Thermal Stability of Rapidly Quenched TI-NI-AL Amorphous Alloys

1985 ◽  
Vol 58 ◽  
Author(s):  
K. Aoki ◽  
K. Hiraga ◽  
T. Masumoto
Keyword(s):  
Thermal Stability ◽  
Amorphous Phase ◽  
Amorphous Alloys ◽  
Melt Spinning ◽  
Composition Range ◽  
Amorphous Matrix ◽  
Al Alloys ◽  
The Other ◽  
Molten State ◽  
Thermal Stability Of

ABSTRACTTi-Ni-Al alloys were rapidly quenched from a molten state by the melt spinning method. Three kinds of metastable phases, namely, amorphous,nonequilibrium and quasicrystalline phases are formed in these alloys. The amorphous phase is formed in the range of 35 to 70 at% Ti and 0 to 25 at% Al. The nonequilibrium phases are formed in the composition range of 25 to 33 at% Ti. On the other hand, fine quasicrystalline phases are distributed in the amorphous matrix of the Ti-rich alloys. Crystallization temperatures and the hardness of the amorphous alloys were also examined.

scholarly journals Synthesis and Properties of Bulk Metallic Glasses in Pd-Ni-P and Pd-Cu-P Alloys

1996 ◽  
Vol 455 ◽  
Author(s):  
Y. He ◽  
R. B. Schwarz
Keyword(s):  
Thermal Stability ◽  
Glass Transition ◽  
Metallic Glasses ◽  
Amorphous Alloys ◽  
Composition Range ◽  
Wide Composition Range ◽  
Upper Limit ◽  
Ternary Alloy Systems ◽  
The Difference ◽  
Thermal Stability Of

ABSTRACTBulk amorphous Pd-Ni-P and Pd-Cu-P alloy rods with diameters ranging from 7 to 25 mm have been synthesized over a wide composition range using a fluxing technique. For most bulk amorphous Pd-Ni-P alloys, the difference ΔT = Tx - Tg between the crystallization temperature Tx and the glass transition temperature Tg is larger than 90 K, while for bulk amorphous Pd-Cu-P alloys, ΔT varies from 27 to 73 K. Pd40Ni40P20 has the highest glass formability, and 300-gram bulk amorphous cylinders, 25 mm in diameter and 50 mm in length, can be easily produced. This size, however, is not an upper limit. The paper presents the glass formation ranges for both ternary alloy systems and data on the thermal stability of the amorphous alloys, as well as their specific heat, density, and elastic properties.

Thermal Stability of Amorphous Al-Fe-Y Prepared by Mechanical Alloying

2014 ◽  
Vol 804 ◽  
pp. 271-274 ◽  
Author(s):  
Nguyen Hoang Viet ◽  
Nguyen Thi Hoang Oanh ◽  
Pham Ngoc Dieu Quynh ◽  
Tran Quoc Lap ◽  
Ji Soon Kim
Keyword(s):  
Thermal Stability ◽  
Mechanical Alloying ◽  
Amorphous Alloys ◽  
Ball Mill ◽  
The Other ◽  
Scanning Calorimetry ◽  
Powder Alloys ◽  
Stage Crystallization ◽  
Dsc Analyses ◽  
Thermal Stability Of

Al-Fe-Y amorphous alloys of Al84Fe16, Al82Fe18 and Al82Fe16Y2 composition were prepared by mechanical alloying in a planetary ball mill P100. A nearly complete amorphization could be achieved for the Al84Fe16, Al82Fe18 and Al82Fe16Y2 powder alloys after 100h of milling at a rotational speed of 350 rpm in hexane medium. Differential scanning calorimetry (DSC) analyses revealed three-stage crystallization processes for Al82Fe18 and Al82Fe16Y2 alloys and four-stage crystallization processes for Al84Fe16 alloy, respectively. Taking into account the DSC data, the thermal stability increased in the order of Al84Fe16, Al82Fe18, and Al82Fe16Y2 composition. The Al82Fe16Y2 alloy exhibited a relatively better thermal stability than the other two alloys.

scholarly journals Influence of Al addition on the thermal stability and mechanical properties of Fe76.5-xCu1Si13.5b9Alx amorphous alloys

2012 ◽  
Vol 48 (1) ◽  
pp. 45-51 ◽  
Author(s):  
Y.Y. Sun ◽  
M. Song
Keyword(s):  
Mechanical Properties ◽  
Thermal Stability ◽  
Amorphous Alloys ◽  
Melt Spinning ◽  
The Other ◽  
Al Content ◽  
Amorphous Ribbons ◽  
Other Hand ◽  
Al Addition

This paper fabricated Fe76.5-xCu1Si13.5B9Alx (x=0,1,2,3,5,7 at.%) amorphous ribbons using singleroller melt-spinning method. The effect of Al content on the thermal stability and mechanical properties was investigated. The results indicated that Al addition have little effect on the amorphous formation ability of the alloys. On the other hand, increasing the Al content can substantially increase Tx2, which corresponds to the crystallization of Fe borides. Nanoindentation tests indicated that hardness of the alloys increase slightly with increasing the Al content, and Young?s modulus has a complicated relationship with the Al content.

Effects of Cu and Zr on the Formation and Thermal Stability of Al–Ni–Zr–Cu–Y Amorphous Alloy

2012 ◽  
Vol 271-272 ◽  
pp. 36-41
Author(s):  
Wei Yuan Yu ◽  
Wen Jiang Lu ◽  
Nai Rui Li
Keyword(s):  
Thermal Stability ◽  
Amorphous Alloy ◽  
Amorphous Alloys ◽  
Melt Spinning ◽  
Glass Forming Ability ◽  
X Ray Diffraction ◽  
Scanning Calorimetry ◽  
Glass Forming ◽  
Spinning Process ◽  
Thermal Stability Of

Al85Ni10Zr3Y2 and Al80Ni10Zr8-xCuxY2（x=1,2,3,5） alloy ribbons had been prepared by single roller melt-spinning process under vacuum conditions. The ribbons were investigated by X–ray diffraction and differential scanning calorimetry (DSC). The results revealed the strong effect of content of Cu、Zr elements on the glass forming ability and the thermal stability of the alloys. The formation of amorphous alloys are sensitive to contens of these two elements. The completely amorphous alloy or the primary amorphous phase alloy can be obtained when the content of Cu or Zr reach an optimization, otherwise only gaining crystal phase. Al80Ni10Zr7Cu1Y2 and Al80Ni10Zr3Cu5Y2 alloys possess the excellent glass forming ability, which can form the completely amorphous alloy or the composite material of the partial crystal in remaining amorphous.

scholarly journals Effect of alloying elements on thermal stability of nanocrystalline Al alloys

2021 ◽  
Vol 31 (1) ◽  
pp. 11-23
Author(s):  
Hany Rizk AMMAR ◽  
Muneer BAIG ◽  
Asiful Hossain SEIKH ◽  
Jabair Ali MOHAMMED
Keyword(s):  
Thermal Stability ◽  
Al Alloys ◽  
Alloying Elements ◽  
Thermal Stability Of ◽  
Effect Of Alloying

Toxic properties of Aeromonas proteolytica

1974 ◽  
Vol 20 (10) ◽  
pp. 1403-1409 ◽  
Author(s):  
B. G. Foster ◽  
Mary O. Hanna
Keyword(s):  
Thermal Stability ◽  
Culture Filtrate ◽  
Hemolytic Activity ◽  
Optimal Growth ◽  
Growth Conditions ◽  
The Other ◽  
Activity Peak ◽  
Endopeptidase Activity ◽  
Time Periods ◽  
Thermal Stability Of

Aeromonas proteolytica was grown for various time periods in nutrient broth, tryptic soy broth, a semisynthetic medium, and 1 and 5% peptone under different conditions involving temperature and in continuous shake and stationary flasks. The cell-free culture filtrates were tested for hemolytic, endopeptidase, and dermonecrotic activity and optimal growth conditions for their production were determined. The dermonecrotic activity and endopeptidase activity was found to be parallel in all tests, while hemolysin was independent of the other two. Studies on the thermal stability of the culture filtrate revealed that hemolysin and dermonecrotic and endopeptidase activity were destroyed at 70 °C for 30 min. Fractionation of the filtrate by Sephadex G-200 resolved three peaks at 280 nm. Peak I was inactive; peak II contained endopeptidase and dermonecrotic and hemolytic activity; peak III contained pigment and hemolysin. Evidence is presented that the endopeptidase and dermonecrotic substance found in the cell-free filtrates of A. proteolytica grown medium appear at the same time and thus may be the same entity.

scholarly journals Thermal Stability of Field- and Stress-Induced Anisotropy in Nanocrystalline Fe-Based and Amorphous Co-Based Alloys

1999 ◽  
Vol 32 (1-4) ◽  
pp. 281-287 ◽  
Author(s):  
N. V. Dmitrieva ◽  
V. A. Lukshina ◽  
G. V. Kurlyandskaya ◽  
A. P. Potapov
Keyword(s):  
Thermal Stability ◽  
Magnetic Anisotropy ◽  
Amorphous Alloys ◽  
Nanocrystalline Alloy ◽  
Induced Anisotropy ◽  
External Effects ◽  
Nanocrystalline And Amorphous ◽  
Induced Magnetic Anisotropy ◽  
Stress Induced Anisotropy ◽  
Thermal Stability Of

Thermal stability of induced magnetic anisotropy (IMA) was studied in a course of subsequent annealings without any external effects for already field- or stress-annealed specimens of the nanocrystalline Fe73.5Cu1Nb3Si13.5B9 and amorphous Fe3Co67Cr3Si15B12 alloys. For these alloys the dependence of IMA thermal stability on the magnitude of the IMA constant (Ku) and temperature of stress-annealing was investigated. For the nanocrystalline alloy thermal stability of field- and stress-induced anisotropy with identical Ku was compared. It was shown that nanocrystalline specimens with identical Ku values after field- or stress-annealing have identical thermal stability of IMA. This can point to a similarity of the mechanisms of IMA formation after field- or stress-annealings. Thermal stability of stress-induced anisotropy in the nanocrystalline alloy with Ku value less than 1000 J/m3 and the amorphous alloy with Ku less than 100 J/m3 depends on the value of Ku. For both stress-annealed nanocrystalline and amorphous alloys magnetic anisotropy induced at higher temperatures is more stable because more long-range and energy-taking processes take place at these temperatures.

Solid state amorphization reactions in deformed Ni-Zr multilayered composites

1990 ◽  
Vol 5 (3) ◽  
pp. 488-497 ◽  
Author(s):  
G. C. Wong ◽  
W. L. Johnson ◽  
E. J. Cotts
Keyword(s):  
Thermal Stability ◽  
Solid State ◽  
Amorphous Phase ◽  
Equilibrium Phase ◽  
Solid State Reactions ◽  
Heat Of Mixing ◽  
Scanning Calorimetry ◽  
Multilayered Composites ◽  
State Amorphization ◽  
Thermal Stability Of

The mechanisms of metallic glass formation and competing crystallization processes in mechanically-deformed Ni-Zr multilayered composites have been investigated by means of differential scanning calorimetry and x-ray diffraction. Our investigation of the heat of formation of amorphous NixZr1−x alloys shows a large negative heat of mixing (on the order of 30 kJ/mole) for compositions near Zr55Ni45 with a compositional dependence qualitatively similar to that predicted by mean field theory. We find that the products of solid state reactions in composites of Ni and Zr can be better understood in terms of the equilibrium phase diagram and the thermal stability of liquid quenched metallic glasses. We have determined the composition of the growing amorphous phase at the Zr interface in these Ni-Zr diffusion couples to be 55 ± 4% Zr. We investigated the kinetics of solid state reactions competing with the solid state amorphization reaction and found the value of the activation energy of the initial crystallization and growth of the growing amorphous phase to be 2.0 ± 0.1 eV, establishing an upper limit on the thermal stability of the growing amorphous phase.

THERMAL STABILITY OF AMORPHOUS ALLOYS

1980 ◽  
Vol 41 (C8) ◽  
pp. C8-559-C8-562 ◽  
Author(s):  
K. H.J. Buschow
Keyword(s):  
Thermal Stability ◽  
Amorphous Alloys ◽  
Thermal Stability Of

Synthesis of Fe-rich Fe–Al nanocrystalline solid solutions using ball milling

1999 ◽  
Vol 14 (5) ◽  
pp. 1760-1770 ◽  
Author(s):  
H. G. Jiang ◽  
H. M. Hu ◽  
E. J. Lavernia
Keyword(s):  
Heat Treatment ◽  
Activation Energy ◽  
Thermal Stability ◽  
Intermetallic Compound ◽  
Ball Milling ◽  
Microstructural Evolution ◽  
Solid Solutions ◽  
Al Alloys ◽  
Time Intervals ◽  
Thermal Stability Of

The synthesis of nanocrystalline Fe, Fe–4 wt% Al, and Fe–10 wt% Al solid solutions by SPEX ball milling has been studied. The microstructural evolution during ball milling, as well as subsequent heat treatment, has been characterized. The results demonstrate that ball milling promotes the formation of αFe–4 wt% Al and αFe–10 wt% Al solid solutions by reducing the activation energy of these alloys and generating thermal energy during this process. For Fe–10 wt% Al powders milled for various time intervals up to approximately 20 min, the FeAl intermetallic compound is formed. For alloys annealed at temperatures ranging from 600 to 1000 °C, the addition of 10 wt% Al to Fe significantly enhances the thermal stability of the nanocrystalline Fe–Al alloys. Interestingly, the addition of Al within the range of 4–10 wt% seems to have little effect on the thermal stability of these alloys annealed under the same conditions. Also, the thermal stability improves for alloys milled in air as opposed to those processed using Ar.

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