Thermo- and chemo-electrical behavior of carbon nanotube filled co-continuous conductive polymer nanocomposites (CPC) to develop amperometric sensors

2008 ◽  
Vol 1143 ◽  
Author(s):  
Jianbo Lu ◽  
Mickaël Castro ◽  
Bijandra Kumar ◽  
Jean-François Feller
Keyword(s):  
Temperature Sensor ◽  
Conductive Polymer ◽  
Multiwall Carbon Nanotubes ◽  
Polymer Nanocomposite ◽  
Melt Mixing ◽  
Conductive Phase ◽  
Polyamide 12 ◽  
Barrier Effects ◽  
Vapor Sensing ◽  
Mixing Method

ABSTRACTThe conductive polymer nanocomposite (CPC) of multiwall carbon nanotubes (MWNT) filled Polycaprolactone (PCL) was formulated by melt mixing method. PCL based conductive phase served as disperse phase, blended with polypropylene (PP) and polyamide 12 (PA12) respectively. The thermo- and chemo-electrical properties of mono- and bi-component CPC have been investigated independently. Results show that PP/PCL-CNT CPC is a good temperature sensor whereas no significant response was observed while exposing to toluene vapor. In contrast, PA12/PCL-CNT exhibits good vapor sensing capability instead of temperature sensor. It is assumed that PP phase prevents the diffusion of vapor molecules within PCL conductive phase. The vapor sensing results indicated that PP external matrix provides the CPC with higher barrier effects than PA12.

Rheological and Thermal Behaviour of High Impact Polystyrene Nanocomposite

2011 ◽  
Vol 383-390 ◽  
pp. 3849-3853 ◽  
Author(s):  
Ahmed S. AL-Ghamdi ◽  
Mohammad Yeakub Ali
Keyword(s):  
Thermal Behaviour ◽  
Multiwall Carbon Nanotubes ◽  
High Impact ◽  
Marginal Effect ◽  
Rheological Characteristics ◽  
Melt Mixing ◽  
High Impact Polystyrene ◽  
Differential Scanning Calorimeter Analysis ◽  
Mixing Method ◽  
Multiwall Carbon

This paper presents the study of rheological and thermal behaviour of high impact polystyrene/multiwall carbon nanotubes (HIPS/MWCNTs) nanocomposite. The nanocomposite was prepared via melt mixing method. The influence of different loadings of MWCNTs on the HIPS viscosity and other rheological characteristics were analyzed experimentally. Other rheological characteristics were studied using dynamic analysis of viscosity through rotational rehometer. Glass transition temperature (Tg) were also investigated using non-isothermal differential scanning calorimeter analysis. The viscosity was found to be directly proportional to MWCNTs’ loading, up to five times the value of pure HIPS at loading level of 7.5wt% of MWCNTs. The MWCNTs loading demonstrated a marginal effect (1-2%) on the Tg.

Pressure and microwave sensors/actuators based on smart hydrogel/conductive polymer nanocomposite

2014 ◽  
Vol 190 ◽  
pp. 270-278 ◽  
Author(s):  
Rebeca E. Rivero ◽  
María A. Molina ◽  
Claudia R. Rivarola ◽  
Cesar A. Barbero
Keyword(s):  
Conductive Polymer ◽  
Polymer Nanocomposite ◽  
Smart Hydrogel ◽  
Microwave Sensors

scholarly journals Polyamide 12/Multiwalled Carbon Nanotube and Carbon Black Nanocomposites Manufactured by 3D Printing Fused Filament Fabrication: A Comparison of the Electrical, Thermoelectric, and Mechanical Properties

2021 ◽  
Vol 7 (2) ◽  
pp. 38
Author(s):  
Nectarios Vidakis ◽  
Markos Petousis ◽  
Lazaros Tzounis ◽  
Emmanuel Velidakis ◽  
Nikolaos Mountakis ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
3D Printing ◽  
Carbon Black ◽  
Large Scale ◽  
Fracture Mechanisms ◽  
Fused Filament Fabrication ◽  
Melt Mixing ◽  
Multiwalled Carbon ◽  
Electrically Conductive ◽  
Polyamide 12

In this study, nanocomposites with polyamide 12 (PA12) as the polymer matrix and multiwalled carbon nanotubes (MWCNTs) and carbon black (CB) at different loadings (2.5, 5.0, and 10.0 wt.%) as fillers, were produced in 3D printing filament form by melt mixing extrusion process. The filament was then used to build specimens with the fused filament fabrication (FFF) three-dimensional (3D) printing process. The aim was to produce by FFF 3D printing, electrically conductive and thermoelectric functional specimens with enhanced mechanical properties. All nanocomposites’ samples were electrically conductive at filler loadings above the electrical percolation threshold. The highest thermoelectric performance was obtained for the PA12/CNT nanocomposite at 10.0 wt.%. The static tensile and flexural mechanical properties, as well as the Charpy’s impact and Vickers microhardness, were determined. The highest improvement in mechanical properties was observed for the PA12/CNT nanocomposites at 5.0 wt.% filler loading. The fracture mechanisms were identified by fractographic analyses of scanning electron microscopy (SEM) images acquired from fractured surfaces of tensile tested specimens. The nanocomposites produced could find a variety of applications such as; 3D-printed organic thermoelectric materials for plausible large-scale thermal energy harvesting applications, resistors for flexible circuitry, and piezoresistive sensors for strain sensing.

Microstructure and Mechanical Properties of In Situ TiB2/6061 Composites

2012 ◽  
Vol 535-537 ◽  
pp. 14-17
Author(s):  
Long Hua Zhong ◽  
Yu Tao Zhao ◽  
Song Li Zhang ◽  
Rong Wen
Keyword(s):  
Master Alloy ◽  
Volume Fraction ◽  
X Ray Diffraction ◽  
Melt Mixing ◽  
X Ray ◽  
Mixing Method ◽  
Particulate Volume Fraction ◽  
Ti Powder ◽  
Particulate Volume

In situ TiB2/6061 composites have been successfully synthesized through chemical reaction between 6061 master alloy, Al-3B master alloy and Ti powder. The composites fabricated by direct melt mixing method was investigated by Scanning Electron Microscope (SEM), Energy Dispersive x-ray Spectroscopy (EDS) and X-Ray Diffraction (XRD), The results shown the existence of TiB2particles. The size of most TiB2particles were just in micron level, and even reached to sub-micron level. The increase in microhardness and tensile strength for the as-prepared composites with 5% particulate volume fraction (PVF) are up to 26.8% and 51.2% respectively.

PLA conductive filament for 3D printed smart sensing applications

2018 ◽  
Vol 24 (4) ◽  
pp. 739-743 ◽  
Author(s):  
Simone Luigi Marasso ◽  
Matteo Cocuzza ◽  
Valentina Bertana ◽  
Francesco Perrucci ◽  
Alessio Tommasi ◽  
...  
Keyword(s):  
Temperature Sensor ◽  
Low Cost ◽  
Conductive Polymer ◽  
Temperature Characteristic ◽  
Temperature Sensors ◽  
Electrical Performance ◽  
Content Type ◽  
Sensing Applications ◽  
3D Printed

Purpose This paper aims to present a study on a commercial conductive polylactic acid (PLA) filament and its potential application in a three-dimensional (3D) printed smart cap embedding a resistive temperature sensor made of this material. The final aim of this study is to add a fundamental block to the electrical characterization of printed conductive polymers, which are promising to mimic the electrical performance of metals and semiconductors. The studied PLA filament demonstrates not only to be suitable for a simple 3D printed concept but also to show peculiar characteristics that can be exploited to fabricate freeform low-cost temperature sensors. Design/methodology/approach The first part is focused on the conductive properties of the PLA filament and its temperature dependency. After obtaining a resistance temperature characteristic of this material, the same was used to fabricate a part of a 3D printed smart cap. Findings An approach to the characterization of the 3D printed conductive polymer has been presented. The major results are related to the definition of resistance vs temperature characteristic of the material. This model was then exploited to design a temperature sensor embedded in a 3D printed smart cap. Practical implications This study demonstrates that commercial conductive PLA filaments can be suitable materials for 3D printed low-cost temperature sensors or constitutive parts of a 3D printed smart object. Originality/value The paper clearly demonstrates that a new generation of 3D printed smart objects can already be obtained using low-cost commercial materials.

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