Two Species/Nonideal Solution Model for Amorphous/Amorphous Phase Transitions

1996 ◽  
Vol 455 ◽  
Author(s):  
Cornelius T. Moynihan
Keyword(s):  
Phase Transition ◽  
Phase Transitions ◽  
Critical Temperature ◽  
Amorphous Phase ◽  
Thermodynamic Model ◽  
Critical Pressure ◽  
Solution Model ◽  
Amorphous Phases ◽  
First Order ◽  
Temperature And Pressure

ABSTRACTA simple macroscopic thermodynamic model for first order transitions between two amorphous phases in a one component liquid is reviewed, augmented and evaluated. The model presumes the existence in the liquid of two species, whose concentrations are temperature and pressure dependent and which form a solution with large, positive deviations from ideality. Application of the model to recent data indicates that water can undergo an amorphous/amorphous phase transition below a critical temperature Tc of 217K and above a critical pressure Pc of 380 atm.

scholarly journals Electric properties of olive oil under pressure

2021 ◽  
Author(s):  
L. T. Pawlicki ◽  
R. M. Siegoczyński ◽  
S. Ptasznik ◽  
K. Marszałek
Keyword(s):  
Molecular Structure ◽  
Phase Transition ◽  
Phase Diagram ◽  
Phase Transitions ◽  
Olive Oil ◽  
Material Parameters ◽  
First Order ◽  
Long Time ◽  
Capacitive Reactance ◽  
First Order Phase

AbstractThe main purpose of the experiment was a thermodynamic research with use of the electric methods chosen. The substance examined was olive oil. The paper presents the resistance, capacitive reactance, relative permittivity and resistivity of olive. Compression was applied with two mean velocities up to 450 MPa. The results were shown as functions of pressure and time and depicted on the impedance phase diagram. The three first order phase transitions have been detected. All the changes in material parameters were observed during phase transitions. The material parameters measured turned out to be the much more sensitive long-time phase transition factors than temperature. The values of material parameters and their dependence on pressure and time were compared with the molecular structure, arrangement of molecules and interactions between them. Knowledge about olive oil parameters change with pressure and its phase transitions is very important for olive oil production and conservation.

scholarly journals Cosmological phase transitions: is effective field theory just a toy?

2021 ◽  
Vol 2021 (3) ◽  
Author(s):  
Marieke Postma ◽  
Graham White
Keyword(s):  
Field Theory ◽  
Phase Transition ◽  
Phase Transitions ◽  
Effective Field Theory ◽  
New Physics ◽  
Effective Field ◽  
Tree Level ◽  
Dark Sector ◽  
First Order ◽  
First Order Phase

Abstract To obtain a first order phase transition requires large new physics corrections to the Standard Model (SM) Higgs potential. This implies that the scale of new physics is relatively low, raising the question whether an effective field theory (EFT) description can be used to analyse the phase transition in a (nearly) model-independent way. We show analytically and numerically that first order phase transitions in perturbative extensions of the SM cannot be described by the SM-EFT. The exception are Higgs-singlet extension with tree-level matching; but even in this case the SM-EFT can only capture part of the full parameter space, and if truncated at dim-6 operators, the description is at most qualitative. We also comment on the applicability of EFT techniques to dark sector phase transitions.

scholarly journals Limiting first-order phase transitions in dark gauge sectors from gravitational waves experiments

2017 ◽  
Vol 32 (08) ◽  
pp. 1750049 ◽  
Author(s):  
Andrea Addazi
Keyword(s):  
Phase Transition ◽  
Phase Transitions ◽  
Standard Model ◽  
Gravitational Waves ◽  
Parameter Space ◽  
Higgs Potential ◽  
Electroweak Phase Transition ◽  
First Order ◽  
First Order Phase

We discuss the possibility to indirectly test first-order phase transitions of hidden sectors. We study the interesting example of a Dark Standard Model (D-SM) with a deformed parameter space in the Higgs potential. A dark electroweak phase transition can be limited from next future experiments like eLISA and DECIGO.

Two-Dimensional Phase Transitions Associated with a Surface Miscibility Gap in Cu-Ag Alloys

1990 ◽  
Vol 202 ◽  
Author(s):  
Y. Liu ◽  
P. Wynblatt
Keyword(s):  
Phase Transition ◽  
Phase Transitions ◽  
Critical Temperature ◽  
Abrupt Change ◽  
Surface Composition ◽  
Bulk Composition ◽  
Miscibility Gap ◽  
Experimental Measurements ◽  
Two Dimensional ◽  
Surface Phase

ABSTRACTA surface phase transition associated with a surface miscibility gap has been observed on the (111) surface of Cu-Ag alloys both in computer simulations and in experimental measurements of surface composition. This transition is characterized by an abrupt change in surface composition associated with changes in either bulk composition or temperature.The simulations have revealed that the transition from a Cu-rich to a Ag-rich surface phase is accompanied by interesting changes in surface structure. The experiments show that the surface critical temperature lies somewhere between 505 and 560°C.

OBSERVATION OF PHASE TRANSITIONS AT THE (100) SURFACE OF Al-3 at.% Ag

1995 ◽  
Vol 02 (02) ◽  
pp. 141-145 ◽  
Author(s):  
E. WETLI ◽  
M. HOCHSTRASSER ◽  
D. PESCIA ◽  
M. ERBUDAK
Keyword(s):  
Phase Transition ◽  
Phase Transitions ◽  
Photoelectron Spectroscopy ◽  
Short Range ◽  
Short Range Order ◽  
Elevated Temperatures ◽  
X Ray ◽  
First Order ◽  
First Order Phase Transition ◽  
First Order Phase

In the bulk binary alloy Al-3 at.% Ag , Ag 2 Al precipitates are formed below 410°C which are reversibly dissolved at elevated temperatures. We have followed this phase transition at a (100) surface as a function of temperature by monitoring the bandwidth of the Ag 4d states in X-ray photoelectron spectroscopy. Since the bandwidth measures the coordination number of the emitting atoms, it directly reveals the short-range order of the Ag atoms at the surface. The measurements show that the dissolution of the Ag -rich clusters starts at temperatures at least 100 K below the bulk transition, and the observed hysteresis behavior is indicative of a first-order phase transition at the surface.

GRAVITATIONAL WAVES FROM COSMOLOGICAL PHASE TRANSITIONS

2009 ◽  
Vol 24 (08n09) ◽  
pp. 1541-1544
Author(s):  
ARIEL MÉGEVAND
Keyword(s):  
Phase Transition ◽  
Phase Transitions ◽  
Gravitational Waves ◽  
Order Phase Transition ◽  
Gravitational Radiation ◽  
First Order ◽  
First Order Phase Transition ◽  
First Order Phase

I discuss the gravitational radiation produced in a first-order phase transition due to the turbulence that is caused by bubble expansion. I compare the cases of deflagration and detonation bubbles.

Subcritical and Supercritical Nanodroplet Evaporation: A Molecular Dynamics Investigation

2007 ◽  
Author(s):  
S. Mikkilineni ◽  
E. S. Landry ◽  
A. J. H. McGaughey
Keyword(s):  
Molecular Dynamics ◽  
Critical Temperature ◽  
Critical Pressure ◽  
Ambient Pressure ◽  
Transition Line ◽  
Ambient Temperatures ◽  
Lennard Jones ◽  
Temperature And Pressure ◽  
A New Technique ◽  
Dynamics Simulations

Molecular dynamics simulations are used to investigate the subcritical and supercritical evaporation of a Lennard-Jones (LJ) argon nanodroplet in its own vapor. Using a new technique to control both the ambient temperature and pressure, a range of conditions are considered to define a transition line between subcritical and supercritical evaporation. The evaporation is considered to be supercritical if the surface temperature of the droplet reaches the LJ argon critical temperature during its lifetime. Between ambient temperatures of 300 K and 800 K, the transition from subcritical to supercritical evaporation is observed to occur at an ambient pressure 1.4 times greater than the LJ argon critical pressure. For subcritical conditions, the droplet lifetimes obtained from the simulations are compared to independently predicted lifetimes from the D2 law.

Phase transitions and topological defects

2018 ◽  
Author(s):  
Michael Kachelriess
Keyword(s):  
Phase Transition ◽  
Phase Transitions ◽  
Early Universe ◽  
Topological Defects ◽  
False Vacuum ◽  
First Order ◽  
Broken Symmetries ◽  
First Order Phase Transition ◽  
True Vacuum ◽  
First Order Phase

As the early universe cools down, it may perform transitions to phases with more and more broken symmetries. In a first-order phase transition, fields may be trapped in the false vacuum; the rate of the resulting tunneling process to the true vacuum is derived. Phase transitions can lead also to the formation of topological defects. Their structure and the reason for their stability are discussed.

Sign in / Sign up

Export Citation Format

Share Document