Improvement of Young's modulus and tensile strength of polymer impregnation and pyrolysis processed SiC/SiC composite by improved continuity of matrix

2004 ◽  
Vol 19 (8) ◽  
pp. 2377-2388 ◽  
Author(s):  
S. Ochiai ◽  
H. Okuda ◽  
S. Kimura ◽  
K. Morishita ◽  
M. Tanaka ◽  
...  
Keyword(s):  
Monte Carlo Simulation ◽  
Tensile Strength ◽  
Monte Carlo ◽  
Young’S Modulus ◽  
Young's Modulus ◽  
Shear Lag ◽  
Pyrolysis Method ◽  
The Matrix ◽  
Barium Magnesium Aluminosilicate ◽  
Polymer Impregnation

Influences of the continuity of the matrix on Young's modulus and tensile strength of unidirectional SiC/SiC mini-composite prepared by the polymer impregnation and pyrolysis method were studied experimentally by observation of appearance of matrix and tensile test and analytically by a shear lag–Monte Carlo simulation. The continuity of the matrix was improved by the addition of particles such as ZrSiO4, barium magnesium aluminosilicate, and Pyrex (borosilicate glass) into the matrix. The improved continuity of the matrix led to the increase in stress carrying capacity of the matrix and therefore to the increase in Young's modulus and tensile strength of the composite. Such a correlation between the continuity of the matrix and the property of the composite was verified numerically by the shear lag–Monte Carlo simulation.

scholarly journals Bioactive Cellulose Nanocrystal-Poly(ε-Caprolactone) Nanocomposites for Bone Tissue Engineering Applications

2021 ◽  
Vol 9 ◽  
Author(s):  
Jung Ki Hong ◽  
Shelley L. Cooke ◽  
Abby R. Whittington ◽  
Maren Roman
Keyword(s):  
Contact Angle ◽  
Tensile Strength ◽  
Calcium Phosphate ◽  
Ultimate Tensile Strength ◽  
Young’S Modulus ◽  
Young's Modulus ◽  
Mineral Formation ◽  
Water Contact ◽  
Bone Scaffolds ◽  
The Matrix

3D-printed bone scaffolds hold great promise for the individualized treatment of critical-size bone defects. Among the resorbable polymers available for use as 3D-printable scaffold materials, poly(ε-caprolactone) (PCL) has many benefits. However, its relatively low stiffness and lack of bioactivity limit its use in load-bearing bone scaffolds. This study tests the hypothesis that surface-oxidized cellulose nanocrystals (SO-CNCs), decorated with carboxyl groups, can act as multi-functional scaffold additives that (1) improve the mechanical properties of PCL and (2) induce biomineral formation upon PCL resorption. To this end, an in vitro biomineralization study was performed to assess the ability of SO-CNCs to induce the formation of calcium phosphate minerals. In addition, PCL nanocomposites containing different amounts of SO-CNCs (1, 2, 3, 5, and 10 wt%) were prepared using melt compounding extrusion and characterized in terms of Young's modulus, ultimate tensile strength, crystallinity, thermal transitions, and water contact angle. Neither sulfuric acid-hydrolyzed CNCs (SH-CNCs) nor SO-CNCs were toxic to MC3T3 preosteoblasts during a 24 h exposure at concentrations ranging from 0.25 to 3.0 mg/mL. SO-CNCs were more effective at inducing mineral formation than SH-CNCs in simulated body fluid (1x). An SO-CNC content of 10 wt% in the PCL matrix caused a more than 2-fold increase in Young's modulus (stiffness) and a more than 60% increase in ultimate tensile strength. The matrix glass transition and melting temperatures were not affected by the SO-CNCs but the crystallization temperature increased by about 5.5°C upon addition of 10 wt% SO-CNCs, the matrix crystallinity decreased from about 43 to about 40%, and the water contact angle decreased from 87 to 82.6°. The abilities of SO-CNCs to induce calcium phosphate mineral formation and increase the Young's modulus of PCL render them attractive for applications as multi-functional nanoscale additives in PCL-based bone scaffolds.

Effect of Microcrystalline Cellulose from Banana Stem Fiber on Mechanical Properties and Crystallinity of PLA Composite Films

2011 ◽  
Vol 695 ◽  
pp. 170-173 ◽  
Author(s):  
Voravadee Suchaiya ◽  
Duangdao Aht-Ong
Keyword(s):  
Tensile Strength ◽  
Young’S Modulus ◽  
Microcrystalline Cellulose ◽  
Young's Modulus ◽  
Agricultural Waste ◽  
Composite Films ◽  
Sem Image ◽  
Biocomposite Films ◽  
Twin Screw ◽  
Banana Stem

This work focused on the preparation of the biocomposite films of polylactic acid (PLA) reinforced with microcrystalline cellulose (MCC) prepared from agricultural waste, banana stem fiber, and commercial microcrystalline cellulose, Avicel PH 101. Banana stem microcrystalline cellulose (BS MCC) was prepared by three steps, delignification, bleaching, and acid hydrolysis. PLA and two types of MCC were processed using twin screw extruder and fabricated into film by a compression molding. The mechanical and crystalline behaviors of the biocomopsite films were investigated as a function of type and amount of MCC. The tensile strength and Young’s modulus of PLA composites were increased when concentration of MCC increased. Particularly, banana stem (BS MCC) can enhance tensile strength and Young’s modulus of PLA composites than the commercial MCC (Avicel PH 101) because BS MCC had better dispersion in PLA matrix than Avicel PH 101. This result was confirmed by SEM image of fractured surface of PLA composites. In addition, XRD patterns of BS MCC/PLA composites exhibited higher crystalline peak than that of Avicel PH 101/PLA composites

Effect of Castor Oil Impregnation on the Physical and Mechanical Properties of Bacterial Cellulose

2012 ◽  
Vol 3 (1) ◽  
pp. 13-26
Author(s):  
Myrtha Karina ◽  
Lucia Indrarti ◽  
Rike Yudianti ◽  
Indriyati
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Bacterial Cellulose ◽  
Young’S Modulus ◽  
Castor Oil ◽  
Young's Modulus ◽  
Physical And Mechanical Properties ◽  
Scanning Electron Micrographs ◽  
Elongation At Break ◽  
Acetone Water

The effect of castor oil on the physical and mechanical properties of bacterial cellulose is described. Bacterial cellulose (BC) was impregnated with 0.5–2% (w/v) castor oil (CO) in acetone–water, providing BCCO films. Scanning electron micrographs revealed that the castor oil penetrated the pores of the bacterial cellulose, resulting in a smoother morphology and enhanced hydrophilicity. Castor oil caused a slight change in crystallinity indices and resulted in reduced tensile strength and Young's modulus but increased elongation at break. A significant reduction in tensile strength and Young's modulus was achieved in BCCO films with 2% castor oil, and there was an improvement in elongation at break and hydrophilicity. Impregnation with castor oil, a biodegradable and safe plasticiser, resulted in less rigid and more ductile composites.

A UNIQUE APPROACH TO EXPERIMENTAL CHARACTERIZATION OF A THERMOSETTING POLYMER MATRIX FOR ICME FRAMEWORKS

2021 ◽  
Author(s):  
MICHAEL N. OLAYA ◽  
SAGAR PATIL ◽  
GREGORY M. ODEGARD ◽  
MARIANNA MAIARÙ
Keyword(s):  
Tensile Strength ◽  
Young’S Modulus ◽  
Young's Modulus ◽  
Cure Kinetics ◽  
Image Correlation ◽  
Scanning Calorimetry ◽  
Mixing Ratios ◽  
Fitting Procedure ◽  
Amine Content

A novel approach for characterization of thermosetting epoxy resins as a function of the degree of cure is presented. Density, cure kinetics, tensile strength, and Young’s modulus are experimentally characterized across four mixing ratios of DGEBF/DETDA epoxy. Dynamic differential scanning calorimetry (DSC) is used to characterize parameters for a Prout-Thompkins kinetic model unique to each mixing ratio case through a data fitting procedure. Tensile strength and Young’s modulus are then characterized using stress-strain data extracted from quasi-static, uniaxial tension tests at room temperature. Strains are measured with the 2-D digital image correlation (DIC) optical strain measurement technique. Strength tends to increase as amine content use in the formulation increases. The converse trend is observed for Young’s modulus. Density measurements also reveal an inverse relationship with amine content.

Tensile and water absorption properties of solvent cast biofilms of sugarcane leaves fibre-filled poly(lactic) acid

2018 ◽  
Vol 33 (3) ◽  
pp. 289-304 ◽  
Author(s):  
Kuhananthan Nanthakumar ◽  
Chan Ming Yeng ◽  
Koay Seong Chun
Keyword(s):  
Tensile Strength ◽  
Lactic Acid ◽  
Water Absorption ◽  
Young’S Modulus ◽  
Young's Modulus ◽  
Poly Lactic Acid ◽  
Infrared Analysis ◽  
Absorption Properties ◽  
Elongation At Break ◽  
Bleaching Treatment

This research covers the preparation of poly(lactic acid) (PLA)/sugarcane leaves fibre (SLF) biofilms via a solvent-casting method. The results showed that the tensile strength and Young’s modulus of PLA/SLF biofilms increased with the increasing of SLF content. Nevertheless, the elongation at break showed an opposite trend as compared to tensile strength and Young’s modulus of biofilms. Moreover, water absorption properties of PLA/SLF biofilms increased with the increasing of SLF content. In contrast, the tensile strength and Young’s modulus of biofilms were enhanced after bleaching treatment with hydrogen peroxide on SLF, but the elongation at break and water absorption properties of bleached biofilms were reduced due to the improvement of filler–matrix adhesion in biofilms. The tensile and water properties were further discussed using B-factor and Fick’s law, respectively. Furthermore, the functional groups of unbleached and bleached SLF were characterized by Fourier transform infrared analysis.

scholarly journals Pentaerythritol Tetrasalicylate in the Chemical Composition of Root Canal Sealers

2018 ◽  
Vol 29 (1) ◽  
pp. 48-53
Author(s):  
Manuela Gonçalves de Souza e Silva ◽  
Eliseu Aldrighi Münchow ◽  
Rafael Pino Vitti ◽  
Mário Alexandre Coelho Sinhoreti ◽  
Evandro Piva ◽  
...  
Keyword(s):  
Tensile Strength ◽  
Young’S Modulus ◽  
Root Canal ◽  
Methyl Salicylate ◽  
Young's Modulus ◽  
Setting Time ◽  
Molar Ratio ◽  
Resonance Spectroscopy ◽  
Root Canal Sealers ◽  
Diametral Tensile Strength

Abstract The aim of this study was to synthesize and evaluate physicochemical properties of a new salicylate derivative in experimental calcium-based root canal sealers. Two salicylate derivatives were synthesized for the transesterification reaction of methyl salicylate with two different alcohols (1,3-butylenoglicol disalicylate-BD and pentaerythritol tetrasalicylate -PT) in molar ratio 1:3 and 1:6, respectively. The products (BD and PT), were characterized by Fourier Transform Infrared Spectroscopy (FTIR) and Nuclear Magnetic Resonance spectroscopy (RMN). Calcium-based experimental sealers were prepared with the same catalyst paste (60% of MTA, 39% of n-ethyl-o-toluenesulfonamide, and 1% titanium dioxide) and four different concentrations of BD and PT in the base pastes (40/0 - control, 35/5, 30/10 and 20/20) with 60% of bismuth oxide. The experimental sealers were evaluated for setting time, solubility (24 h, 7, 14 and 30 days), diametral tensile strength and Young’s Modulus. Data were analyzed by one- or two-way ANOVA with Tukey’s test (p<0.05). The addition of PT reduced the materials setting time. After 24 h the sealer 40/0 and 35/5 had higher solubility, and after 14 and 28 days the sealer 20/20 showed the lowest solubility (p<0.05). After 7 days the sealer 20/20 stabilized its solubility. The sealer 40/0 presented the highest values and the 20/20 presented the lowest values of diametral tensile strength and Young’s modulus (p<0.05). The addition of PT to calcium-based root canal sealers provides benefits to the setting time and solubility.

scholarly journals Modified rule of mixtures and Halpin–Tsai model for prediction of tensile strength of micron-sized reinforced composites and Young’s modulus of multiscale reinforced composites for direct extrusion fabrication

2018 ◽  
Vol 10 (7) ◽  
pp. 168781401878528 ◽  
Author(s):  
Zirong Luo ◽  
Xin Li ◽  
Jianzhong Shang ◽  
Hong Zhu ◽  
Delei Fang
Keyword(s):  
Carbon Nanotubes ◽  
Tensile Strength ◽  
Young’S Modulus ◽  
Carbon Fibers ◽  
Epoxy Resins ◽  
Young's Modulus ◽  
Resin Matrix ◽  
Reinforced Composites ◽  
Rule Of Mixtures ◽  
Combined Use

A modified rule of mixtures is required to account for the experimentally observed nonlinear variation of tensile strength. A modified Halpin–Tsai model was presented to predict the Young’s modulus of multiscale reinforced composites with both micron-sized and nano-sized reinforcements. In the composites, both micron-sized fillers—carbon fibers—and nano-sized fillers—rubber nanoparticles and carbon nanotubes—are added into the epoxy resin matrix. Carbon fibers can help epoxy resins increase both the tensile strength and Young’s modulus, while rubber nanoparticles and carbon nanotubes can improve the toughness without sacrificing other properties. Mechanical experiments and scanning electron microscopy observations were used to study the effects of the micron-sized and nano-sized reinforcements and their combination on tensile and toughness properties of the composites. The results showed that the combined use of multiscale reinforcements had synergetic effects on both the strength and the toughness of the composites.

Sign in / Sign up

Export Citation Format

Share Document