Influence of soil pH on inorganic phosphorus sorption and desorption in a humid brazilian Ultisol

Liming is a common practice to raise soil pH and increase phosphorus (P) bioavailability in tropical regions. However, reports on the effect of liming on P sorption and bioavailability are controversial. The process of phosphorus desorption is more important than P sorption for defining P bioavailability. However few studies on the relationship between soil pH and P desorption are available, and even fewer in the tropical soils. The effects of soil pH on P sorption and desorption in an Ultisol from Bahia, Brazil, were investigated in this study. Phosphorus sorption decreased by up to 21 and 34 % with pH increases from 4.7 to 5.9 and 7.0, respectively. Decreasing Langmuir K parameter and decreasing partition coefficients (Kd) with increasing pH supported this trend. Phosphorus desorption was positively affected by increased soil pH by both the total amount of P desorbed and the ratio of desorbed P to initially sorbed P. A decreased K parameter and increased Kd value, particularly at the highest pH value and highest P-addition level, endorsed this phenomenon. Liming the soil had the double effect of reducing P sorption (up to 4.5 kg ha-1 of remaining P in solution) and enhancing P desorption (up to 2.7 kg ha-1 of additionally released P into solution).

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Biochar Chemistry in a Weathered Tropical Soil: Kinetics of Phosphorus Sorption

Agriculture ◽

10.3390/agriculture11040295 ◽

2021 ◽

Vol 11 (4) ◽

pp. 295

Author(s):

Marina Moura Morales ◽

Nicholas Brian Comerford ◽

Maurel Behling ◽

Daniel Carneiro de Abreu ◽

Iraê Amaral Guerrini

Keyword(s):

Mineral Soil ◽

Soil Surface ◽

Kinetic Studies ◽

Inorganic Phosphorus ◽

Initial Reaction ◽

Phosphorus Sorption ◽

P Sorption ◽

Published Research ◽

Kinetics Of

The phosphorus (P) chemistry of biochar (BC)-amended soils is poorly understood. This statement is based on the lack of published research attempting a comprehensive characterization of biochar’s influence on P sorption. Therefore, this study addressed the kinetic limitations of these processes. This was accomplished using a fast pyrolysis biochar made from a mix of waste materials applied to a highly weathered Latossolo Vermelho distrofico (Oxisol) from São Paulo, Brazil. Standard method (batch method) was used. The sorption kinetic studies indicated that P sorption in both cases, soil (S) and soil-biochar (SBC), had a relatively fast initial reaction between 0 to 5 min. This may have happened because adding biochar to the soil decreased P sorption capacity compared to the mineral soil alone. Presumably, this is a result of: (i) Inorganic phosphorus desorbed from biochar was resorbed onto the mineral soil; (ii) charcoal particles physically covered P sorption locations on soil; or (iii) the pH increased when BC was added SBC and the soil surface became more negatively charged, thus increasing anion repulsion and decreasing P sorption.

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Linking phosphorus sorption and magnetic susceptibility in clays and tropical soils

Soil Research ◽

10.1071/sr20099 ◽

2020 ◽

Vol 58 (5) ◽

pp. 430 ◽

Cited By ~ 1

Author(s):

G. C. Poggere ◽

V. Barrón ◽

A. V. Inda ◽

J. Z. Barbosa ◽

A. D. B. Brito ◽

...

Keyword(s):

Magnetic Susceptibility ◽

Adsorption Capacity ◽

Tropical Soils ◽

Maximum Adsorption Capacity ◽

Phosphorus Sorption ◽

P Adsorption ◽

Opposite Trend ◽

Adsorption Data ◽

The Relationship ◽

P Desorption

Maghemite (Mh) and magnetic susceptibility have been little studied in relation to phosphorus (P) sorption, despite the fact that tropical soils – particularly those derived from mafic rocks – may contain substantial amounts of this iron oxide. In this work, we investigated the relationship between P adsorption and magnetic susceptibility in tropical soils, and determined the maximum adsorption capacity of P (MACP) and P desorption in seven pedogenic clays from magnetic soils with contrasting parent materials and three synthetic Mh samples. Considering the heterogeneity of the soil dataset in this study, the exclusive adoption of magnetic susceptibility as an indicator of P adsorption potential in soil remains uncertain. The relationship between magnetic susceptibility and adsorbed P was more evident in the B horizon of red soils from basic igneous rocks. In this group, soils with magnetic susceptibility above 20 × 10−6 m3 kg−1 had high adsorbed P. Although the pedogenic clays exhibited lower MACP values (1353–2570 mg kg–1) than the synthetic Mh samples (3786–4321 mg kg–1), P desorption exhibited the opposite trend (~14% vs ~8%). The substantial P adsorption capacity of synthetic Mh confirmed the adsorption data for pedogenic clays, which were strongly influenced by magnetic susceptibility, Mh and gibbsite contents, and specific surface area.

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Phosphorus sorption on tropical soils with relevance to Earth system model needs

Soil Research ◽

10.1071/sr18197 ◽

2019 ◽

Vol 57 (1) ◽

pp. 17 ◽

Cited By ~ 2

Author(s):

Julia Brenner ◽

Wesley Porter ◽

Jana R. Phillips ◽

Joanne Childs ◽

Xiaojuan Yang ◽

...

Keyword(s):

Sorption Isotherms ◽

Clay Content ◽

Tropical Soils ◽

Soil Characteristics ◽

P Availability ◽

Earth System ◽

Phosphorus Sorption ◽

Soil P ◽

P Sorption ◽

Earth System Models

Phosphorus (P) availability critically limits the productivity of tropical forests growing on highly weathered, low-P soils. Although efforts to incorporate P into Earth system models (ESMs) provide an opportunity to better estimate tropical forest response to climate change, P sorption dynamics and controls on soil P availability are not well constrained. Here, we measured P and dissolved organic carbon (DOC) sorption isotherms on 23 soils from tropical Oxisol, Ultisol, Inceptisol, Andisol, and Aridisol soils using P concentrations from 10 to 500mg P L−1, and DOC concentrations from 10 to 100mg DOC L−1. Isotherms were fit to the Langmuir equation and parameters were related to soil characteristics. Maximum P sorption capacity (Qmax) was significantly correlated with clay content (ρ=0.658) and aluminium (Al)- or iron (Fe)-oxide concentrations (ρ=0.470 and 0.461 respectively), and the DOC Qmax was correlated with Fe oxides (ρ=0.491). Readily available soil characteristics could eventually be used to estimate Qmax values. Analysis of literature values demonstrated that the maximum initial P concentration added to soils had a significant impact on the resultant Qmax, suggesting that an insufficiently low initial P range could underestimate Qmax. This study improves methods for measuring P Qmax and estimating Qmax in the absence of isotherm analyses and provides key data for use in ESMs.

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PHOSPHORUS SORPTION KINETIC ON ACID UPLAND SMECTITIC SOIL AMENDED WITH CALCIUM CARBONATE AND CALCIUM SILICATE

Jurnal Ilmu Tanah dan Lingkungan ◽

10.29244/jitl.11.2.58-62 ◽

2019 ◽

Vol 11 (2) ◽

pp. 58-62

Author(s):

Arief Hartono

Keyword(s):

Calcium Carbonate ◽

Rate Constant ◽

Soil Ph ◽

Calcium Silicate ◽

Chemical Properties ◽

Order Kinetic ◽

Phosphorus Sorption ◽

Sorption Kinetic ◽

P Sorption ◽

Exchangeable Al

Acid upland smectitic soil is identified by high amount of exchangeable Al due to the weathering of aluminum (Al) octahedral layer by H+ saturation and by very low phosphorus (P) status. Calcium carbonate (CaCO3) and calcium silicate (CaSiO3) were commonly used to decrease exchangeable Al and increase soil pH. Laboratory experiments were conducted with clayey smectitic Typic Paleudults from Gajrug region, West Java. The CaCO3 and CaSiO3 were added at rates to replace 0, 1.5 or 3 times of exchangeable Al. After one month of incubation, P sorption kinetic experiments were conducted. The changes in some chemical properties after one month incubation showed that both CaCO3 and CaSiO3 increased the soil pH, exchangeable Ca, and base saturation but did not increase the cation exchange capacity. The results of the experiment showed that both CaCO3 and CaSiO3 decreased the rate constant value of first order kinetic equation (k) and the P sorbed maximum (a) at given amount of added P compared to Control.The CaCO3 was better than CaSiO3 in decreasing k values and on the contrary for a values. The decrease in P maximum sorption and the rate constant of the soil amended with CaSiO3 and CaCO3 due to occupation of P sorption sites by silicates and hydroxyl ions. The CaCO3with the rate to replace 1.5 x exchangeable Al was recommended to decrease the rate constant of P sorption. However, the CaSiO3 at the rate to replace 3 x exchangeable Al was recommended to decrease the maximum P sorption.

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Competitive sorption and desorption of phosphate and citrate in clayey and sandy loam soils

Revista Brasileira de Ciência do Solo ◽

10.1590/s0100-06832014000400011 ◽

2014 ◽

Vol 38 (4) ◽

pp. 1153-1161 ◽

Cited By ~ 9

Author(s):

Matheus Fonseca de Souza ◽

Emanuelle Mercês Barros Soares ◽

Ivo Ribeiro da Silva ◽

Roberto Ferreira Novais ◽

Mailson Félix de Oliveira Silva

Keyword(s):

Organic Acids ◽

Factorial Design ◽

Sandy Loam ◽

Competitive Sorption ◽

Phosphorus Sorption ◽

P Sorption ◽

Combined Application ◽

P Application ◽

Phosphorus Desorption ◽

In The Beginning

The increase of organic acids in soils can reduce phosphorus sorption. The objective of the study was to evaluate the competitive sorption of P and citrate in clayey and sandy loam soils, using a stirred-flow system. Three experiments were performed with soil samples (0-20 cm layer) of clayey (RYL-cl) and sandy loam (RYL-sl) Red Yellow Latosols (Oxisols). In the first study, the treatments were arranged in a 2 × 5 factorial design, with two soil types and five combinations of phosphorus and citrate application (only P; P + citrate; and citrate applied 7, 22, 52 min before P); in the second, the treatments were arranged in a 2 × 2 factorial design, corresponding to two soils and two forms of P and citrate application (only citrate and citrate + P); and in the third study, the treatments in a 2 × 2 × 6 factorial design consisted of two soils, two extractors (citrate and water) and six incubation times. In the RYL-cl and RYL-sl, P sorption was highest (44 and 25 % of P application, respectively), in the absence of citrate application. Under citrate application, P sorption was reduced in all treatments. The combined application of citrate and P reduced P sorption to 25.8 % of the initially applied P in RYL-cl and to 16.7 % in RYL-sl, in comparison to P without citrate. Citrate sorption in RYL-cl and RYL-sl was highest in the absence of P application, corresponding to 32.0 and 30.2 % of the citrate applied, respectively. With P application, citrate sorption was reduced to 26.4 and 19.7 % of the initially applied citrate in RYL-cl and RYL-sl, respectively. Phosphorus desorption was greater when citrate was used. Phosphorus desorption with citrate and water was higher in the beginning (until 24 h of incubation of P) in RYL-cl and RYL-sl, indicating a rapid initial phase, followed by a slow release phase. This suggests that according to the contact time of P with the soil colloids, the previously adsorbed P can be released to the soil solution in the presence of competing ligands such as citrate. In conclusion, a soil management with continuous input of organic acids is desirable, in view of their potential to compete for P sorption sites, especially in rather weathered soils.

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ADSORÇÃO DE FÓSFORO EM SOLOS DE REGIÕES TROPICAIS

Nativa ◽

10.31413/nativa.v9i1.10973 ◽

2021 ◽

Vol 9 (1) ◽

pp. 30-35

Author(s):

Ana Paula Carrara Vinha ◽

Bruna Helena Carrara ◽

Emanuella Farias Santos Souza ◽

Jussane Antunes Fogaça dos Santos ◽

Sayonara Andrade C.Moreno Arantes

Keyword(s):

Organic Matter ◽

Adsorption Capacity ◽

Clay Content ◽

Tropical Soils ◽

Exchange Capacity ◽

Phosphorus Sorption ◽

Phosphorus Adsorption ◽

Adsorption Dynamics ◽

Tropical Regions ◽

P Adsorption

O fósforo (P) é o nutriente mais limitante ao cultivo nos solos tropicais, que, geralmente, apresentam alta capacidade de adsorção de P. Alguns atributos químicos e físicos do solo como o teor de argila, pH, CTC efetiva e matéria orgânica influenciam na dinâmica de adsorção. O objetivo deste estudo foi avaliar o processo de adsorção do fósforo em um Latossolo Vermelho Amarelo (LVA) e um Neossolo Quartzarênico (RQ) da região de transição Cerrado-Amazônia, e avaliar os atributos dos solos que influenciam na dinâmica de adsorção do P. Os ensaios de sorção foram realizados pelo método “Batch” ou em batelada e à partir dos dados obtidos foram construídas curvas obtendo a equação linearizada de Langmuir, com as quais foram determinados os valores de capacidade máxima de adsorção de P (CMAP), a constante relacionada com a energia de ligação (KL) e o fator capacidade de P máximo (FCPmáx). Houve diferença na CMAP, KL e FCPmáx dos solos estudados, sendo que os maiores valores foram encontrados no LVA, devido principalmente ao maior teor de argila em relação ao RQ. A matéria orgânica foi um dos poucos atributos que tiveram correlação negativa com os atributos de adsorção, ressaltando sua importância no manejo para aumentar a eficiência da adubação fosfatada. Palavras-chave: Latossolo Vermelho Amarelo; Neossolo Quartzarênico; Isotermas de adsorção. Phosphorus adsorption in soils of tropical regions ABSTRACT: Phosphorus (P) is the most limiting nutrient for cultivation in tropical soils, as they generally have high P adsorption capacity. Some chemical and physical attributes of soil such as clay content, pH, effective cation exchange capacity (ECEC) and organic matter influence the adsorption dynamics. The objective of this study was to evaluate the behaviour of the phosphorus adsorption process in a Red-Yellow Latosol and a Quartzarenic Neosol from the Cerrado-Amazon transition region, and to evaluate the soil attributes that influence the adsorption dynamics of the soil of the phosphorus. Sorption tests were performed using the “Bach” method, from the Langmuir linearized equation, the maximum P adsorption capacity (MPAC), the constant with the binding energy (KB) and the maximum capacity factor (PCFmax) were selected. There was a difference in MPAC, KB and PCFmax of the studied soils, and the highest values were found in the Red-Yellow Oxisol, mainly due to the higher clay content in relation to theTypic Quartzipisamment. Organic matter was one of the few attributes that had a negative correlation with the adsorption attributes, highlighting (emphasizing) it’s importance in (soil) management to increase the efficiency of phosphate fertilization. Keywords: Red-Yellow Latosol; Quartzarenic Neosol; adsorption isotherms.

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Describing Phosphorus Sorption Processes on Volcanic Soil in the Presence of Copper or Silver Engineered Nanoparticles

Minerals ◽

10.3390/min11040373 ◽

2021 ◽

Vol 11 (4) ◽

pp. 373

Author(s):

Jonathan Suazo-Hernández ◽

Erwin Klumpp ◽

Nicolás Arancibia-Miranda ◽

Patricia Poblete-Grant ◽

Alejandra Jara ◽

...

Keyword(s):

Organic Matter ◽

Crop Production ◽

Agricultural Soils ◽

Ph Value ◽

Consumer Products ◽

Soil Samples ◽

Engineered Nanoparticles ◽

P Availability ◽

Agricultural Crop ◽

Phosphorus Sorption

Engineered nanoparticles (ENPs) present in consumer products are being released into the agricultural systems. There is little information about the direct effect of ENPs on phosphorus (P) availability, which is an essential nutrient for crop growthnaturally occurring in agricultural soils. The present study examined the effect of 1, 3, and 5% doses of Cu0 or Ag0 ENPs stabilized with L-ascorbic acid (suspension pH 2–3) on P ad- and desorption in an agricultural Andisol with total organic matter (T-OM) and with partial removal of organic matter (R-OM) by performing batch experiments. Our results showed that the adsorption kinetics data of H2PO4− on T-OM and R-OM soil samples with and without ENPs were adequately described by the pseudo-second-order (PSO) and Elovich models. The adsorption isotherm data of H2PO4− from T-OM and R-OM soil samples following ENPs addition were better fitted by the Langmuir model than the Freundlich model. When the Cu0 or Ag0 ENPs doses were increased, the pH value decreased and H2PO4− adsorption increased on T-OM and R-OM. The H2PO4− desorption (%) was lower with Cu0 ENPs than Ag0 ENPs. Overall, the incorporation of ENPs into Andisols generated an increase in P retention, which may affect agricultural crop production.

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Modifications of phosphorus in Latosol as a function of humic acids and acidity

Revista Brasileira de Engenharia Agrícola e Ambiental ◽

10.1590/1807-1929/agriambi.v22n7p488-492 ◽

2018 ◽

Vol 22 (7) ◽

pp. 488-492 ◽

Cited By ~ 1

Author(s):

Márcia H. Beck ◽

Pedro A. V. Escosteguy ◽

Deborah P. Dick

Keyword(s):

Factorial Design ◽

Humic Acids ◽

Soil Ph ◽

Crucial Role ◽

Soil Acidity ◽

Ph Value ◽

P Availability ◽

Soil P ◽

P Content

ABSTRACT The effect of humic acids (HA) on phosphorus (P) availability is still contradictory; thus, it is necessary to identify the conditions that play a crucial role in this effect. The aim of this study was to investigate the effect of HA application, combined with doses of P, on the content of this nutrient in a Latosol with and without acidity correction. Two experiments were carried out, one with HA from peat and another with HA from mineral charcoal (leonardite). Doses of these acids (0; 1.12 and 5.62 mg C g-1 of soil) and P (26.2 and 104.7 mg P g-1 of soil, 1 and 4-fold higher than recommended, respectively) were tested at soil pH 4.5 and 7.0, in a three-factorial design. The soil was incubated for 20 days and the soil-P content was measured by Mehlich-1 and remaining-P tests. The effect of HAs on P availability varied with the P doses and soil acidity. Humic acids application increases P content in Latosol when P dose is higher than recommended and there is no acidity correction (pH 4.5). However, there is no effect of HAs application on soil-P content when applying the recommended amount of this nutrient, irrespective of the pH value.

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