scholarly journals Premium quality hydraulic oils

2021 ◽  
Author(s):  
Milan Kambič
Keyword(s):  
Crude Oil ◽  
American Petroleum Institute ◽  
Refining Process ◽  
Oil Refining ◽  
Base Oil ◽  
Hydraulic Oil ◽  
Base Oils

The base of the final product is the base oil. The final product is ready for use and is a mixture of base oil (or several base oils) and additives. Additives improve the properties of the base oil. Base oils can be mineral or synthetic based. Base oils or base stocks are created from separating and cleaning up crude oil. They are one of several liquid components that are created from crude oil. The crude oil refining process will be briefly described. The American Petroleum Institute implemented a system for describing various base oil types. The result was the development and introduction of base oils group numbers. The API numbers of various base oil groups and the main differences between them will be explained. At the end, premium quality hydraulic oil and its main characteristics will be presented.

Deacidification of Acidic Petroleum Crude Oil Utilizing a Formulated Basic Chemical

2015 ◽  
Vol 1107 ◽  
pp. 335-340 ◽  
Author(s):  
Nurasmat Mohd Shukri ◽  
Jafariah Jaafar ◽  
Wan Azelee Wan Abu Bakar ◽  
Zaiton Abdul Majid
Keyword(s):  
Polyethylene Glycol ◽  
Crude Oil ◽  
New Technology ◽  
Acid Number ◽  
Refining Process ◽  
Oil Refining ◽  
Petroleum Crude ◽  
Total Acid ◽  
Total Acid Number ◽  
Stirring Time

An increasing interest in acidic fractions in crude oil was prompted by the corrosion problems that these compounds caused during oil refining process. This corrosion is associated with the total acid number (TAN). With the anticipated growth of acidic crudes in the market, a new technology for removal of the acidic fractions was introduced. Petronas Penapisan Melaka Light Crude (B) with TAN values of 2.52 was studied. The ammoniated polyethylene glycol (PEG) was used as the deacidifying agent in this study with a concentration range of 100-2500 mg/L. Data indicated that the optimal content of ammoniated polyethylene glycol in crude B was 1500 mg/L, and PEG with molecular weight of 2000 was the most promising co-solvent with the reagent/oil ratio being 0.4:1 (wt/wt). A reaction time of 5 min with a suitable reaction temperature of 40°C and optimal stirring time of 5 min were sufficient to achieve the goal for crude oil B. The TAN was lowered to 0.28 for crude oil B. The percentage of acid removal for crude B was 78. An increase in the concentration of basic chemical reduced the TAN value for crude oil B to less than 1.

A Density-Method-Based Model for Allocating the Refining Cost of Gasoline and Diesel in China

2012 ◽  
Vol 524-527 ◽  
pp. 1773-1779
Author(s):  
Wei Qi Li ◽  
Lin Wei Ma ◽  
Feng Fu ◽  
Ya Ping Dai
Keyword(s):  
Crude Oil ◽  
Influencing Factor ◽  
Refining Process ◽  
Oil Price ◽  
Oil Refining ◽  
Crude Oil Price ◽  
Density Method ◽  
Refining Cost ◽  
The Cost ◽  
Operation Cost

In this paper, we present a density-method-based model to allocate the refining cost to petroleum products such as gasoline and diesel. By using this model, we also present an empirical study of China, which is based on a virtual crude oil refining process proposed referring to the technical configuration of oil refining industry in China. Three scenarios of the cost of gasoline and diesel are illustrated referring to different settings of the change of the international crude oil prices. The results indicate that the cost of gasoline and diesel change nearly the same amplitude as the change of crude oil price. However, the margin between the cost of gasoline and diesel will slightly increase with the rise of crude oil price. Besides, we also present a sensitivity analysis of the operation cost of each unit in the refining process. The results reveal that the operation cost of catalytic reforming is the most important influencing factor of the cost of gasoline, while the operation cost of hydrogen cracking influences the cost of diesel mostly.

scholarly journals RETROFITTING DESIGN OF HEAT EXCHANGER NETWORKS USING ASPEN-HYSYS: A CASE STUDY OF CRUDE OIL REFINING PROCESS

2021 ◽  
Vol 40 (1) ◽  
pp. 15-22
Author(s):  
Mohammed Hussein ◽  
Elzahid N.M ◽  
Ebrahim Esmail ◽  
Mamdouh Gadalla ◽  
Ibrahim Ashour
Keyword(s):  
Heat Exchanger ◽  
Crude Oil ◽  
Refining Process ◽  
Oil Refining ◽  
Aspen Hysys ◽  
Heat Exchanger Networks

Paraffin-based crude oil refining process unit-level energy consumption and CO2 emissions in China

2020 ◽  
Vol 255 ◽  
pp. 120347 ◽  
Author(s):  
Feng-Rui Jia ◽  
Wan-Ting Jing ◽  
Guang-Xin Liu ◽  
Qiang Yue ◽  
He-Ming Wang ◽  
...  
Keyword(s):  
Energy Consumption ◽  
Crude Oil ◽  
Co2 Emissions ◽  
Refining Process ◽  
Oil Refining ◽  
Level Energy ◽  
Process Unit ◽  
Unit Level

Study of the Effect of Crude Oils on the Metallic Corrosion

2018 ◽  
Vol 5 (1) ◽  
pp. 43-54
Author(s):  
Suresh Aluvihara ◽  
Jagath K Premachandra
Keyword(s):  
Crude Oil ◽  
Sulfur Content ◽  
Salt Content ◽  
Ferrous Metal ◽  
Relative Weight ◽  
Oil Refining ◽  
Crude Oils ◽  
Hardness Tester ◽  
Corrosion Rates ◽  
Ferrous Metals

Corrosion is a severe matter regarding the most of metal using industries such as the crude oil refining. The formation of the oxides, sulfides or hydroxides on the surface of metal due to the chemical reaction between metals and surrounding is the corrosion that  highly depended on the corrosive properties of crude oil as well as the chemical composition of ferrous metals since it was expected to investigate the effect of Murban and Das blend crude oils on the rate of corrosion of seven different ferrous metals which are used in the crude oil refining industry and investigate the change in hardness of metals. The sulfur content, acidity and salt content of each crude oil were determined. A series of similar pieces of seven different types of ferrous metals were immersed in each crude oil separately and their rates of corrosion were determined by using their relative weight loss after 15, 30 and 45 days. The corroded metal surfaces were observed under the microscope. The hardness of each metal piece was tested before the immersion in crude oil and after the corrosion with the aid of Vicker’s hardness tester. The metallic concentrations of each crude oil sample were tested using atomic absorption spectroscopy (AAS). The Das blend crude oil contained higher sulfur content and acidity than Murban crude oil. Carbon steel metal pieces showed the highest corrosion rates whereas the stainless steel metal pieces showed the least corrosion rates in both crude oils since that found significant Fe and Cu concentrations from some of crude oil samples. The mild steel and the Monel showed relatively intermediate corrosion rates compared to the other types of ferrous metal pieces in both crude oils. There was a slight decrease in the initial hardness of all the ferrous metal pieces due to corrosion.

scholarly journals Regeneration of Spent Lubricant Refining Clays by Solvent Extraction

2015 ◽  
Vol 2015 ◽  
pp. 1-7 ◽  
Author(s):  
Yan-zhen Wang ◽  
Hai-long Xu ◽  
Li Gao ◽  
Meng-meng Yan ◽  
Hong-ling Duan ◽  
...  
Keyword(s):  
Solvent Extraction ◽  
Petroleum Ether ◽  
Oil Recovery ◽  
Oil Refining ◽  
Lubricating Oil ◽  
Polar Solvents ◽  
Base Oil ◽  
Nonpolar Solvents ◽  
Total Oil ◽  
Storage Times

Step-by-step solvent extraction was used to regenerate spent clay by recovering the adsorbed oil in lubricating oil refining clay. Several polar and nonpolar solvents were tested, and petroleum ether (90–120°C) and ethanol (95 v%) were selected as the nonpolar and polar solvents, respectively. The spent clay was first extracted using petroleum ether (90–120°C) to obtain ideal oil and then extracted with a mixed solvent of petroleum ether (90–120°C) and ethanol (95 v%) two or three times to obtain nonideal oil before being extracted with ethanol and water. Finally, the clay was dried at 130°C to obtain regenerated clay. The total oil recovery can be more than 99 wt% of the adsorbed oil. The recovered ideal oil can be used as lubricating base oil. Shorter storage times for spent clay produce better regeneration results. The regenerated clay can be reused to refine the lubricating base oils.

Kinetic Study of the Thermo-Oxidative Degradation of Squalane (C30H62) Modelling the Base Oil of Engine Lubricants

2009 ◽  
Author(s):  
Moussa Diaby ◽  
Michel Sablier ◽  
Anthony Le Negrate ◽  
Mehdi El Fassi
Keyword(s):  
Oxidative Degradation ◽  
Engine Oil ◽  
Ongoing Research ◽  
Base Oil ◽  
Rate Law ◽  
Tert Butyl ◽  
Oxidation Rates ◽  
Base Oils ◽  
Wide Range ◽  
Thermo Oxidative Degradation

On the basis of ongoing research conducted on the clarification of processes responsible for lubricant degradation in the environment of piston grooves in EGR diesel engines, an experimental investigation was aimed to develop a kinetic model which can be used for the prediction of lubricant oxidative degradation correlated to endurance test conducted on engines. Knowing that base oils are a complex blend of paraffins and naphtenes with a wide range of sizes and structures, their chemistry analysis during the oxidation process can be highly convoluted. In the present work, investigations were carried out with the squalane (C30H62) chosen for its physical and chemical similarities with the lubricant base oils used during the investigations. Thermo-oxidative degradation of this hydrocarbon was conducted at atmospheric pressure in a tubular furnace, while varying temperature and duration of the tests in order to establish an oxidation reaction rate law. The same experimental procedures was applied to squalane doped with two different phenolic antioxidants usually present in engine oil composition: 2,6-di-tert-butyl-4-methylphenol (BHT), and octadecyl-3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate (OBHP). Thus, the effect of both antioxidants on the oxidation rate law was investigated. Data analysis of the oxidized samples (FTIR spectroscopy, gas chromatography/mass spectrometry GC/MS) allowed to rationalize the thermo-oxidative degradation of squalane. The resulting kinetic modelling provides a practical analytical tool to follow the thermal degradation processes, which can be used for prediction of base oil hydrocarbon ageing. If experiments confirmed the role of phenolic additives as an affective agent to lower oxidation rates, the main results lay in the observation of a threshold temperature where a reversed activity of these additives was observed.

scholarly journals Comparing Crude Oils with Different API Gravities on a Molecular Level Using Mass Spectrometric Analysis. Part 1: Whole Crude Oil

Energies ◽  
2018 ◽  
Vol 11 (10) ◽  
pp. 2766 ◽  
Author(s):  
Jandyson Santos ◽  
Alberto Wisniewski Jr. ◽  
Marcos Eberlin ◽  
Wolfgang Schrader
Keyword(s):  
Crude Oil ◽  
Atmospheric Pressure ◽  
Molecular Level ◽  
Carbon Number ◽  
Mass Spectrometric ◽  
Oil Refining ◽  
Crude Oils ◽  
Spectrometric Analysis ◽  
Ft Icr Ms ◽  
Ft Icr

Different ionization techniques based on different principles have been applied for the direct mass spectrometric (MS) analysis of crude oils providing composition profiles. Such profiles have been used to infer a number of crude oil properties. We have tested the ability of two major atmospheric pressure ionization techniques, electrospray ionization (ESI(±)) and atmospheric pressure photoionization (APPI(+)), in conjunction with Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS). The ultrahigh resolution and accuracy measurements of FT-ICR MS allow for the correlation of mass spectrometric (MS) data with crude oil American Petroleum Institute (API) gravities, which is a major quality parameter used to guide crude oil refining, and represents a value of the density of a crude oil. The double bond equivalent (DBE) distribution as a function of the classes of constituents, as well as the carbon numbers as measured by the carbon number distributions, were examined to correlate the API gravities of heavy, medium, and light crude oils with molecular FT-ICR MS data. An aromaticity tendency was found to directly correlate the FT-ICR MS data with API gravities, regardless of the ionization technique used. This means that an analysis on the molecular level can explain the differences between a heavy and a light crude oil on the basis of the aromaticity of the compounds in different classes. This tendency of FT-ICR MS with all three techniques, namely, ESI(+), ESI(−), and APPI(+), indicates that the molecular composition of the constituents of crude oils is directly associated with API gravity.

scholarly journals The Investigation of Viscometric Properties of the Most Reputable Types of Viscosity Index Improvers in Different Lubricant Base Oils: API Groups I, II, and III

Lubricants ◽  
2022 ◽  
Vol 10 (1) ◽  
pp. 6
Author(s):  
Seyed Ali Khalafvandi ◽  
Muhammad Ali Pazokian ◽  
Ehsan Fathollahi
Keyword(s):  
Viscosity Index ◽  
Behavioral Differences ◽  
Base Oil ◽  
Polymer Molecules ◽  
Base Oils ◽  
Two Temperatures ◽  
Higher Temperature ◽  
Viscosity Index Improvers ◽  
Lower Temperature ◽  
Definition Of

Four commercial viscosity index improvers (VII) have been used to investigate the behavioral differences of these compounds in three types of universally applicable base oils. The used VIIs are structurally three types of co-polymer: ethylene-propylene, star isoprene, and two di-block styrene-isoprene. After dissolving of different amounts of VIIs in different base oils, the kinematic viscosities at two standard temperatures were determined and the intrinsic viscosities were calculated according to Huggins method, then the effects of changes in base oil and polymer type were investigated. Intrinsic viscosities as criteria for polymer molecules sizes were found to be higher at lower temperature than at higher temperature. Dependence of intrinsic viscosity on the polymer molecular weight was observed. In the previous works, one or two types of VIIs were studied in only one type of base oil and/or solvent, not different base oils. Furthermore, different ranges of temperatures and concentrations not necessarily applied ranges were selected, but in this work, common base oils and most commercial VIIs were used and the viscometric properties were compared at two temperatures. Viscosities at these temperatures are used for determining VI and definition of lubricant’s viscosity grades. VI improvement is the main cause of VII usage.

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