More Insights into Band Gap Graded a-SiGe:H Solar Cells by Experimental and Simulated Data

1997 ◽  
Vol 467 ◽  
Author(s):  
J. Zimmer ◽  
H. Stiebig ◽  
J. Fölsch ◽  
F. Finger ◽  
Th. Eickhoff ◽  
...  

ABSTRACTAn experimental and numerical study of a-SiGe:H based solar cells with band gap graded i-layer in the shape of a ‘V’ is presented. The variation of the location of the band gap minimum has strong influence on the solar cell performance. Comparisons of experimental and simulated data of the dark IV-behavior, IV-curves under illumination and the quantum efficiency allow insights into the transport and recombination behavior within the solar cell. The simulations reveal that the position as well as the charge state of the defects determine the device characteristics.

1991 ◽  
Vol 219 ◽  
Author(s):  
Bolko Von Roedern

ABSTRACTThe fast changes observed in the stabilized state of a-Si:H solar cells and modules at temperatures below 70°C are inconsistent with the commonly accepted picture of “defect annealing.” The fast changes observed in the stabilized state, for example when the temperature is altered, are explained in terms of converting the charge state of the dangling bond defects that are already present in the material. It is suggested that the slow degradation of solar cells arises from the creation of new defects and can be described by fitting stretched exponential curves to the solar cell performance data.


2018 ◽  
Vol 32 (23) ◽  
pp. 1850269 ◽  
Author(s):  
Mohamed Moustafa ◽  
Tariq Alzoubi

The impact of molybdenum ditelluride (p-type MoTe2) transition metal dichalcogenide (TMDC) material formation as an interfacial layer between CdTe absorber layer and Mo back contact is investigated. The simulation is conducted using the solar cell capacitance simulator (SCAPS) software. Band gap energy, carrier concentration, and layer thickness of the p-MoTe2 have been varied in this study to investigate the possible influences of p-MoTe2 on the electrical properties and the photovoltaic parameters of CdTe thin film solar cells. It has been observed that a thickness of the p-MoTe2 interfacial layer less than 60 nm leads to a decrease in the cell performance. In regard to the effect of the band gap, a maximum efficiency of 16.4% at the optimum energy gap value of 0.95 eV has been obtained at a doping of [Formula: see text]. Additionally, increasing the acceptor carrier concentration [Formula: see text] of MoTe2 enhances the solar cell performance. The solar cell efficiency reaches 15.5% with [Formula: see text] of [Formula: see text] with layer thicknesses above 80 nm. This might be attributed to the possibility of forming a back surface field for the photogenerated electrons, which reduces recombination at the back contact and hence provides a low resistivity contact for holes. The results justify that the MoTe2 interfacial layer mediates an ohmic contact to CdTe films.


2020 ◽  
Vol 12 ◽  
Author(s):  
Shingmila Hungyo ◽  
Khomdram Jolson Singh ◽  
Dickson Warepam ◽  
Rudra Sankar Dhar

Background: Energy is a major concern in every aspect of our life. Solar energy is a renewable environment friendly source of energy. Therefore, solar cells are vastly studied with different technology and with different material. Objective: The main objective here is to analyze InGaN material for solar cell applications with less complicated structures of MQW solar cells on revising solar cell with the recombination structure, I-V characteristics and its efficiency. Methods: The device is simulated using SILVACO ATLAS where the well and the barrier layers are inserted in the depletion region employing material combination of InGaN / GaN which increases the solar cell performance parameter. This work focuses on the photogeneration rate, recombination in the active region as well as its current voltage relation from the simulation. Results: With the increase in the number of QW periods in the active region of the device, the photovoltaic parameters especially conversion efficiency increases significantly. Under space AM0 solar illumination, the cell efficiency increases up to 8.2 % for 20 MQWs with 20% Indium content for the InGaN/GaN structure. It enhances the external quantum efficiency (EQE) upto 36% at nearly 380nm wavelength range near the UV region. Conclusion: The modelled structure is efficiently simulated using TCAD SILVACO ATLAS, and the material Indium Gallium Nitride semiconductor shows an excellent solar cell performance with high solar radiation. It is also observed that with increase in the number of well periods the solar cell performance increases which demonstrates the feasibility of Indium Gallium Nitride solar cell with additional MQW period as power source.


2015 ◽  
Vol 1741 ◽  
Author(s):  
Koichi Matsushima ◽  
Ryota Shimizu ◽  
Tomoaki Ide ◽  
Daisuke Yamashita ◽  
Hyunwoong Seo ◽  
...  

ABSTRACTWe succeeded in photovoltaic power generation of p-i-n solar cells utilizing epitaxial ZnInON film with a wide band gap of 3.1 eV as the intrinsic layer, suitable for a top cell of tandem solar cells. The solar cell shows a high open circuit voltage (Voc) of 1.68 V under solar simulator light irradiation of 3.2 mW/cm2. The solar cell performance becomes worse under 100 mW/cm2, which is mainly attributed to the leakage current caused by crystal defects and grain boundaries. X-ray diffraction analysis reveals that the ZnInON film has rather large tilt and twist angles and a high dislocation density of 7.62×1010 cm-2. Such low crystallinity is a bottleneck for high performance of the solar cells. Our results demonstrate a potential of epitaxial ZnInON films as an intrinsic layer of wide band gap p-i-n solar cells with a high Voc.


2014 ◽  
Vol 2 (45) ◽  
pp. 19282-19289 ◽  
Author(s):  
Zhenggang Huang ◽  
Elisa Collado Fregoso ◽  
Stoichko Dimitrov ◽  
Pabitra Shakya Tuladhar ◽  
Ying Woan Soon ◽  
...  

The performance of bulk heterojunction solar cells based on a novel donor polymer DPP-TT-T was optimised by tuning molecular weight and thermal annealing.


Author(s):  
Hung-Cheng Chen ◽  
Jie-Min Lan ◽  
Hsiang-Lin Hsu ◽  
Chia-Wei Li ◽  
Tien-Shou Shieh ◽  
...  

Three different benzylammonium halide (Cl, Br, and I) salts were investigated to elucidate their effects as additives on MAPbI3 perovskite surface morphology, crystal structure, optical properties, and solar cell performance and stability.


2001 ◽  
Vol 664 ◽  
Author(s):  
Baojie Yana ◽  
Jeffrey Yanga ◽  
Kenneth Lord ◽  
Subhendu Guha

ABSTRACTA systematic study has been made of the annealing kinetics of amorphous silicon (a-Si) alloy solar cells. The cells were deposited at various rates using H2 dilution with radio frequency (RF) and modified very high frequency (MVHF) glow discharge. In order to minimize the effect of annealing during light soaking, the solar cells were degraded under 30 suns at room temperature to quickly reach their saturated states. The samples were then annealed at an elevated temperature. The J-V characteristics were recorded as a function of annealing time. The correlation of solar cell performance and defect density in the intrinsic layer was obtained by computer simulation. Finally, the annealing activation energy distribution (Ea) was deduced by fitting the experimental data to a theoretical model. The results show that the RF low rate solar cell with high H2 dilution has the lowest Ea and the narrowest distribution, while the RF cell with no H2 dilution has the highest Ea and the broadest distribution. The MVHF cell made at 8Å/s withhigh H2 dilution shows a lower Ea and a narrower distribution than the RF cell made at 3 Å/s, despite the higher rate. We conclude that different annealing kinetics plays an important role in determining the stabilized performance of a-Si alloy solar cells.


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