The Application of Nano-Structured Silica Based Admixture in Gypsum Binders

2014 ◽  
Vol 1611 ◽  
pp. 165-170 ◽  
Author(s):  
E.V. Voitovich ◽  
A.V. Cherevatova ◽  
I.V. Zhernovsky ◽  
H.-B. Fisher ◽  
K. Sobolev

ABSTRACTThis article reports on a new composite gypsum binder (CGB) with nanostructured silica-based admixture (NSS). NSS is obtained by a wet ultrafine milling of quartz sand resulting in the formation of an inorganic polydisperse binding system, which has a high concentration of active nanoscale phase (about 10%). Developed CGB contains hemihydrate gypsum and nano-component based on quartz sand. It is observed that the addition of 15–20 % of NSS improves the rheological properties of gypsum systems through the formation of solvate shells hindering the access of water to gypsum particles; this process also retards the setting of binder.The experimental program used infrared IR spectroscopy, X-ray diffraction (XRD) and scanning electron microscopy (SEM) to reveal the contribution of NSS. The porosity of CGB is analyzed by the kinetics of water adsorption and BET. The XRD and IR investigations determined the formation of a new sulfosilicate phase, hydroxyellestadite during the hydration of CGB. With the addition of NSS an overall reduction in pore volume, as well as the shifts in macro-, meso- and nano- porosity values are observed.Analysis of CGB microstructure reveals that in the presence of the NSS the size and morphology of crystals are changed contributing to the formation of dense fine-grained structure. Experimental studies have demonstrated that the composite gypsum binders with NSS are characterized by reduced water absorption and increased density, as well as improved mechanical performance especially, higher compressive strength.

2010 ◽  
Vol 37-38 ◽  
pp. 64-67
Author(s):  
Jin Song Chen ◽  
Yin Hui Huang ◽  
Bin Qiao ◽  
Jian Ming Yang ◽  
Yi Qiang He

The principles of jet electrodeposition orientated by rapid prototyping were introduced. The nanocrystalline nickel parts with simple shape were fabricated using jet electrodeposition. The microstructure and phase transformation of nanocrystalline nickel were observed under the scanning microscope and X-ray diffraction instrument. The results show that the jet electrodeposition can greatly enhance the limited current density, fine crystalline particles and improve deposition quality. The nickel parts prepared by jet electrodeposition own a fine-grained structure (average grain size 25.6nm) with a smooth surface and high dimensional accuracy under the optimum processing parameters.


Metals ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 1488
Author(s):  
Lev B. Zuev ◽  
Galina V. Shlyakhova ◽  
Svetlana A. Barannikova

Radial forging is a reliable way to produce Ti alloy rods without preliminary mechanical processing of their surface, which is in turn a mandatory procedure during almost each stage of the existing technology. In the present research, hot pressing and radial forging (RF) of the titanium-based Ti-3.3Al-5Mo-5V alloy were carried out to study the specifics of plasticized metal flow and microstructural evolution in different sections of the rods. The structural analysis of these rods was performed using metallography and X-ray diffraction techniques. The X-ray diffraction reveals the two-phase state of the alloy. The phase content in the alloy was shown to vary upon radial forging. Finally, radial forging was found to be a reliable method to achieve the uniform fine-grained structure and high quality of the rod surface.


Author(s):  
Jodh Singh ◽  
◽  
Munish Gupta ◽  
Rajesh Kumar ◽  
Harmesh Kumar ◽  
...  

Latest trend of miniaturization of thermal systems, calls for the improvement in their efficiency. Nanofluid contains the nanoparticles having large surface area and improves the thermal efficiency. This enhancement is the function of different mechanisms and parameter. This paper explores the heat transfer nature of nanofluids by addressing the experimental studies available in literature and conducting an experimental study using water based Copper oxide nanofluids. Nanoparticles were characterized by X-ray diffraction analysis and Field Emission Scanning Electron Microscopy to confirm the material, size and morphology of the nanoparticles. Thermal conductivity analysis has been performed at 30˚C, 40˚Cand 50˚C with 0.1%,0.5% and 1% concentration by weight. Mechanism of agglomeration, concentration and size of particles are found to be more significant in affecting the heat transfer. The maximum enhancement of 22.9 % in thermal conductivity is found in case of 1% weight concentration nanofluids consisting of small size (20nm) nanoparticles at temperature of 50˚C.


1992 ◽  
Vol 6 ◽  
pp. 38-38
Author(s):  
Thomas W. Broadhead ◽  
Steven G. Driese

Small skeletal sediment particles, by virtue of their size, experience physical sedimentological conditions different from those affecting large (i.e., > 4 mm) particles. In shallow, high-energy marine carbonate environments with an overall fine-grained (< 4 mm) sediment composition, grain-to-grain impacts are probably of insufficient magnitude to overcome the cushioning effect of water and cause abrasive wear. Very large skeletal grains within such a setting will promote physical degradation, but biological activity (microboring, bioerosion) is more effective in modifying particle surfaces and diminishing grain size. Only in eolian environments are collisions between small grains effective in causing abrasion. Quartz sand, a particularly important abrasive agent in the destruction of large skeletal parts under even moderate energy regimes, also appears to be appreciably important for the degradation of small skeletons only under eolian conditions.Conodonts are small (0.2–2.0 mm), phosphatic teeth, which may have belonged to an extinct (Cambrian-Triassic) group of jawless fish. They occur principally in marine and marginal marine sedimentary rocks; most specimens probably were deposited as discrete particles or as components of fecal masses. Because the extent and nature of degradation of a skeleton reflects its taphonomic history, evaluation of the susceptibility of conodonts to physical abrasion is important. Bioerosion, probably the principal cause of degradation of calcareous skeletons, was probably insignificant in alteration of conodonts. Their mineralogical composition made conodonts unlikely substrates for endoliths, and they were insufficiently abundant to serve as a recyclable source of phosphate for larger metazoans. Chemical breakdown of skeletal apatite would not have occurred, although atmospheric exposure may have promoted degradation of organic laminae, causing exfoliation.Experimental studies of abrasion (elements of Palmatolepis sp., Polygnathus sp. - U. Devonian, Iowa) plus petrographic examination of conodont bearing marine, marginal marine, and eolian facies of the Morgan Formation (M. Pennsylvanian, Utah and Colorado) suggests that abrasion of conodonts is insignificant in aqueous environments, and likely to occur to a major degree only under eolian conditions. High-energy (25.6 cm/sec) conditions were simulated in a tumbler containing quartz sand (4Φ − 2Φ), artificial sea water and moderate conodont abundances (50 specimens/kg). Abrasion produced under these artificially extreme conditions (e.g., continuous motion for up to 20 km travel distance) was at a scale detectable only with SEM. “Dry” tumbling experiments were ineffective, as noted by other authors simulating conditions for abrasion of mineral grains. Eolian conditions were simulated in a glass “wind tube” (see Kuenen, 1960, Journal of Geology) using a similar range of quartz sand sizes. Air velocity of approximately 100 cm/sec produced subtle visually detectable abrasion following 5 hours of exposure/transport in 2Φ quartz sand (1667 specimens/kg), but exhibited no visual evidence of abrasion under similar conditions with 3Φ sand.The Morgan Formation is a mixed carbonate/siliciclastic sequence that reflects repeated episodes of submergence and exposure of a carbonate shelf and laterally adjacent siliciclastic eolian “sand sea.” It represents a virtually ideal ancient example for the interpretation of the effects of natural sedimentary processes because of its well-documented environmental heterogeneity and contains both abraded and unabraded conodonts. Conodonts sampled from high-energy subtidal carbonate facies of the Morgan are unabraded, irrespective of the presence of quartz sand; platform and delicate ramiform elements are all represented. Conodonts sampled from mixed siliciclastic/carbonate eolian facies are extremely abraded; only the most durable Pa elements of Adetognathus sp. and Idiognathodus sp. are preserved, although fine surface details and denticles are worn and anterior blades are missing. Laboratory simulations confirm the interpretation that marine processes are generally insufficient to physically abrade small phosphatic skeletal grains and that highly abraded Morgan conodonts experienced extremely long residence times in the eolian environment where they were transported, repeatedly buried, and exposed to bombardment and abrasion by quartz sand.Supported by NSF EAR9004300


2011 ◽  
Vol 287-290 ◽  
pp. 420-423
Author(s):  
Jin Song Chen

Jet electrodeposition orientated by rapid fabrication were introduced , The nanocrystalline nickel parts were fabricated using jet electrodeposition . The microstructure and phase transformation of nanocrystalline nickel were observed under the scanning microscope and X-ray diffraction instrument . The results show that the jet electrodeposition can greatly enhance the limited current density, fine crystalline particles and improve deposition quality. The nickel parts prepared by jet electrodeposition own a fine-grained structure with a smooth surface and high dimensional accuracy under the optimum processing parameters.


Author(s):  
Valerii Makarenko ◽  
Yuriy Vynnykov ◽  
Andrii Manhura

The results of experimental studies of the molybdenum impurity influence on corrosion and mechanical properties of carbonsteel (Grade 20) joint welds are presented in the article. In particular, it has been found that the highest and stable values ofthe impact strength and resistance properties of cracks (К1s and δs), as well as the resistance to sulfide corrosion cracking ofthe metal of tubular steel joints, are achieved at a concentration of molybdenum in it from 0,2 to 0,4%, which is realized byputting a molybdenum powder in the electrode coating in the amount of 0,5-1,0%. On the basis of the obtained results an optimalchemical composition of the weld metal was determined which is characterized by a fine-grained structure with a smallamount of non-metallic impurities of globular shape. Optimal content of the doping micro-additive - molybdenum should beselected, based on both the influence of molybdenum on the size of structural components, but, most importantly, on its effecton the corrosion and mechanical properties of metal joint weld.


Latest trend of miniaturization of thermal systems, calls for the improvement in their efficiency. Nanofluid contains the nanoparticles having large surface area and improves the thermal efficiency. This enhancement is the function of different mechanisms and parameter. This paper explores the heat transfer nature of nanofluids by addressing the experimental studies available in literature and conducting an experimental study using water based Copper oxide nanofluids. Nanoparticles were characterized by X-ray diffraction analysis and Field Emission Scanning Electron Microscopy to confirm the material, size and morphology of the nanoparticles. Thermal conductivity analysis has been performed at 30˚C, 40˚Cand 50˚C with 0.1%,0.5% and 1% concentration by weight. Mechanism of agglomeration, concentration and size of particles are found to be more significant in affecting the heat transfer. The maximum enhancement of 22.9 % in thermal conductivity is found in case of 1% weight concentration nanofluids consisting of small size (20nm) nanoparticles at temperature of 50˚C.


Materials ◽  
2021 ◽  
Vol 14 (22) ◽  
pp. 7059
Author(s):  
Mikhail G. Lavrentev ◽  
Vladimir T. Bublik ◽  
Filipp O. Milovich ◽  
Viktoriya P. Panchenko ◽  
Yuri N. Parkhomenko ◽  
...  

In this study, Ingots of (Bi, Sb)2Te3 thermoelectric material with p-type conductivity have been obtained by hot extrusion. The main regularities of hot extrusion of 30 mm rods have been analyzed with the aid of a mathematical simulation on the basis of the joint use of elastic-plastic body approximations. The phase composition, texture and microstructure of the (Bi, Sb)2Te3 solid solutions have been studied using X-ray diffraction and scanning electron microscopy. The thermoelectric properties have been studied using the Harman method. We show that extrusion through a 30 mm diameter die produces a homogeneous strain. The extruded specimens exhibit a fine-grained structure and a clear axial texture in which the cleavage planes are parallel to the extrusion axis. The quantity of defects in the grains of the (Bi, Sb)2Te3 thermoelectric material decreases with an increase in the extrusion rate. An increase in the extrusion temperature leads to a decrease in the Seebeck coefficient and an increase in the electrical conductivity. The specimens extruded at 450 °C and a 0.5 mm/min extrusion rate have the highest thermoelectric figure of merit (Z = 3.2 × 10−3 K−1).


Author(s):  
Daniel C. Pease

A previous study demonstrated that tissue could be successfully infiltrated with 50% glutaraldehyde, and then subsequently polymerized with urea to create an embedment which retained cytomembrane lipids in sectioned material. As a result, the 180-190 Å periodicity characteristic of fresh, mammalian myelin was preserved in sections, as was a brilliant birefringence, and the capacity to bind OsO4 vapor in the hydrophobic bilayers. An associated (unpublished) study, carried out in co-operation with Drs. C.K. Akers and D.F. Parsons, demonstrated that the high concentration of glutaraldehyde (and urea) did not significantly alter the X-ray diffraction pattern of aldehyde-fixed, myelin. Thus, by itself, 50% glutaraldehyde has little effect upon cytomembrane systems and can be used with confidence for the first stages of dehydration.


Polymers ◽  
2021 ◽  
Vol 13 (10) ◽  
pp. 1563
Author(s):  
Sofia Marquez-Bravo ◽  
Ingo Doench ◽  
Pamela Molina ◽  
Flor Estefany Bentley ◽  
Arnaud Kamdem Tamo ◽  
...  

Extremely high mechanical performance spun bionanocomposite fibers of chitosan (CHI), and cellulose nanofibers (CNFs) were successfully achieved by gel spinning of CHI aqueous viscous formulations filled with CNFs. The microstructural characterization of the fibers by X-ray diffraction revealed the crystallization of the CHI polymer chains into anhydrous chitosan allomorph. The spinning process combining acidic–basic–neutralization–stretching–drying steps allowed obtaining CHI/CNF composite fibers of high crystallinity, with enhanced effect at incorporating the CNFs. Chitosan crystallization seems to be promoted by the presence of cellulose nanofibers, serving as nucleation sites for the growing of CHI crystals. Moreover, the preferential orientation of both CNFs and CHI crystals along the spun fiber direction was revealed in the two-dimensional X-ray diffraction patterns. By increasing the CNF amount up to the optimum concentration of 0.4 wt % in the viscous CHI/CNF collodion, Young’s modulus of the spun fibers significantly increased up to 8 GPa. Similarly, the stress at break and the yield stress drastically increased from 115 to 163 MPa, and from 67 to 119 MPa, respectively, by adding only 0.4 wt % of CNFs into a collodion solution containing 4 wt % of chitosan. The toughness of the CHI-based fibers thereby increased from 5 to 9 MJ.m−3. For higher CNFs contents like 0.5 wt %, the high mechanical performance of the CHI/CNF composite fibers was still observed, but with a slight worsening of the mechanical parameters, which may be related to a minor disruption of the CHI matrix hydrogel network constituting the collodion and gel fiber, as precursor state for the dry fiber formation. Finally, the rheological behavior observed for the different CHI/CNF viscous collodions and the obtained structural, thermal and mechanical properties results revealed an optimum matrix/filler compatibility and interface when adding 0.4 wt % of nanofibrillated cellulose (CNF) into 4 wt % CHI formulations, yielding functional bionanocomposite fibers of outstanding mechanical properties.


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