Intercalated Two-Dimensional Ceramic Nanocomposites

1992 ◽  
Vol 267 ◽  
Author(s):  
E.P. Giannelis ◽  
V. Mehrotra ◽  
O. Tse ◽  
R.A. Vaia ◽  
T.-C. Sung

ABSTRACTNew generations of polymer-ceramic nanocomposites are being developed by intercalation of layered solids. Synthetic approaches include intercalative polymerization, direct polymer intercalation and molecular dispersion of the host layers in the polymer matrix. The unique physical and mechanical properties of the hybrids are attributed to the molecular dispersion and the synergism between the individual components.

1991 ◽  
Vol 249 ◽  
Author(s):  
E.P. Giannelis ◽  
V. Mehrotra ◽  
O. Tse ◽  
R.A. Vaia ◽  
T.-C. Sung

ABSTRACTNew generations of polymer-ceramic nanocomposites are being developed by intercalation of layered solids. Synthetic approaches include intercalative polymerization, direct polymer intercalation and molecular dispersion of the host layers in the polymer matrix. The unique physical and mechanical properties of the hybrids are attributed to the molecular dispersion and the synergism between the individual components.


2020 ◽  
Vol 869 ◽  
pp. 488-493
Author(s):  
Aues A. Beev ◽  
Svetlana Yu. Khashirova ◽  
Azamat L. Slonov ◽  
Ismel V. Musov ◽  
Azamat Zhansitov ◽  
...  

The article presents the results of sizing of discrete carbon fibers with various substances and their effect on the properties of polyetherimide composites. As sizing agents, 1,3-diaminobenzene, 4,4'-dihydroxy-2,2-diphenylpropane, polyetherimide and oligoetherether sulfone were used. The study of physical and mechanical properties showed that all the substances used increase the properties of the carbon-filled composite based on polyetherimide. The highest mechanical properties are demonstrated by a composite containing carbon fibers treated with 1,3-diaminobenzene, which indicates improved compatibility of the filler and the polymer matrix and enhanced intermolecular interactions.


2020 ◽  
Author(s):  
Maryna Leshchyshyn Mykolaivna ◽  
Svitlana Stepanivna Garkavenko ◽  
Antonina Ivanivna Babich

Determination of values and dependencies of deformation and physical and mechanical properties of materials of shoe models and finished products. According to the results of theoretical, analytical and marketing research, a number of experimental tests of materials have been carried out to prove the practical significance of the work, namely tests for: deformation of the vamp part of the product, uniaxial and biaxial stretching, bending, dry and wet friction, adhesion, elongation and tearing. There has been established the nature of the distribution of the total elongations of the samples of the vamps cut from different areas of the leather, as well as the ability of the leather material to be formed when improving the shape of the product or changing the shape of the shoetree. The processes of deformation of the vamp part of shoe blanks, physical and mechanical properties of different groups of modern materials and values analysis of similarity of their deformation properties have been studied. There has been created a working model-transformer for carrying out preliminary measurement of clients’ feet at the individual order. The expediency of these works has been proved experimentally. A working version of a model-transformer for foot measurements has been made and as a result of the works approbation, a sample of shoes has been made. The ergonomic properties of the manufactured footwear have been improved due to the use of materials with enhanced physical and mechanical properties. The article investigates the deformation of the most vulnerable vamp part of the men's model of a typical model, as well as the physical and mechanical characteristics of leather materials for manufacturing models and shoes of this type. Providing high quality and comfort of footwear, accuracy of parameters selection of foot measurement, zones of beams and achievement of form stability of footwear with a top from genuine leathers has been predicted.


2019 ◽  
Vol 184 ◽  
pp. 107836 ◽  
Author(s):  
O. Velazquez-Meraz ◽  
J.E. Ledezma-Sillas ◽  
C. Carreño-Gallardo ◽  
W. Yang ◽  
N.M. Chaudhari ◽  
...  

Author(s):  
Sujan Kanti Das ◽  
Mithun Rani Nath ◽  
Rajib Chandra Das ◽  
Manas Mondal ◽  
Snahasis Bhowmik

Compression molding has produced quartz-reinforced polyester composites (QPCs) weighing 10 to 40 per cent quartz relative to the weight of unsaturated polyester resin. Synergistic changes were made in the composite properties and were superior to those of the individual components. The composite's physical and  mechanical properties such as bulk density, water absorption , tensile strength, flexural strength, hardness have illustrated the competency of the composite being developed. It was found that for the resultant composite examined, the percentage of water absorption is very small. However, when quartz content were increased, water absorption grew very slowly. Enhancement of mechanical properties strongly corresponds to strong adhesion force of quartz with the matrix and it influenced by well-disperse quartz particles on the whole surface of composite. This paper also performed thermal characterization of the composites. Because of these remarkable properties, as prepared composite can find applications in packaging, fuel cell, solar cell, structural materials and households purposes.


Author(s):  
Himanshu Gupta ◽  
Kamal Kanaujiya ◽  
Syed Mazher Abbas Rizvi

To determine the possibility of using sugar- cane bagasse (SCB)and ground nut shell particulate(GNSP) waste as reinforcing ?ller in the thermo plastic polymer matrix, SCB&GNSP-reinforced polypropylene (PP) composites were prepared. The PP and SCB and GNSP composites were prepared by the extrusion of PP and GNSP with 5, 10, 15, and 20 wt % of SCB and GNSP with 3,6,9 and 12% filler in a co rotating twin screw extruder.. The extruded strands were cut into pellets and injection molded to make test specimens. These specimens were tested for physical and mechanical properties such as tensile, flexural, Izod impact strength shore D hardness and water absorption. It was found that the Tensile strength increased from 29.06 to 31.38 MPa, Flexural strength increased from 28.62 to 43.56 MPa, Izod impact strength decreased from 35.11 to 30.93 J/m, and Shore D Hardness increased from 64.88 to 77.89, with increase in filler loading from 5 to 20% in the PP matrix. The decrease in Izod Impact strength and elongation with addition of SCB & GNSP filler to PP matrix follows the general trend of filler effects on polymer matrix. However, the main purpose of this work was to study the effect of SCB & GNSP waste on the mechanical properties of the PP Composites. The SCB and GNSP waste can be used as filler in the PP composites, which will reduce cost and give environmental benefits.


Author(s):  
Inna Slepchuk ◽  
Olga Ya. Semeshko ◽  
Tatiana S. Asaulyuk ◽  
Yuliya G. Saribekova

The influence of crosslinking agents on the characteristics and properties of films from aqueous dispersions of styrene-acrylic polymers Lacritex 309, 430 and 640 was studied in order to obtain coatings on textile materials. Mono-, di- and triglycidyl esters are chosen as crosslinking agents. The choice of aqueous dispersions of polymers and crosslinkers is due to strict environmental requirements for textile products. By determining the amount of aceton-insoluble fractions of the formed polymer films, it was determined that the incorporation of crosslinkers is required in the Lacritex dispersion 640, and the films based on Lacritex 430 and 309 are distinguished by a high degree of intermolecular crosslinking. Optimum concentrations of crosslinkers have been established, which provide a high degree of curing of Lacritex 640. Using the sol-gel method, the structural parameters of the spatial nets of styrene-acrylic polymers (the part of sol fraction, the degree of crosslinking, the part of active chains, the average molecular weight of the chain segment, the crosslink density) were calculated. The polymer films from the individual polymer Lacritex 430 have the highest indexes of physic mechanical characteristics. Lacritex 640/Laproxide 703 compositions can be used as polymer matrixes for textile materials. The formation of crosslinks of hydroxyl and carboxyl groups of the styrene-acrylic polymer with epoxy groups of the crosslinking agent was confirmed by IR spectroscopy. The investigation of the effect of water and soap-soda treatments at various temperatures shows that the films under study have high resistance to water and soap-soda solution. The results of investigation of the tensile strength, the elongation at break, the hardness of the coating surface by the Koenig method and the stickiness according to the FINAT method (Test Method Number 9) of the formed polymer films indicate high physical and mechanical properties such as increased mechanical strength and elasticity, reduced hardness and tackiness. Thus, based on the studies carried out, it can be concluded that the individual styrene-acrylic Lacritex polymers 309 and 430 provide the formation of a strong three-dimensional spatial structure of the polymer film and can be used without crosslinking agents. The use of Lacritex 640 is possible in the composition together with the Laproxide 703 crosslinking agent at an optimum concentration of 4%. A polymer film based on this composition has a high degree of crosslinking, and as a result, increased resistance to organic solvents, reduced hydrolytic degradation at high temperatures, and increased physico-mechanical properties. A polymer film based on this composition has a high degree of crosslinking, hence, has increased resistance to organic solvents, reduced hydrolytic degradation at high temperatures, and increased physical and mechanical properties. Forcitation:Slepchuk I., Semeshko O.Ya., Asaulyuk T.S., Saribekova Yu.G. Investigation of impact of rosslinking agents on characteristics of spatial net and properties of styrene-acrylic polymer films. Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol. 2018. V. 61. N 7. P. 67-75


2018 ◽  
Vol 196 ◽  
pp. 04044
Author(s):  
Wioletta Godlewska ◽  
Artur Koper

Nowadays, one of the most important challenge in civil construction is design, build and use buildings in sustainable development way. This article describes one of the most important thermo-modernization undertaking, which is increase of insulation of external walls. The research was prepared in special technology on samples with silicon, mineral, acrylic thin-layer plasters and with adhesive mass only. Purpose of the research was to analyze the physical and mechanical properties of the additional layer with this four variants of plastering mortar. The research, which was made by authors showed that the thin – layer plasters are characterized by resistance to environmental factors, which they are directly exposed. The connection between the individual layers of the thermal insulation system secures durability of the plasters. The samples with mineral plastering mortar were characterized by the highest interlayer adhesion


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