Robustness versus Performance Assessment for Different Gamma-TiAl Processing Routes

2011 ◽  
Vol 1295 ◽  
Author(s):  
Marc Thomas

ABSTRACTOne of the main driving force for the development of advanced structural materials is weight saving especially in the transportation industry in order to reduce CO2 emission. The utilization of gamma aluminides, as good candidates for aerospace applications, is strongly related to the development of a cost-effective and robust processing route, as far as possible. It is well established that the processing route, i.e. cast, wrought or PM, has a dramatic effect on the microstructure and texture of gamma-TiAl alloys. Therefore, significant microstructural variations through post-heat treatments coupled with compositional modifications can only guarantee a proper balance of desired properties. However, a number of metallurgical factors during the processing steps can contribute to some scattering in properties. This review will highlight several critical process variables in terms of the resulting g-TiAl microstructures. Of primary importance is the as-cast texture which is difficult to control and may contribute to prefer some alternative processing routes to ensure a better repeatability in mechanical results. Some innovative processing techniques for controlling the structure will then be presented. The main point which will be discussed in this paper is whether an approach leading to a robust process would not be at the expense of the high performance of the structural material.

2007 ◽  
Vol 29-30 ◽  
pp. 127-130
Author(s):  
Colleen J. Bettles ◽  
Rimma Lapovok ◽  
H.P. Ng ◽  
Dacian Tomus ◽  
Barry C. Muddle

The range of commercial titanium alloys available is currently extremely restricted, with one alloy (Ti-6Al-4V), and derivatives of it, accounting for a very large proportion of all applications. High performance alloys are costly to fabricate and limited to low-volume applications that can sustain the cost. With the emergence of new processing technologies that promise to reduce significantly the cost of production of titanium metal, especially in powder form, there is an emerging imperative for cost-effective near net shape powder processing techniques to permit the benefit of reduced metal cost to be passed on to higher-volume applications. Equally, there is a need for the design and development of new alloys that are intrinsically low-cost and lend themselves to fabrication by novel cost-effective net shape processing. The approaches that might be used to select, design and process both conventional alloys and novel alloy systems will be reviewed, with a focus on innovation in design of low-cost alloys amenable to new processing paths and increasingly tolerant of variability in composition.


2018 ◽  
Vol 188 ◽  
pp. 04004
Author(s):  
Nicola Gallo ◽  
Silvio Pappadá ◽  
Umberto Raganato ◽  
Stefano Corvaglia

As the use of composites for high-performance structures for aerospace applications is constantly increasing, together with the complexity and scale of such structures, an increasingly effort is carried out for the development of advanced techniques for composites structural repair. Mechanical loads and environmental conditions often cause composite damages. If material damage is not extensive, structural repair is the most cost-effective solution. Composite patches can be mechanically fastened, adhesively bonded or co-cured. Bonding or co-curing process provides enhanced stress transfer mechanisms, joint efficiencies and aerodynamic performance. In this paper an innovative and reliable technique to repair damaged composite aeronautical components, named High Pressure Repair Dome (HPRD), is shown. The innovative aspect of this solution is the possibility to bond or co-cure a composite prepreg patch under a pressurized dome, thus using a prepreg compatible with the composite structure. HPRD was developed to allow in-situ repairing on full-scale structures, with the possibility of an accurate control of the parameters of the curing cycle. The advantages and performance of HPRD approach will be discussed and compared with traditional techniques, describing the results achieved and the activity on-course for the full industrialization of this system.


Author(s):  
Laraib Alam Khan ◽  
Wajid Ali Khan ◽  
S. Ahmed

This chapter gives an overview of cost effective processing techniques, employed for manufacturing of sandwich structures, primarily for high performance applications. The scope of this chapter is to review the processes which may produce the autoclave cured quality parts, without the use of autoclave. The chapter starts with an overview of autoclave processing, highlighting the different features, which depicts the capacity of technique to produce highly repeatable parts. Studies related to manufacturing of sandwich structures in autoclave, with and without adhesive film, are reviewed and discussed. Process briefs and recent developments of different out of autoclave (OOA) techniques for manufacturing of sandwich structures are then discussed which includes, OOA prepregs systems, Quickstep processing, Vacuum Infusion Process, compression molding, double belt press and filament winding. A brief overview of manufacturing processes for thermoplastic based sandwich structures is also provided at the end.


Author(s):  
K.L. More ◽  
R.A. Lowden ◽  
T.M. Besmann

Silicon nitride possesses an attractive combination of thermo-mechanical properties which makes it a strong candidate material for many structural ceramic applications. Unfortunately, many of the conventional processing techniques used to produce Si3N4, such as hot-pressing, sintering, and hot-isostatic pressing, utilize significant amounts of densification aids (Y2O3, Al2O3, MgO, etc.) which ultimately lowers the utilization temperature to well below that of pure Si3N4 and also decreases the oxidation resistance. Chemical vapor deposition (CVD) is an alternative processing method for producing pure Si3N4. However, deposits made at temperatures less than ~1200°C are usually amorphous and at slightly higher temperatures, the deposition of crystalline material requires extremely low deposition rates (~5 μm/h). Niihara and Hirai deposited crystalline α-Si3N4 at 1400°C at a deposition rate of ~730 μm/h. Hirai and Hayashi successfully lowered the CVD temperature for the growth of crystalline Si3N4 by adding TiCl4 vapor to the SiCl4, NH3, and H2 reactants. This resulted in the growth of α-Si3N4 with small amounts of TiN at temperatures as low as 1250°C.


TAPPI Journal ◽  
2018 ◽  
Vol 17 (09) ◽  
pp. 507-515 ◽  
Author(s):  
David Skuse ◽  
Mark Windebank ◽  
Tafadzwa Motsi ◽  
Guillaume Tellier

When pulp and minerals are co-processed in aqueous suspension, the mineral acts as a grinding aid, facilitating the cost-effective production of fibrils. Furthermore, this processing allows the utilization of robust industrial milling equipment. There are 40000 dry metric tons of mineral/microfbrillated (MFC) cellulose composite production capacity in operation across three continents. These mineral/MFC products have been cleared by the FDA for use as a dry and wet strength agent in coated and uncoated food contact paper and paperboard applications. We have previously reported that use of these mineral/MFC composite materials in fiber-based applications allows generally improved wet and dry mechanical properties with concomitant opportunities for cost savings, property improvements, or grade developments and that the materials can be prepared using a range of fibers and minerals. Here, we: (1) report the development of new products that offer improved performance, (2) compare the performance of these new materials with that of a range of other nanocellulosic material types, (3) illustrate the performance of these new materials in reinforcement (paper and board) and viscosification applications, and (4) discuss product form requirements for different applications.


2011 ◽  
Vol 39 (3) ◽  
pp. 193-209 ◽  
Author(s):  
H. Surendranath ◽  
M. Dunbar

Abstract Over the last few decades, finite element analysis has become an integral part of the overall tire design process. Engineers need to perform a number of different simulations to evaluate new designs and study the effect of proposed design changes. However, tires pose formidable simulation challenges due to the presence of highly nonlinear rubber compounds, embedded reinforcements, complex tread geometries, rolling contact, and large deformations. Accurate simulation requires careful consideration of these factors, resulting in the extensive turnaround time, often times prolonging the design cycle. Therefore, it is extremely critical to explore means to reduce the turnaround time while producing reliable results. Compute clusters have recently become a cost effective means to perform high performance computing (HPC). Distributed memory parallel solvers designed to take advantage of compute clusters have become increasingly popular. In this paper, we examine the use of HPC for various tire simulations and demonstrate how it can significantly reduce simulation turnaround time. Abaqus/Standard is used for routine tire simulations like footprint and steady state rolling. Abaqus/Explicit is used for transient rolling and hydroplaning simulations. The run times and scaling data corresponding to models of various sizes and complexity are presented.


2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Robert Christie

Abstract This paper presents an overview of the general chemical principles underlying the structures, synthesis and technical performance of azo pigments, the dominant chemical class of industrial organic pigments in the yellow, orange, and red shade areas, both numerically and in terms of tonnage manufactured. A description of the most significant historical features in this group of pigments is provided, starting from the discovery of the chemistry on which azo colorants are based by Griess in the mid-nineteenth century, through the commercial introduction of the most important classical azo pigments in the early twentieth century, including products known as the Hansa Yellows, β-naphthol reds, including metal salt pigments, and the diarylide yellows and oranges, to the development in the 1950s and 1960s of two classes of azo pigments that exhibit high performance, disazo condensation pigments and benzimidazolone-based azo pigments. A feature that complicates the description of the chemical structures of azo pigments is that they exist in the solid state as the ketohydrazone rather than the hydroxyazo form, in which they have been traditionally been illustrated. Numerous structural studies conducted over the years on an extensive range of azo pigments have demonstrated this feature. In this text, they are referred to throughout as azo (hydrazone) pigments. Since a common synthetic procedure is used in the manufacture of virtually all azo (hydrazone) pigments, this is discussed in some detail, including practical aspects. The procedure brings together two organic components as the fundamental starting materials, a diazo component and a coupling component. An important reason for the dominance of azo (hydrazone) pigments is that they are highly cost-effective. The syntheses generally involve low cost, commodity organic starting materials and are carried out in water as the reaction solvent, which offers obvious economic and environmental advantages. The versatility of the approach means that an immense number of products may be prepared, so that they have been adapted structurally to meet the requirements of many applications. On an industrial scale, the processes are straightforward, making use of simple, multi-purpose chemical plant. Azo pigments may be produced in virtually quantitative yields and the processes are carried out at or below ambient temperatures, thus presenting low energy requirements. Finally, provided that careful control of the reaction conditions is maintained, azo pigments may be prepared directly by an aqueous precipitation process that can optimise physical form, with control of particle size distribution, crystalline structure, and surface character. The applications of azo pigments are outlined, with more detail reserved for subsequent papers on individual products.


Molecules ◽  
2021 ◽  
Vol 26 (15) ◽  
pp. 4545
Author(s):  
Sudharsan Sadhasivam ◽  
Omer Barda ◽  
Varda Zakin ◽  
Ram Reifen ◽  
Edward Sionov

Patulin (PAT) and citrinin (CTN) are the most common mycotoxins produced by Penicillium and Aspergillus species and are often associated with fruits and fruit by-products. Hence, simple and reliable methods for monitoring these toxins in foodstuffs are required for regular quality assessment. In this study, we aimed to establish a cost-effective method for detection and quantification of PAT and CTN in pome fruits, such as apples and pears, using high-performance liquid chromatography (HPLC) coupled with spectroscopic detectors without the need for any clean-up steps. The method showed good performance in the analysis of these mycotoxins in apple and pear fruit samples with recovery ranges of 55–97% for PAT and 84–101% for CTN, respectively. The limits of detection (LOD) of PAT and CTN in fruits were 0.006 µg/g and 0.001 µg/g, while their limits of quantification (LOQ) were 0.018 µg/g and 0.003 µg/g, respectively. The present findings indicate that the newly developed HPLC method provides rapid and accurate detection of PAT and CTN in fruits.


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