) ◽  
pp. 89-92 ◽  
Author(s):  
Neil E. Johnson ◽  
Mickey E. Gunter ◽  
Diana N. Solie ◽  
Charles R. Knowles
Keyword(s):  
Rare Earth ◽  
Powder Diffraction ◽  
Weight Percent ◽  
Optical Data ◽  
Alaska Range ◽  
North Central ◽  
X Ray ◽  
The North ◽  
Cell Dimensions ◽  
Unit Cell Dimensions

AbstractPowder X-ray and optical data have been recorded for a sample of exceptionally rare earth-poor eudialyte (Na12(Ca, REE)6(Fe2+,Mn,Mg)3Zr3(Zr,Nb)x[Si9O27−y(OH)y]2[Si3O9]2(C1,F)z, with x = 0. 1–0.9, y = 1–3 and z = 0.7–1.4) from a pegmatitic vein associated with the peralkaline Windy Fork granite in the north–central Alaska range. The eudialyte is uniaxial positive with ω= 1.6062(2), ε= 1.6138 (3) and microprobe analyses indicate that the sum of REE + Yis less than 0.1 weight percent. Refined unit cell dimensions are: a = 14.2572(4), c = 30.1338(27), Dx= 2.67, F30= 128 (0.006, 42), M20= 76. An indexed powder diffraction pattern is given.

X–Ray Powder Diffraction Data for Synthetic Varieties of Tetrahedrite

1991 ◽  
Vol 6 (1) ◽  
pp. 43-47 ◽  
Author(s):  
Neil E. Johnson
Keyword(s):  
Powder Diffraction ◽  
Experimental Unit ◽  
Regression Equations ◽  
Powder Diffraction Data ◽  
X Ray Diffraction ◽  
X Ray ◽  
Validation Test ◽  
Cell Dimensions ◽  
Synthetic Varieties ◽  
Unit Cell Dimensions

AbstractA series of five synthetic tetrahedrite-group minerals has been prepared and examined using powder X-ray diffraction in order to update current powder data and provide a validation test of cell dimension prediction equations. The tetrahedrites (nominally (Cu10X2)Sb4S13 with X = Zn, Cd, Mn, Hg and Fe) have the following properties: zincian tetrahedrite, a = 10.3833 (1) Å, Dx = 4.974 (1) g/cm3, F30 = 264 (0.004, 31), M20 = 279; cadmian tetrahedrite, a = 10.5066 (1) Å, Dx = 5.073 (1) g/cm3, F30 = 208 (0.004, 37), M20 = 249; manganoan tetrahedrite, a = 10.4384 (1) Å, Dx = 4.822 (1) g/cm3, F30 = 274 (0.003, 33), M20 = 302; mercurian tetrahedrite, a = 10.5071 (1) Å, Dx = 5.570 (1) g/cm3, F30 = 150 (0.006, 35), M20 = 156; ferroan tetrahedrite, a = 10.3630 (1) Å, Dx = 5.002 (1) g/cm3, F30 = 253 (0.004, 33), M20 = 281. The experimental unit cell dimensions obtained in this study are in excellent agreement with calculated values produced using regression equations developed previously.

Crystal data and X-ray powder diffraction data of 2,4-diiodo-4-nitrophenol (disophenol), C6H3I2NO3. More precise X-ray powder diffraction data of p-nitrophenol, C6H5NO3

1996 ◽  
Vol 11 (4) ◽  
pp. 301-304
Author(s):  
Héctor Novoa de Armas ◽  
Rolando González Hernández ◽  
José Antonio Henao Martínez ◽  
Ramón Poméz Hernández
Keyword(s):  
Powder Diffraction ◽  
Diffraction Data ◽  
Unit Cell ◽  
Crystal Data ◽  
Powder Diffraction Data ◽  
Space Group ◽  
X Ray ◽  
Cell Dimensions ◽  
Unit Cell Dimensions ◽  
Monoclinic Cell

p-nitrophenol, C6H5NO3, and disophenol, C6H3I2NO3, have been investigated by means of X-ray powder diffraction. The unit cell dimensions were determined from diffractometer methods, using monochromatic CuKα1 radiation, and evaluated by indexing programs. The monoclinic cell found for p-nitrophenol was a=6.159(2) Å, b=8.890(2) Å, c=11.770(2) Å, β=103.04(2)°, Z=4, space group P21 or P2l/m, Dx=1.469 Mg/m3. The monoclinic cell found for disophenol has the dimensions a=8.886(1) Å, b=14.088(2) Å, c=8.521(1) Å, β=91.11(1)°, Z=4, space group P2, P2, Pm or P2/m, Dx=2.438 Mg/m3.

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