Influence of thermal cycling modes on VK8 hard alloy mechanical and tribological properties

Author(s):  
S. I. Bogodukhov ◽  
E. S. Kozik ◽  
E. V. Svidenko

Hard alloys are popular materials widely used in the toolmaking industry. Refractory carbides included in their composition make carbide tools very hard (80 to 92 HRA) and heat-resistant (800 to 1000 °С) so as they can be used at cutting speeds several times higher than those used for high-speed steels. However, hard alloys differ from the latter by lower strength (1000 to 1500 MPa) and the absence of impact strength, and this constitutes an urgent problem. We studied the influence of thermal cycling modes on the mechanical and tribological properties of VK8 (WC–8Co) hard alloy used in the manufacture of cutters and cutting inserts for metal working on metal-cutting machines. As the object of study, we selected 5×5×35 mm billets made of VK8 (WC–8Co) alloy manufactured by powder metallurgy methods at Dimitrovgrad Tool Plant. The following criteria were selected for heat treatment mode evaluation: Vickers hardness, flexural strength, and mass wear resistance (as compared to the wear of asreceived samples that were not heat treated). Plates in the initial state and after heat treatment were subjected to abrasion tests. Wear results were evaluated by the change in the mass of plates. Regularities of the influence of various time and temperature conditions of heat treatment on the tribological properties of products made of VK group tungsten hard alloys were determined. An increase in the number of thermal cycling cycles improved such mechanical properties of the VK8 hard alloy as strength and hardness. When repeating the cycles five times, an increase in abrasive wear resistance was obtained compared to the initial nonheat-treated sample. The elemental composition of the VK8 hard alloy changed insignificantly after thermal cycling, only a slight increase in oxygen was observed on the surface of plates. The grain size after thermal cycling increased in comparison with the initial VK8 hard alloy. It was found that VK8 hard alloy thermocyclic treatment leads to a change in the phase composition. X-ray phase analysis showed the presence of a large amount of α-Co with an hcp-type lattice on the surface of a hard alloy and a solid solution of WC in α-Co. A change in the cobalt modification ratio causes a decrease in microstresses. An analysis of the carbide phase structure state showed that the size of crystallites and microstresses changed after thermal cycling. The lattice constant of the cobalt cubic solid solution decreased, which may indicate a decrease in the amount of tungsten carbide and carbon dissolved in it. Statistical processing of experimental results included the calculation of the average value of the mechanical property, its dispersion and standard deviation in the selected confidence interval.

2006 ◽  
Vol 129 (4) ◽  
pp. 523-529 ◽  
Author(s):  
Ping Huang ◽  
Rong Liu ◽  
Xijia Wu ◽  
Matthew X. Yao

The chemical composition of Stellite® 21 alloy was modified by doubling the molybdenum (Mo) content for enhanced corrosion and wear resistance. The specimens were fabricated using a casting technique. Half of the specimens experienced a heat treatment at 1050°C for an hour. The microstructure and phase analyses of the specimens were conducted using electron scanning microscopy and X-ray diffraction. The mechanical properties of the specimens were determined in terms of the ASTM Standard Test Method for Tension Testing of Metallic Materials (E8-96). The mechanical behaviors of individual phases in the specimen materials were investigated using a nano-indentation technique. The wear resistance of the specimens was evaluated on a ball-on-disk tribometer. The experimental results revealed that the increased Mo content had significant effects on the mechanical and tribological properties of the low-carbon Stellite® alloy and the heat treatment also influenced these properties.


Coatings ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 670
Author(s):  
Gifty Oppong Boakye ◽  
Arna María Ormsdóttir ◽  
Baldur Geir Gunnarsson ◽  
Sandeep Irukuvarghula ◽  
Raja Khan ◽  
...  

The selection of electroless nickel-phosphorus plating (ENP) has been inclined towards their properties and advantages with complex geometry applications. These properties include coating uniformity, low surface roughness, low wettability, high hardness, lubricity, and corrosion- and wear-resistance. Materials used in geothermal environments are exposed to harsh conditions such as high loads, temperature, and corrosive fluids, causing corrosion, scaling, erosion and wear of components. To improve the corrosion- and wear-resistance and anti-scaling properties of materials for geothermal environment, a ENP duplex coating with PTFE nanoparticles was developed and deposited on mild steel within the H2020 EU Geo-Coat project. ENP thin adhesive layer and ENP+PTFE top functional layer form the duplex structure of the coating. The objective of this study was to test the mechanical and tribological properties of the developed ENP-PTFE coatings with varying PTFE content. The microstructural, mechanical and tribological properties of the as-deposited coating with increasing PTFE content in the top functional layer in the order: ENP1, ENP2 and ENP3 were evaluated. The results showed maximum wear protection of the substrates at the lowest load; however, increasing load and sliding cycles increased the wear rates, and 79% increased lubrication was recorded for the ENP2 duplex coating. The wear performance of ENP3 greatly improved with a wear resistance of 8.3 × 104 m/mm3 compared to 6.9 × 104 m/mm3 for ENP2 and 2.1 × 104 m/mm3 for ENP1. The results are applicable in developing low friction, hydrophobic or wear-resistive surfaces for geothermal application.


Coatings ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 1456
Author(s):  
Qiang Wang ◽  
Runling Qian ◽  
Ju Yang ◽  
Wenjuan Niu ◽  
Liucheng Zhou ◽  
...  

In order to improve the wear resistance of 27SiMn steel substrate, Fe−based alloy coatings were prepared by laser cladding technology in the present study. In comparison to the conventional gravity powder feeding (GF) process, high−speed powder feeding (HF) process was used to prepare Fe−based alloy coating on 27SiMn steel substrate. The effect of diversified energy composition of powder materials on the microstructure and properties of coatings were systematically studied. X−ray diffractometer (XRD), optical microscope (OM) and scanning electron microscope (SEM) were used to analyze the phase structure and microstructure of Fe−based alloy coatings, and the hardness and tribological properties were measured by the microhardness tester and ball on disc wear tester, respectively. The results show that the microstructure of conventional gravity feeding (GF) coatings was composed of coarse columnar crystals. In comparison, owing to the diversification of energy composition, the microstructure of the high−speed powder feeding (HF) coatings consists of uniform and small grains. The total energy of the HF process was 75.5% of that of the GF process, proving that high−efficiency cladding can be achieved at lower laser energy. The refinement of the microstructure is beneficial to improve the hardness and wear resistance of the coating, and the hardness of the HF coating increased by 9.4% and the wear loss decreased to 80.5%, compared with the GF coating. The wear surface of the HF coating suffered less damage, and the wear mechanism was slightly adhesive wear. In contrast, wear was more serious in the GF coating, and the wear mechanism was transformed into severe adhesive wear.


2018 ◽  
Vol 27 (47) ◽  
pp. 101
Author(s):  
Sandra Arias ◽  
Maryory Gómez ◽  
Esteban Correa ◽  
Félix Echeverría-Echeverría ◽  
Juan Guillermo Castaño

Nickel-Boron autocatalytic coatings are widely used in several industries to improve mechanical properties of materials such as hardness and wear resistance. Tribological properties were evaluated in Ni-B autocatalytic coatings deposited on AISI/SAE 1018 carbon steel before and after a heat treatment at 450 °C for one hour. Tribological tests were carried out by dry sliding, using a load of 5 N and a sliding speed of 0.012 m/s, in a homemade ball-on-disk tribometer, which followed ASTM G99 standard. According to the tribological evaluation, the heat treatments applied to Ni-B coatings improved their tribological performance. This research corroborates that by applying an adequate heat treatment, hardness and wear resistance of Ni-B coatings can be improved significantly.


2019 ◽  
Vol 26 (1) ◽  
pp. 402-411 ◽  
Author(s):  
Zhiwei Wu ◽  
Yan Wang ◽  
Sihao Li ◽  
Xiaoyong Wang ◽  
Zhaojun Xu ◽  
...  

AbstractBCN coatings with different chemical compositions were prepared using RF magnetron sputtering via adjusting N2 flow. The influence of N2 flow on the bonding structure, mechanical and tribological properties of coating was studied. The structural analysis indicated the coexistence of B-N, B-C, and N-C bonds, suggesting the formation of a ternary BCN hybridization. The maximum Vickers hardness of 1614.7 HV was obtained at the low N2 flow (5 sccm), whereas the adhesion strength of BCN coatings on 316L stainless steel was improved with an increase of N2 flow. The friction behavior of BCN coatings sliding against different materials (acerbic, beech and lauan wood) was performed using ball-on-disk tribo-meter in air. The low friction coefficient was easier to obtain as sliding against hardwood i.e. acerbic balls. BCN-5 and BCN-10 coatings presented better wear resistance regardless of softwood or hardwood, whilst other two coatings were more suitable for mating softwood i.e. beech and lauan.


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