scholarly journals Characterization and nutrient release from silicate rocks and influence on chemical changes in soil

2012 ◽  
Vol 36 (3) ◽  
pp. 951-962 ◽  
Author(s):  
Douglas Ramos Guelfi Silva ◽  
Giuliano Marchi ◽  
Carlos Roberto Spehar ◽  
Luiz Roberto Guimarães Guilherme ◽  
Thomaz Adolpho Rein ◽  
...  

The expansion of Brazilian agriculture has led to a heavy dependence on imported fertilizers to ensure the supply of the growing food demand. This fact has contributed to a growing interest in alternative nutrient sources, such as ground silicate rocks. It is necessary, however, to know the potential of nutrient release and changes these materials can cause in soils. The purpose of this study was to characterize six silicate rocks and evaluate their effects on the chemical properties of treated soil, assessed by chemical extractants after greenhouse incubation. The experimental design consisted of completely randomized plots, in a 3 x 6 factorial scheme, with four replications. The factors were potassium levels (0-control: without silicate rock application; 200; 400; 600 kg ha-1 of K2O), supplied as six silicate rock types (breccia, biotite schist, ultramafic rock, phlogopite schist and two types of mining waste). The chemical, physical and mineralogical properties of the alternative rock fertilizers were characterized. Treatments were applied to a dystrophic Red-Yellow Oxisol (Ferralsol), which was incubated for 100 days, at 70 % (w/w) moisture in 3.7 kg/pots. The soil was evaluated for pH; calcium and magnesium were extracted with KCl 1 mol L-1; potassium, phosphorus and sodium by Mehlich 1; nickel, copper and zinc with DTPA; and the saturation of the cation exchange capacity was calculated for aluminum, calcium, magnesium, potassium, and sodium, and overall base saturation. The alternative fertilizers affected soil chemical properties. Ultramafic rock and Chapada mining byproduct (CMB) were the silicate rocks that most influenced soil pH, while the mining byproduct (MB) led to high K levels. Zinc availability was highest in the treatments with mining byproduct and Cu in soil fertilized with Chapada and mining byproduct.

2015 ◽  
Vol 39 (1) ◽  
pp. 194-204 ◽  
Author(s):  
Vanessa Martins ◽  
Douglas Ramos Guelfi Silva ◽  
Giuliano Marchi ◽  
Maurício Cunha Almeida Leite ◽  
Éder de Souza Martins ◽  
...  

The current high price of potassium chloride and the dependence of Brazil on imported materials to supply the domestic demand call for studies evaluating the efficiency of alternative sources of nutrients. The aim of this work was to evaluate the effect of silicate rock powder and a manganese mining by-product, and secondary materials originated from these two materials, on soil chemical properties and on brachiaria production. This greenhouse experiment was conducted in pots with 5 kg of soil (Latossolo Vermelho-Amarelo distrófico - Oxisol). The alternative nutrient sources were: verdete, verdete treated with NH4OH, phonolite, ultramafic rock, mining waste and the proportion of 75 % of these K fertilizers and 25 % lime. Mixtures containing 25 % of lime were heated at 800 ºC for 1 h. These sources were applied at rates of 0, 150, 300, 450 and 600 kg ha-1 K2O, and incubated for 45 days. The mixtures of heated silicate rocks with lime promoted higher increases in soil pH in decreasing order: ultramafic rock>verdete>phonolite>mining waste. Applying the mining waste-lime mixture increased soil exchangeable K, and available P when ultramafic rock was incorporated. When ultramafic rock was applied, the release of Ca2+ increased significantly. Mining subproduct released the highest amount of Zn2+ and Mn2+ to the soil. The application of alternative sources of K, with variable chemical composition, altered the nutrient availability and soil chemical properties, improving mainly plant development and K plant uptake, and are important nutrient sources.


Lithos ◽  
2013 ◽  
Vol 175-176 ◽  
pp. 30-39 ◽  
Author(s):  
J. Seo ◽  
C.W. Oh ◽  
S.G. Choi ◽  
V.J. Rajesh

2021 ◽  
Vol 24 (1) ◽  
pp. 77-87
Author(s):  
SS Keya ◽  
MG Miah ◽  
MA Rahman ◽  
MT Islam

Excess use of agrochemicals for intensive cultivation affects crop quality and destroys agro-ecosystems, and eventually creates health hazards. The study aims to investigate the effect of Gliricidia sepium (GS) tree leaf as suitable green manures for supplementing nutrient supply along with nitrogen (N) fertilizer to produce quality tomato and soil fertility improvement. A field experiment was conducted at the Bangabandhu Sheikh Mujibur Rahman Agricultural University, Bangladesh, from November 2016 to March 2017. The experiment was laid out in a randomized complete block design (two factors) with three replications. There were nine treatment combinations with three levels of GS tree leaves (5, 10 and 15 t ha−1) and three doses of N (0, 50 and 100% of the recommended dose of fertilizer). The highest tomato yield was recorded in GS15×N100 treatment combination, which was 41.68% higher compared to the control treatment. Decreasing C: N ratio in increasing dose of GS and N treated plot indicated the quality of tree leaves that ensures faster decomposition and high nutrient release pattern of this species. Increasing rate of soil pH and cation exchange capacity (CEC) in different treatments as compared to initial soil showed soil fertility improvement. Overall, the results indicated that quality tomato could be grown successfully by the application of G. sepium tree leaves along with an appropriate amount of N fertilizer. Ann. Bangladesh Agric. (2020) 24(1) : 77-87


2022 ◽  
Author(s):  
Omar Alfarisi ◽  
Djamel Ouzzane ◽  
Mohamed Sassi ◽  
TieJun Zhang

<p><a></a>Each grid block in a 3D geological model requires a rock type that represents all physical and chemical properties of that block. The properties that classify rock types are lithology, permeability, and capillary pressure. Scientists and engineers determined these properties using conventional laboratory measurements, which embedded destructive methods to the sample or altered some of its properties (i.e., wettability, permeability, and porosity) because the measurements process includes sample crushing, fluid flow, or fluid saturation. Lately, Digital Rock Physics (DRT) has emerged to quantify these properties from micro-Computerized Tomography (uCT) and Magnetic Resonance Imaging (MRI) images. However, the literature did not attempt rock typing in a wholly digital context. We propose performing Digital Rock Typing (DRT) by: (1) integrating the latest DRP advances in a novel process that honors digital rock properties determination, while; (2) digitalizing the latest rock typing approaches in carbonate, and (3) introducing a novel carbonate rock typing process that utilizes computer vision capabilities to provide more insight about the heterogeneous carbonate rock texture.<br></p>


2017 ◽  
Vol 38 (1) ◽  
pp. 143
Author(s):  
Liane Barreto Alves Pinheiro ◽  
Rodrigo Camara ◽  
Marcos Gervasio Pereira ◽  
Eduardo Lima ◽  
Maria Elizabeth Fernandes Correia ◽  
...  

Mound-building termites are important agents of soil bioperturbation, but these species have not been extensively studied thus far. The present study aimed to evaluate the soil particle-size and the chemical attributes of termite mounds and the surrounding soil under different land use strategies. A one-hectare plot was defined for an unmanaged degraded pasture, planted pasture, and for a eucalyptus Corymbia citriodora plantation. In each plot, the top, center, and base sections of five Cornitermes cumulans mounds, and the surrounding soil at the depths of 0-5; 5-10; 10-20 cm, were sampled in the Pinheiral, Rio de Janeiro state. In the three areas, the center of the mounds contained higher clay content, organic carbon, phosphorous, calcium and magnesium, total bases, and cation exchangeable capacity, when compared to the top, base, and the surrounding soils. However, the center had lower values of exchangeable acidity and potassium, of the three areas. In the eucalyptus plantation, the values of pH, total bases, calcium, and magnesium were lower, whereas aluminum, exchangeable acidity, sodium, and cation exchange capacity were higher both in the mounds and in the surrounding soil, in relation to the pastures. There were no differences among the three areas in terms of organic carbon, potassium, phosphorous, and total bases, in the mounds and adjacent soil. Thus, the termite activity altered the clay content and most of the soil chemical properties in all of the studied areas, but only for the center of the mounds. However, the effect of these organisms was different in the eucalyptus plantation in relation to the pasture areas.


2019 ◽  
Vol 14 (1) ◽  
pp. 20-34
Author(s):  
T. G. RYASHCHENKO ◽  
N. N. UKHOVA ◽  
S. I. SHTELMAKH ◽  
N. I. BELYANINA ◽  
P. S. BELYANIN

The article considers the study results of composition, microstructure and physical-chemical properties of the quaternary clays of the Prikhankayskaya depression in district of the lake Khanka (Primorye) on the example of air-dry samples of geological borehole 45-b in the range of 18–62 m. The objective of research was to obtain new information about the properties of widespread clay sediments in this area using geologic-lithological materials and laboratory data. The schematic geologic-lithological column was composed with the selection of various zones in the quaternary clay sediments section and the border with sediments of the Neogene System. The methodological scheme of laboratory studies of clays was proposed. This scheme includes the determination of chemical and microelement composition, clay minerals, contents of carbonates, water-soluble salts, mobile forms of aluminum oxide, humus, as well as microstructural parameters (method «Microstructure») and some physical-chemical properties. Geochemical coefficients (Kz, CIA, CIW, ICV) determined the degree of chemical maturity of clays and confirmed the results of palynological studies reflecting the fluctuations of the climatic conditions of their formation. For the group of toxic microelements for the first time the special indicator (Zc) was calculated. Which was the criterion for a degree of pollution of the clay sediments section. Clay minerals of the quaternary clays are represented by smectite and hydromica. The clear change in the mineral association was found when passing to the Neogene sediments (kaolinite prevails). The method «Microstructure» revealed the aggregated type of clays microstructure, the domination of the particles of coarse dust fraction among the primary (free) particles and the almost complete absence of the particles of fine-grained sand fraction, the participation of various fractions in the composition of aggregates. The variants of the formation of certain types of aggregates (on sizes) in the fluviolacustrine «khankayskiy» clays are presented. Solid part density, water resistance (soaking time), sedimentation volume, plasticity, relative swelling (samples-pastes) were determined using standard methods for clays. By special methods, the cation exchange capacity was measured and the calculated values of the plasticity index were obtained from forecasting formulas using the yield limit. The proposed methodological scheme of complex laboratory studies of clay sediments can be recommended for problematic geologic-lithological and engineering-geological sections.


Author(s):  
Vítězslav Vlček ◽  
Miroslav Pohanka

Soil samples (n = 11) were collected in the chernozem areas of the Czech Republic (the Central Europe) from the topsoil and used as representative samples. All sampling areas have been used for agricultural purposes (arable soil) and they were selected as typical representatives of agricultural soil. These samples represented the soil with same genesis (to reduction differencies between soil types) but with different soil properties (physical and chemical). Complete chemical and physical analyses were made for confirmation of copper adsorption on solid phase: we analysed the particle size distribution, content of oxidizable carbon (Cox), the cation exchange capacity (CEC), supply of exchange calcium, magnesium, sodium, phosphorus and potassium, soil reaction and the total supply of Fe, Al, Mn, Ca, Mg, K, P and N. The strongest simple correlation between analysed soil properties and copper concentration had content of available magnesium (r = 0.44) and available phosphorus (r = −0.51). In the case of multiple correlations (i. e. collective influence of multiple soil properties) had the strongest influence combination of clay, soil reaction, total content of phosphorus, available magnesium and available phosphorus. The main influence of phosphorus and magnesium is evident. We suppose that copper and phosphorus enter into specific complex. Influence of these five soil properties can explain 92.7 % (r = 0.927) changes in the content of copper changes in the experiment.


Author(s):  
C. V. Ogbenna ◽  
V. E. Osodeke

Aim: A pot experiment was carried out to determine the effect of sawdust ash and lime (Ca(OH)2) on soil characteristics and yield of sunflower in acidic soil of southeastern Nigeria. Study Design: The experiment was laid out in split-plot design, using sawdust ash (0, 1, 2, 3, 4 t ha-1) as the sub plot and lime (0, 0.5, 1.0, 1.5 t ha-1) as the main plot. Place and Duration of Study: Study was conducted outdoors at Michael Okpara University of Agriculture Umudike, Nigeria, during the 2010 planting season. Materials and Methods: Treatment combinations were applied to the 60 buckets containing soil, mixed thoroughly and watered adequately. After 1 week of treatment application, two sunflower seeds were planted and later thinned to one seedling per bucket. Plant growth and yield data were collected. Pre planting and post-harvest soil samples were collected and analyzed for soil properties. Results: Results showed that with the exception of organic carbon there was significant effect of treatments on all soil chemical properties. Lime and sawdust ash (SDA) as single and combined treatments significantly increased total nitrogen (P=0.05), available phosphorus (P<0.010), and base saturation (P<0.012). The interaction between SDA and lime significantly (P=0.05) increased total exchangeable bases and effective cation exchange capacity, while soil pH was significantly increased (P=0.05) by single applications. The increases in soil chemical properties led to significant positive response of the sunflower. With the exception of number of leaves, other plant parameters (Plant height, stem diameter, head weight, 50 seed weight, head diameter) had significant increases for sawdust ash alone at P=0.05. Correlation studies showed positive significant relationship between soil pH and sunflower yield. Conclusion: The study showed that sunflower performed best at the combination of 3 tha-1 SDA and 1.5 t ha-1 lime producing a mean head weight of 45.4 g.


2017 ◽  
Vol 2 (1) ◽  
Author(s):  
M. M. Nasef ◽  
H. Saidi ◽  
A. H. Yahaya

Crosslinked cation exchange membranes bearing sulfonic acid groups (PE-g-PSSA/DVB) were prepared by radiationinduced grafting of styrene/divinylbenzene (DVB) mixtures onto low density polyethylene (PE) films followed by sulfonation reactions. The effect of addition of DVB (2 and 4%) on the grafting behavior and the physico-chemical properties of the membranes such as ion exchange capacity, swelling and ionic conductivity were evaluated incorrelation with grafting yield (Y%). The structural and thermal properties of the membranes were also studied using differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA), respectively. Crosslinking with DVB was found to considerably affect the properties of the membranes in a way that reduces the swelling properties and enhances the chemical stability. The ion conductivity of the crosslinked membranes recorded a level of 10–2 S/cm at sufficient grafting yield (28%) despite the reduction caused by the formation of crosslinking structure. The results of this work suggest that membranes prepared in this study are potential alternatives for various electrochemical applications.


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