Misfit Strain Relief Beyond the Critical Thickness Using Curvature Measurements and in Situ Characterization of the Magneto-Optic Kerr Effect

1994 ◽  
Vol 356 ◽  
Author(s):  
H. E. Inglefield ◽  
G. Bochi ◽  
C. A. Ballentine ◽  
R. C. O’Handley ◽  
C. V. Thompson

AbstractEpitaxial misfit has been characterized in Ni/Cu/Si (100) as a function of Ni film thickness using wafer curvature measurements. This strain can be related to measurements of magnetic anisotropy made in the deposition system using the magneto-optic Kerr effect. Films were deposited using molecular beam epitaxy (MBE) with varying Ni epilayer thickness between 10 and 1000Å. The change in wafer curvature due to misfit strain was measured using optical interferometry and the strain was calculated using Stoney’s equation. Transmission electron microscopy was used to characterize misfit dislocations at the Ni/Cu interface. It has been determined that misfit strain can have a very strong effect on magnetic anisotropy, particularly in the regime between the critical thickness and complete misfit accommodation, where strain has been found to decrease significantly as a function of film thickness. A critical strain has been determined at which a transition in the direction of magnetization easy axis from perpendicular to the film to in the film plane occurs. This discovery allows the use of Kerr effect measurements to characterize misfit strain in situ.

1993 ◽  
Vol 313 ◽  
Author(s):  
Ould-Mahfoud S ◽  
Megy R. ◽  
Bardou N. ◽  
Bartenlian B. ◽  
Beauvillain P. ◽  
...  

ABSTRACTWe present a comparative in situ RHEED and Polar Magneto-optic Kerr Effect study of the first stages of the growth of a Au overlayer on top of a (111) Co ultrathin film. Drastic behaviours are evidenced on the RHEED diagram, Magnetic anisotropy and coercive force, around 1,5 ML of Au coverage.


1993 ◽  
Vol 313 ◽  
Author(s):  
G. Bochi ◽  
C. A. Ballentine ◽  
H. E. Inglefield ◽  
S. S. Bogomolov ◽  
C. V. Thompson ◽  
...  

ABSTRACTEpitaxial Ni/Cu (001) films grown on Si (001) by Molecular Beam Epitaxy were studied in-situ using the Surface Magneto-optic Kerr Effect (SMOKE) and ex-situ with a Vibrating Sample Magnetometer (VSM). Perpendicular Magnetization is observed for Ni thicknesses 15 Å ≤ h ≤ 60 Å and fully in-plane magnetization for h ≥ 70 Å when the films are characterized in-situ. The reversal in magnetic anisotropy observed in-situ at 60 Å shifts to 125 Å when the films are exposed to air. 100 Å Ni films deposited on Cu1−x-Nix alloy substrates also show a reversal in magnetic anisotropy as x is changed. These results suggest that changes in magnetic anisotropy correlate with misfit strain accommodation.


1991 ◽  
Vol 231 ◽  
Author(s):  
B.M. Clemens ◽  
R.L. White ◽  
W.D. Nix ◽  
J.A. Bain

AbstractWe consider the anisotropies due to coherency strains and the inilioliogcliotis stratlus associated with misfit dislocations, both of which give rise to anisotropy through maguctostrictive coupling. Coherency strains can give rise to anl apparent surface anisotrnpy due to the decrease in coherency strain with the film thickness. This anisotropy is comparable in magnitude to that observed experimentally for Fe [110] epitaxial thiut films on W [110]. The strain field associated with misfit dislocations produces a. surface anisotropy which is also comparable in magnitude to experimentally observed anisotropies. Dislocatioms along the inplane [001] and [110] directions both produce the same preferred direction of maguctization orientation.


2018 ◽  
Vol 20 (43) ◽  
pp. 27350-27360 ◽  
Author(s):  
Yuxi Ma ◽  
Jason D. Nicholas

This work demonstrates, for the first time, that a variety of disparate and technologically-relevent thermal, mechanical, and electrochemical oxygen-exchange material properties can all be obtained from in situ, current-collector-free wafer curvature measurements.


1989 ◽  
Vol 160 ◽  
Author(s):  
Eric P. Kvam ◽  
D.M. Maher ◽  
C.J. Humphreys

AbstractWe have observed that the nature of misfit dislocations introduced near the critical thickness in GexSi1-x alloys on (001)Si changes markedly in the region 0.4 ≤ x ≤ 0.5. At or below the lower end of this compositional range, the observed microstructure is comprised almost entirely of 60° type dislocations, while at the high end, the dislocation structure is almost entirely Lomer edge type. Concurrent with this change, the dislocation density at the top of the epilayer varies by a factor of about 60X. Similarly, several other observables (e.g. dislocation length and spacing) also change appreciably.Part of the reason for the morphological variation seems to be a change in the source for dislocation introduction, in conjunction with a change in glide behaviour of dislocations as a function of film thickness. Evidence will be presented that indicates strain, as well as thickness, has a critical value for some dislocation introduction mechanisms, and that these together determine the resulting microstructure.Furthermore, it appears unlikely that the edge-type Lomer dislocations which appear at about x = 0.5 are either introduced directly, by climb, or grown in, as in the three-dimensional island growth and coalescence which occurs when x approaches unity. Instead, a two-step mechanism involving glissile dislocations is proposed and discussed.


1993 ◽  
Vol 308 ◽  
Author(s):  
H.E. Inglefield ◽  
C.A. Ballentine ◽  
G. Bochi ◽  
S.S. Bogomolov ◽  
R.C. O'Handley ◽  
...  

ABSTRACTWe have detected magnetic transitions in Ni/Cu (100) films as a function of Ni thickness through in situ measurements of the magneto-optic Kerr effect (MOKE). Crystalline quality was monitored using in situ RHEED and Auger electron spectroscopy. Films were deposited by molecular beam epitaxy on silicon wafers and cleaved sodium chloride with varying epitaxial Ni layer thicknesses between 10 and 200 A. High-resolution TEM images of these films indicate decreasing misfit dislocation spacing and decreasing strain as measured by moiré fringe analysis with increasing Ni thickness. These observations have been correlated with changes in magnetic anisotropy as measured by MOKE. MOKE, therefore, may provide a tool for in situ monitoring of the kinetics of misfit accommodation in magnetic thin films.


2021 ◽  
Vol 92 (2) ◽  
pp. 025105
Author(s):  
A. Brozyniak ◽  
G. Mendirek ◽  
M. Hohage ◽  
A. Navarro-Quezada ◽  
P. Zeppenfeld

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