The fate of natural organic matter during UV/H2O2 advanced oxidation of drinking water

Dunea, the drinking water company for The Hague and surroundings, has as objective the production of drinking water of impeccable quality, particularly with respect to organic micropollutants. As organic micropollutants are only a minor part of the total natural organic matter, a challenge is posed in targeting the removal of a very small, specific part of the DOC, without removing all of the natural organic matter. In addition, organic micropollutants encompass a broad range of physicochemical properties, which make their removal by a single treatment step impossible. Combining AOP with artificial recharge and recovery, two complementary processes are expected to provide a hybrid system for organic micropollutant removal, according to the Dutch multiple barrier approach. Pilot-scale experiments with O3 and different advanced oxidation processes (UV/H2O2, UV/O3 and O3/H2O2) were carried out in cooperation between Dunea and ITT Wedeco. The pilot installation had a capacity of about 0.5–2.0 m3/h, with a varying LP-UV-dose, ozone dose and peroxide dose. Atrazine, isoproturone, carbamazepine, diclofenac and ibuprofen are well removed by UV/H2O2 as well as by O3/H2O2. In general, O3/H2O2 is a more energy efficient process compared to UV/H2O2. MTBE is best removed by O3/H2O2, Amidotrizoic acid and iohexol are best removed by UV/H2O2.

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Removal of natural organic matter from drinking water by advanced oxidation processes

Chemosphere ◽

10.1016/j.chemosphere.2010.04.067 ◽

2010 ◽

Vol 80 (4) ◽

pp. 351-365 ◽

Cited By ~ 394

Author(s):

Anu Matilainen ◽

Mika Sillanpää

Keyword(s):

Drinking Water ◽

Organic Matter ◽

Natural Organic Matter ◽

Advanced Oxidation Processes ◽

Advanced Oxidation ◽

Oxidation Processes

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Coagulation/flocculation/ultrafiltration for natural organic matter removal in drinking water production

Water Science & Technology Water Supply ◽

10.2166/ws.2004.0111 ◽

2004 ◽

Vol 4 (5-6) ◽

pp. 215-222 ◽

Cited By ~ 2

Author(s):

A.R. Costa ◽

M.N. de Pinho

Keyword(s):

Drinking Water ◽

Organic Matter ◽

Natural Organic Matter ◽

Membrane Fouling ◽

Membrane Filtration ◽

Membrane Surface ◽

Water Production ◽

Cellulose Acetate Membranes ◽

Wide Range ◽

Drinking Water Production

Membrane fouling by natural organic matter (NOM), namely by humic substances (HS), is a major problem in water treatment for drinking water production using membrane processes. Membrane fouling is dependent on membrane morphology like pore size and on water characteristics namely NOM nature. This work addresses the evaluation of the efficiency of ultrafiltration (UF) and Coagulation/Flocculation/UF performance in terms of permeation fluxes and HS removal, of the water from Tagus River (Valada). The operation of coagulation with chitosan was evaluated as a pretreatment for minimization of membrane fouling. UF experiments were carried out in flat cells of 13.2×10−4 m2 of membrane surface area and at transmembrane pressures from 1 to 4 bar. Five cellulose acetate membranes were laboratory made to cover a wide range of molecular weight cut-off (MWCO): 2,300, 11,000, 28,000, 60,000 and 75,000 Da. Severe fouling is observed for the membranes with the highest cut-off. In the permeation experiments of raw water, coagulation prior to membrane filtration led to a significant improvement of the permeation performance of the membranes with the highest MWCO due to the particles and colloidal matter removal.

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