Evaluation of Sources and Ecological Risk of PAHs in Different Layers of Soil and Groundwater

Author(s):  
Predrag Ilić ◽  
Dragana Nešković Markić ◽  
Ljiljana Stojanović Bjelić

Research subjects of this study are four representative locations in the industrial complex, in the city of Banja Luka, Republic of Srpska, Bosnia and Herzegovina. 16 polycyclic aromatic hydrocarbons (PAHs), humus and pH were determined. The main objective of the paper is to determine the concentration levels, to assess the probable sources of PAHs contamination in soil and groundwater and to determine the ecological risk. The ∑16PAHs in soil (at depths of 30 cm, 100 cm, 200 cm, 300 cm and 400 cm) ranged from 0.99 to 2.24 mg/kg, from 0.34 to 0.46, from 0.24 to 0.32, from 0.13 to 0.27 and from 0.13 to 0.47, with mean values of 1.70 mg/kg, 0.40 mg/kg, 0.28 mg/kg, 0.20 mg/kg and 0.26 mg/kg, respectively. The ∑16PAHs in groundwater ranged from 0.23 to 4.50 mg/m3, with mean value of 1.42 mg/m3. Surface soil and groundwater are heavily contaminated. All values of ∑PAHs in soil layers were lower in the depths of the soil. Factor analysis indicates three sources of contamination, RC1 (pyrogenic), RC2 (petrogenic) and RC3 (biomass), with 52.39%, 26.14% and 8.46% of total variance, respectively. ∑PAH and PAHs indicate high ecological risk for most PAHs, which decreases with soil depth.

Author(s):  
Predrag Ilić ◽  
Dragana Nešković Markić ◽  
Ljiljana Stojanović Bjelić

Research subjects of this study are four representative locations in the industrial complex, in the city of Banja Luka, Republic of Srpska, Bosnia and Herzegovina. 16 polycyclic aromatic hydrocarbons (PAHs) (∑16PAHs), humus and pH were determined. The main objective of the paper is to determine the concentration levels, to assess the probable sources of PAHs contamination in soil and groundwater and to determine the ecological risk. The ∑16PAHs in soil (at depths of 30 cm, 100 cm, 200 cm, 300 cm and 400 cm) ranged from 0.99 to 2.24 mg/kg, from 0.34 to 0.46, from 0.24 to 0.32, from 0.13 to 0.27 and from 0.13 to 0.47, with mean values of 1.70 mg/kg, 0.40 mg/kg, 0.28 mg/kg, 0.20 mg/kg and 0.26 mg/kg, respectively. The ∑16PAHs in groundwater ranged from 0.23 to 4.50 mg/m3, with a mean value of 1.42 mg/m3. Surface soil and groundwater are heavily contaminated. All values of ∑PAHs in soil layers were lower in the depths of the soil. Factor analysis indicates three sources of contamination, i.e. principal component (PC) PC1 (pyrogenic), PC2 (petrogenic) and PC3 (biomass), with 52.39%, 26.14% and 8.46% of the total variance, respectively. ∑PAH and PAHs indicate high ecological risk for most PAHs, which decreases with soil depth.


2021 ◽  
Vol 28 (3) ◽  
pp. 355-363
Author(s):  
Predrag Ilić ◽  
Svetlana Ilić ◽  
Dragana Nešković Markić ◽  
Ljiljana Stojanović Bjelić ◽  
Zia Ur Rahman Farooqi ◽  
...  

Abstract Polycyclic aromatic hydrocarbons (PAHs) are formed from anthropogenic activities, i.e. industrial emissions, incomplete combustion of petroleum, coal and other fossil fuels and other industrial and domestic activities. Research areas of this study are four representative locations in the industrial complex, in the city of Banja Luka, Republic of Srpska, Bosnia and Herzegovina. The main objective of the paper is to determine the ecological risk and to assess probable sources of PAHs contamination in soil and groundwater. The results of this study reflect the effects of coal combustion (pyrogenic origin), petrogenic and biomass origin and may provide basic data for the remediation of PAHs in the location. The ecological risk in soil (at depths of 30, 100, 200, 300 and 400 cm) and groundwater is determined. The mean values of ecological risk in soil and groundwater decreased with soil depth. Values of RQ(NCs) for groundwater were found at high ecological risk, for Ant, Chr, DahA, Acy, Pyr, BaA, Phe, Flo, Nap, Ace and Fluo, with values 28.57, 20.59, 300.00, 242.86, 185.71, 1700.0, 76.67, 53.33, 15.83, 100.00 and 57.14, respectively. ∑16PAH indicated high ecological risk for most PAHs, which decreased with soil depth. The value of RQ(NCs) for ΣPAHs in groundwater indicates high ecological risk (ΣPAHs ≥ 800 and RQ(MPCs) ≥ 1). This is the first study on the ecological risk of PAHs in soil and groundwater in industrial soils in Banja Luka and provides baseline information for further studies and additional investigations of this industrial complex.


2009 ◽  
Vol 36 (1) ◽  
pp. 11 ◽  
Author(s):  
Dirk Gaul ◽  
Dietrich Hertel ◽  
Christoph Leuschner

The importance of root systems for C cycling depends crucially on fine root longevity. We investigated mean values for fine root longevity with root diameter, root C/N ratio and soil depth using radiocarbon (14C) analyses in a temperate Norway spruce [Picea abies (L.) Karst.] forest. In addition, we applied sequential soil coring and minirhizotron observations to estimate fine root longevity in the organic layer of the same stand. The mean radiocarbon age of C in fine roots increased with depth from 5 years in the organic layer to 13 years in 40–60 cm mineral soil depth. Similarly, the C/N ratios of fine root samples were lowest in the organic layer with a mean value of 24 and increased with soil depth. Roots >0.5 mm in diameter tended to live longer than those being <0.5 mm in diameter. By far the strongest variability in fine root longevity estimates was due to the chosen method of investigation, with radiocarbon analyses yielding much higher estimates (5.4 years) than sequential soil coring (0.9 years) and minirhizotron observations (0.7 years). We conclude that sequential soil coring and minirhizotron observations are likely to underestimate mean fine root longevity, and radiocarbon analyses may lead to an overestimation of mean root longevity.


Author(s):  
Sara Lambiase ◽  
Andrea Ariano ◽  
Francesco Paolo Serpe ◽  
Marcello Scivicco ◽  
Salvatore Velotto ◽  
...  

AbstractThis study assesses the PAH and heavy metal levels in muscle of warty crabs (Eriphia verrucosa), from the northern coast of the Campania region improving the data on toxic contaminants in this crustacean. The results showed a minimal PAH contamination; the mean concentrations were as follows: 0.2, 1.6 and 1.7 μg kg-1 wet weight (ww) for BaP, PAH4 and PAH6, respectively. Regarding the levels of the two PAHs not included in the European regulations, the BkF mean concentration was 0.1 μg kg-1 ww, while DahA was detected only in 10.7% of samples. Pb and Cr were also detected at low levels with mean values of 0.068 and 0.468 mg kg-1 ww, respectively; instead, high As levels, with a mean value of 5.021 mg kg-1 ww, were found. Considering the EWIs and the ILCRs calculated in this study, the PAH, Pb and Cr contamination levels found in the edible part of the crabs resulted safe for human consumption. Contrariwise, the ILCR calculated for the As exceeded the acceptable level of cancer risk, although the calculation did not refer to the inorganic form which is the only one recognized as carcinogenic. Hence, this study shows that warty crabs can accumulate environmental contaminants in their muscle tissue representing an important route of exposure to these toxics for the local population that regularly consumes them. This finding highlights the importance of monitoring the presence of these pollutants in crabs and in general in all fish and seafood in order to ensure food safety for consumers.


2019 ◽  
pp. 549-556

The aim of the study was to evaluate the results of the preventive and therapeutic programme addressed to adolescents aged 17 and 18, based on a comparison of the state of dentition prior to and after the completion of the programme. MATERIAL AND METHODS: All 44 adolescents from the City of Skierniewice and the surrounding area who applied for enrolment were included in the programme. Based on clinical examination, the prevalence of active caries, caries intensity expressed by mean values of the DMFT (decayed, missing, filled teeth) Index including D, M, and F components and the Dental Treatment (DT) Index F/(D + F) were assessed. All parameters were presented according to sex. RESULTS: Active caries was observed in 34 (77.3%) patients. Caries was more frequently detected in boys (82.6%) than in girls (71.4%). The value of the Caries Intensity Index, DMF, equalled 12.05 and was significantly higher (p<0.01) in boys than in girls: 13.73 ± 3.63 and 10.06 ± 3.42. In the examined group of 17- and 18-year-olds, the mean number of decayed teeth D (6.31) had the highest mean value, followed by the mean number of filled teeth F (4.26), the mean number of extracted (missing) teeth M (1.48) being the lowest. The values of the F Index were statistically significantly higher (t=2.570; p=0.0195) in boys as compared to girls (5.26 ± 2.69 vs. 3.13 ± 2.83). Mean value the Dental Treatment (DT) Index (F/D+F) appeared to be higher in the group of boys than in girls: 0.431 ± 0.182 and 0.358 ± 0.126, respectively. After the completion of the programme, all adolescents studied achieved the value of the Dental Treatment Index equalling 1. CONCLUSIONS: Dental examination qualifying 17- and 18-year old adolescents in Skierniewice to the preventive and therapeutic programme detected numerous foci of active caries. Implementation of the programme allowed to effectively treat the teeth of the adolescents participating in the project and to develop proper hygiene and dietary habits.


2004 ◽  
Vol 35 (2) ◽  
pp. 119-137 ◽  
Author(s):  
S.D. Gurney ◽  
D.S.L. Lawrence

Seasonal variations in the stable isotopic composition of snow and meltwater were investigated in a sub-arctic, mountainous, but non-glacial, catchment at Okstindan in northern Norway based on analyses of δ18O and δD. Samples were collected during four field periods (August 1998; April 1999; June 1999 and August 1999) at three sites lying on an altitudinal transect (740–970 m a.s.l.). Snowpack data display an increase in the mean values of δ18O (increasing from a mean value of −13.51 to −11.49‰ between April and August), as well as a decrease in variability through the melt period. Comparison with a regional meteoric water line indicates that the slope of the δ18O–δD line for the snowpacks decreases over the same period, dropping from 7.49 to approximately 6.2.This change points to the role of evaporation in snowpack ablation and is confirmed by the vertical profile of deuterium excess. Snowpack seepage data, although limited, also suggest reduced values of δD, as might be associated with local evaporation during meltwater generation. In general, meltwaters were depleted in δ18O relative to the source snowpack at the peak of the melt (June), but later in the year (August) the difference between the two was not statistically significant. The diurnal pattern of isotopic composition indicates that the most depleted meltwaters coincide with the peak in temperature and, hence, meltwater production.


Noise Mapping ◽  
2020 ◽  
Vol 7 (1) ◽  
pp. 239-247
Author(s):  
Alberto E. García-Rivero ◽  
Ricardo Ángel Yuli-Posadas ◽  
Warren Reátegui Romero ◽  
Odón Sánchez-Ccoyllo ◽  
Wilfredo Bulege-Gutierrez ◽  
...  

AbstractThe present study is intended to get to know the levels of perimeter diurnal environmental noise of four hospitals in the city of Lima. The measurement mode used at each hospital was A-weighting, with an integration time of five minutes per recording. It was measured in the FAST mode with calibrations made at the beginning and end of the measurement day. Statistical analysis consisted of the mean comparison T test which was applied at all the hospitals considered in the study. At the four hospitals, at all the hours of measurement and both on working days and non-working days (Sunday), LAeq mean values are higher than 83 dBA. On working days, two periods of maximum noise from 08:00 to 10:00 in the morning and from 17:00 to 19:00 in the afternoon coincide with the start and end of working hours. The perimeter diurnal environmental noise levels determined at the vicinity of four hospitals show higher values in all cases to those established by the Peruvian National Environmental Standards for Noise for special protection areas both for working days and for non-working days. Noise that comes from the dense and disorganized traffic of Lima plays a fundamental role in this behaviour.


Author(s):  
Yuko Komuro ◽  
Yuji Ohta

Conventionally, the strength of toe plantar flexion (STPF) is measured in a seated position, in which not only the target toe joints but also the knee and particularly ankle joints, are usually restrained. We have developed an approach for the measurement of STPF which does not involve restraint and considers the interactions of adjacent joints of the lower extremities. This study aimed to evaluate this new approach and comparing with the seated approach. A thin, light-weight, rigid plate was attached to the sole of the foot in order to immobilize the toe area. Participants were 13 healthy young women (mean age: 24 ± 4 years). For measurement of STPF with the new approach, participants were instructed to stand, raise the device-wearing leg slightly, plantar flex the ankle, and push the sensor sheet with the toes to exert STPF. The sensor sheet of the F-scan II system was inserted between the foot sole and the plate. For measurement with the seated approach, participants were instructed to sit and push the sensor with the toes. They were required to maintain the hip, knee, and ankle joints at 90°. The mean values of maximum STPF of the 13 participants obtained with each approach were compared. There was no significant difference in mean value of maximum STPF when the two approaches were compared (new: 59 ± 23 N, seated: 47 ± 33 N). The coefficient of variation of maximum STPF was smaller for data obtained with the new approach (new: 39%, seated: 70%). Our simple approach enables measurement of STPF without the need for the restraints that are required for the conventional seated approach. These results suggest that the new approach is a valid method for measurement of STPF.


Diagnostics ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 816
Author(s):  
Kuei-Yuan Hou ◽  
Hao-Yuan Lu ◽  
Ching-Ching Yang

This study aimed to facilitate pseudo-CT synthesis from MRI by normalizing MRI intensity of the same tissue type to a similar intensity level. MRI intensity normalization was conducted through dividing MRI by a shading map, which is a smoothed ratio image between MRI and a three-intensity mask. Regarding pseudo-CT synthesis from MRI, a conversion model based on a three-layer convolutional neural network was trained and validated. Before MRI intensity normalization, the mean value ± standard deviation of fat tissue in 0.35 T chest MRI was 297 ± 73 (coefficient of variation (CV) = 24.58%), which was 533 ± 91 (CV = 17.07%) in 1.5 T abdominal MRI. The corresponding results were 149 ± 32 (CV = 21.48%) and 148 ± 28 (CV = 18.92%) after intensity normalization. With regards to pseudo-CT synthesis from MRI, the differences in mean values between pseudo-CT and real CT were 3, 15, and 12 HU for soft tissue, fat, and lung/air in 0.35 T chest imaging, respectively, while the corresponding results were 3, 14, and 15 HU in 1.5 T abdominal imaging. Overall, the proposed workflow is reliable in pseudo-CT synthesis from MRI and is more practicable in clinical routine practice compared with deep learning methods, which demand a high level of resources for building a conversion model.


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