scholarly journals Development of a flame retardant hard sprayed polyurethane foam and the study of its physicochemical, fire retardant and fire extinguishing properties

2019 ◽  
Vol 28 (5) ◽  
pp. 27-38
Author(s):  
V. V. Bogdanova ◽  
O. N. Buraya ◽  
M. M. Tikhonov
Keyword(s):  
Flame Retardant ◽  
Polyurethane Foam ◽  
Fire Retardant ◽  
Fire Extinguishing

The Study of Melamine Modified by Imidazolium Based Ionic Liquid [BMIM]PF6 on the Flame Retardancy of Rigid Polyurethane Foam

2014 ◽  
Vol 1030-1032 ◽  
pp. 241-245 ◽  
Author(s):  
Yan Wei Li
Keyword(s):  
Ionic Liquid ◽  
Flame Retardant ◽  
Polyurethane Foam ◽  
Fire Retardant ◽  
Rigid Polyurethane Foam ◽  
Flame Resistance ◽  
Initial Decomposition Temperature ◽  
Noticeable Effect ◽  
Rigid Foam ◽  
Flame Retardant Properties

In this paper, the effect of C3H6N6modified by imidazolium based Ionic Liquid 1-butyl-methylimidazolium hexafluorophosphate ([BMIM]PF6) on polyurethane rigid foam flame retardant properties was conducted.The results show that the flame retardant properties of C3H6N6 modified with Ionic Liquid significantly increased and the LOI increased form 22.3 to 24.5. In the modification process, the ionic liquid mass have a very noticeable effect to the flame retardant property and when [BMIM]PF6 and C3H6N6 in quality was 4:6, Fire-retardant effect was best.Compared with the prior to the modification, C3H6N6 modified can increase effective Flame resistance of materials, horizontal burning speed from 67.6mm/min down to 33.4mm/min.Thermal degradation data show that C3H6N6 modified could improve initial decomposition temperature and reminder yield of rigid polyurethane foam,and then heat release reduced, the decomposition controlled,thermal stability increased.

Infrared Analysis on Pyrolysis Products of Flame Retardant Rigid Polyurethane Foam

2014 ◽  
Vol 1033-1034 ◽  
pp. 900-906
Author(s):  
Ze Jiang Zhang ◽  
Li Jun Li ◽  
Feng Li ◽  
Jin He ◽  
Zi Qiong Gan
Keyword(s):  
Flame Retardant ◽  
Polyurethane Foam ◽  
Magnesium Hydroxide ◽  
Hydrogen Cyanide ◽  
Flame Retardants ◽  
Fire Retardant ◽  
Infrared Analysis ◽  
Antimony Trioxide ◽  
Stretching Vibration ◽  
Flame Retarded

Infrared spectra of the pyrolysis gases of polyurethane foam flame retarded by MPOP, MP, MC, magnesium hydroxide, or antimony trioxide flame retardants was analyzed online by FTIR method. At 600°C, the polyurethane foam flame retarded by MPOP, MP, MC, magnesium hydroxide or antimony trioxide flame retardants released more hydrogen cyanide than the pure polyurethane foam, proved that the MPOP, MP, MC and magnesium hydroxide flame retardants could change the law that the polyurethane released hydrogen cyanide. At 600 °C, the peak of C=O stretching vibration at 1730cm-1did not appear for the flame-retardant polyurethane, indicating that the flame retardants can make the polyurethane rapidly carbonize and the fewer C=O intermediate was produced. The absorbent peaks of the fire-retardant samples at 1604cm-1, 1538 cm-1, 1250 to 1230 cm-1and 1450cm-1implied that the flame retardants could delay the oxidative decomposition of the polyurethane component at 600 °C, so that more components may be carbonized. When increasing the pyrolysis temperature, the perlite would make polyurethane foam release fewer hydrogen cyanide.

Synergism between Flame Retardant and Phosphonium Salt Modified Layered Silicate on Properties of Rigid Polyurethane Foam Nanocomposite

2012 ◽  
Vol 501 ◽  
pp. 8-12 ◽  
Author(s):  
Soo Kai Wai ◽  
Ahmad Haji Sahrim ◽  
Syazana Ahmad Zubir
Keyword(s):  
Flame Retardant ◽  
Polyurethane Foam ◽  
Phosphonium Salt ◽  
Test Procedure ◽  
Fire Retardant ◽  
Layered Silicate ◽  
Weight Percentage ◽  
Combustion Enthalpy ◽  
Compression Properties ◽  
Synergistic Mechanism

The current research was conducted to study the incorporation of phosphorus-based flame retardant (exolit OP 1230) and phosphonium salt treated montmorillonite (P-MMT) into polyol resin of polyurethane foam, with the purpose of imparting its compression properties and flammability resistance. To prepare the hybrid composite with a 2.5 wt% based on weight percentage of the overall weight of the system, fractions of exolit OP 1230 are mixed with P-MMT following a percentage ratio of 25/75, 50/50 and 75/25. The result of the mechanical property testing showed that the compression strength of composite was decreased with the presence of exolit OP 1230. However, the result obtained also demonstrated that the fire behaviour of the foam was improved. The study indicated that a combination of exolite OP 1230 and P-MMT generates a synergistic mechanism effect which could be used as an effective fire retardant as compared to sample with a 2.5% P-MMT alone. On the other hand, horizontal burning test following an ASTM D635 test procedure was conducted to determine the burning rate and bomb calorimeter model Ika C5003 was employed to detect the combustion enthalpy in this study. Finally, the findings of the analysis of the mechanical properties were further supported by the SEM micrographs.

Mechanical and Flammability Properties of Green Polyurethane Foam with Alumina Trihydrate as Flame Retardant

2017 ◽  
Author(s):  
Amanda Silva ◽  
Enio Henrique Pires da Silva ◽  
Danilo Janes ◽  
Romeu Rony Cavalcante da Costa ◽  
Giovanna Gabriela Crem Silva
Keyword(s):  
Flame Retardant ◽  
Polyurethane Foam ◽  
Alumina Trihydrate

scholarly journals Effects of Graphene Nanoplatelets on Mechanical and Fire Performance of Flax Polypropylene Composites with Intumescent Flame Retardant

Molecules ◽  
2021 ◽  
Vol 26 (13) ◽  
pp. 4094
Author(s):  
Imran Ali ◽  
Nam Kyeun Kim ◽  
Debes Bhattacharyya
Keyword(s):  
Flame Retardant ◽  
Decomposition Rate ◽  
Natural Fiber ◽  
Fire Retardant ◽  
Graphene Nanoplatelets ◽  
Intumescent Flame Retardant ◽  
Fume Hood ◽  
Fire Dynamics ◽  
Polypropylene Composites ◽  
Set Up

The integration of intumescent flame-retardant (IFR) additives in natural fiber-based polymer composites enhances the fire-retardant properties, but it generally has a detrimental effect on the mechanical properties, such as tensile and flexural strengths. In this work, the feasibility of graphene as a reinforcement additive and as an effective synergist for IFR-based flax-polypropylene (PP) composites was investigated. Noticeable improvements in tensile and flexural properties were achieved with the addition of graphene nanoplatelets (GNP) in the composites. Furthermore, better char-forming ability of GNP in combination with IFR was observed, suppressing HRR curves and thus, lowering the total heat release (THR). Thermogravimetric analysis (TGA) detected a reduction in the decomposition rate due to strong interfacial bonding between GNP and PP, whereas the maximum decomposition rate was observed to occur at a higher temperature. The saturation point for the IFR additive along with GNP has also been highlighted in this study. A safe and effective method of graphene encapsulation within PP using the fume-hood set-up was achieved. Finally, the effect of flame retardant on the flax–PP composite has been simulated using Fire Dynamics Simulator.

scholarly journals Liquefaction of waste pine wood and its application in the synthesis of a flame retardant polyurethane foam

RSC Advances ◽  
2017 ◽  
Vol 7 (48) ◽  
pp. 30334-30344 ◽  
Author(s):  
Dizhu Yue ◽  
Oluwasola Oribayo ◽  
Garry L. Rempel ◽  
Qinmin Pan
Keyword(s):  
Flame Retardant ◽  
Polyurethane Foam ◽  
Sustainable Forestry ◽  
Pine Wood ◽  
Sustainable Resources ◽  
Pu Foam

The utilization of sustainable forestry waste resources in the production of polyurethane (PU) foam is a promising green alternative to the use of un-sustainable resources.

Flame-Retardant and Physical Characteristics of Flexible Hybrid Polyurethane Foam Materials Prepared Utilizing Foam-One Technology

2020 ◽  
pp. 409-416
Author(s):  
Chandra Jayakody ◽  
Dan Myers ◽  
Malcolm Crocker ◽  
Kelly Bures ◽  
Jeff Bridge ◽  
...  
Keyword(s):  
Flame Retardant ◽  
Polyurethane Foam ◽  
Physical Characteristics ◽  
Hybrid Polyurethane

scholarly journals RESEARCH OF FEATURES AND COMPOSITIONS OF VERMICULITE FOR USE AS SUSPENSION FIRE RETARDANT FOR TEXTILE MATERIALS

2020 ◽  
Vol 2020 (2) ◽  
pp. 64-69
Author(s):  
I Khaidarov ◽  
◽  
R Ismailov
Keyword(s):  
Mechanical Properties ◽  
Flame Retardant ◽  
Fire Resistance ◽  
Orthophosphoric Acid ◽  
Fire Retardant ◽  
Physical And Mechanical Properties ◽  
Textile Materials ◽  
Dispersed Particles ◽  
Expanded Vermiculite ◽  
Smoke Generation

This article presents studies of fire resistance in the treatment of expanded vermiculite, which depends on the size of the dispersed particles and the orientation of the granules, their moisture and temperature. It has been studied that one of the interesting and important in practice properties of vermiculite is its ability to swell and turn into a lightweight effective material for imparting fire resistance. The properties and compositions of vermiculite from the Tebinbulak deposit are studied, from which a flame-retardant suspension is prepared for processing textile materials based on vermiculite dissolved in orthophosphoric acid and alkali in an aqueous medium. When modifying materials with developed flame-retardant suspensions, it is possible to obtain fire-resistant textile materials that meet the requirements of GOST for fire resistance, smoke generation and other physical and mechanical properties.

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