The tholeiites of the Valaisan domain (Versoyen, western Alps): a Carboniferous magma emplaced in a small oceanic basin

Abstract The mafic-ultramafic assemblages of the Versoyen complex exposed in the Valaisan domain is close to the boundary between the Internal and the External domains of the western Alps. Zircons extracted from the Versoyen complex suggest an emplacement during Paleozoic times, and probably during the Visean (~337 Ma). The base of the Versoyen complex is formed of laccoliths and sills associated with black shales, while pillow basalts and tuffs predominate at the uppermost levels. Locally, basaltic dikelets intruded leucocratic gneiss. Ultramafic-mafic cumulates form the bottom of the thickest intrusions while diabases are present along the chilled margins. All these rocks have been affected by a polyphased metamorphism under eclogitic to blueschist and greenschist facies conditions. Magmatic textures have been destroyed and the igneous mineralogy is seldom preserved. The mafic rocks of the Versoyen complex show tholeiitic to alkali-transitional affinities. The pillow basalts and the sill cores have flat REE patterns characteristic of N-MORB and T-MORB. Their εNd (assuming an age of 337 Ma) ratios range from + 5.7 to + 9 which suggest a mixing of N-MORB and OIB sources. The sill margins show Th, U and LREE-enrichments and negative εNd ratios. These features are likely related to contamination when hot mafic magmas intruded unconsolidated sediments rich in water. The high Th, U, LREE abundances and low εNd ratio of the basaltic dikelet are probably related to crustal contamination occurring during magma ascent. The geochemical characteristics of the Versoyen rocks are compatible with a tholeiitic magma emplaced into a small oceanic basin in the vicinity of a continent. The importance of pre-Mesozoic crustal thinning evidenced in one segment of the boundary between the Internal and External zones of the Alps suggests that the Pennine Front is an Alpine mega-thrust inherited from a Variscan suture.

Download Full-text

Synconvergent and coherent (ultra)high-pressure crustal rock exhumation

10.5194/egusphere-egu21-11119 ◽

2021 ◽

Author(s):

Lorenzo G. Candioti ◽

Joshua D. Vaughan-Hammon ◽

Thibault Duretz ◽

Stefan M. Schmalholz

Keyword(s):

Numerical Models ◽

A Priori ◽

Western Alps ◽

Ultrahigh Pressure ◽

Plate Motion ◽

Crustal Rock ◽

Plate Boundaries ◽

Crustal Rocks ◽

Natural Data ◽

The Alps

Ultrahigh-pressure (UHP) continental crustal rocks were first discovered in the Western Alps in 1984 and have since then been observed at many convergent plate boundaries worldwide. Unveiling the processes leading to the formation and exhumation of (U)HP metamorphic crustal rocks is key to understand the geodynamic evolution of orogens such as the Alps.&#160;Previous numerical studies investigating (U)HP rock exhumation in the Alps predicted deep (>80 km) subduction of crustal rocks and rapid buoyancy-driven exhumation of mainly incoherent (U)HP units, involving significant tectonic mixing forming so-called m&#233;langes. Furthermore, these predictions often rely on excessive erosion or periods of divergent plate motion as important exhumation mechanism. Inconsistent with field observations and natural data, application of these models to the Western Alps was recently criticised.&#160;Here, we present models with continuous plate convergence, which exhibit local tectonic-driven upper plate extension enabling compressive- and buoyancy-driven exhumation of coherent (U)HP units along the subduction interface, involving feasible erosion.&#160;The two-dimensional petrological-thermo-mechanical numerical models presented here predict both subduction initiation and serpentinite channel formation without any a priori prescription of these two features. The (U)HP units are exhumed coherently, without significant internal deformation. Modelled pressure and temperature trajectories and exhumation velocities of selected crustal units agree with estimates for the Western Alps. The presented models support previous hypotheses of synconvergent exhumation, but do not rely on excessive erosion or divergent plate motion. Thus, our predictions provide new insights into processes leading to the exhumation of coherent (U)HP crustal units consistent with observations and natural data from the Western Alps.

Download Full-text

Geochemical Characteristics and Tectonic Setting of Amphibolites in Ifewara Area, Ife-Ilesha Schist Belt, Southwestern Nigeria

Earth Science Research ◽

10.5539/esr.v6n1p43 ◽

2016 ◽

Vol 6 (1) ◽

pp. 43 ◽

Cited By ~ 1

Author(s):

Anthony Temidayo Bolarinwa ◽

Adebimpe Atinuke Adepoju

Keyword(s):

Rare Earth ◽

Rare Earth Elements ◽

Major Element ◽

Tectonic Setting ◽

Crustal Contamination ◽

Geochemical Evolution ◽

Schist Belt ◽

Southwestern Nigeria ◽

Eu Anomaly ◽

Ree Patterns

Trace and Rare Earth Elements (REEs) data are used to constrain the geochemical evolution of the amphibolites from Ifewara in the Ife-Ilesha schist belt of southwestern Nigeria. The amphibolites can be grouped into banded and sheared amphibolites. Major element data show SiO2 (48.34%), Fe2O3 (11.03-17.88%), MgO (5.76-9.90%), CaO (7.76-18.6%) and TiO2 (0.44-1.77%) contents which are similar to amphibolites in other schist belts in Nigeria. The Al2O3 (2.85-15.55%) content is varied, with the higher values suggesting alkali basalt protolith. Trace and rare earth elements composition reveal Sr (160-1077ppm), Rb (0.5-22.9ppm), Ni (4.7-10.2ppm), Co (12.2-50.9 ppm) and Cr (2-7ppm). Chondrite-normalized REE patterns show that the banded amphibolites have HREE depletion and both negative and positive Eu anomalies while the sheared variety showed slight LREE enrichment with no apparent Eu anomaly. The study amphibolites plot in the Mid Oceanic Ridge Basalts (MORB) and within plate basalt fields on the Zr/Y vs Zr discriminatory diagrams. They are further classified as volcanic arc basalt and E-type MORB on the Th- Hf/3- Ta and the Zr-Nb-Y diagrams. The amphibolites precursor is considered a tholeiitic suite that suffered crustal contamination, during emplacement in a rifted crust.

Download Full-text

Rare earth element concentrations in Quaternary volcanic rocks of southwestern British Columbia

Canadian Journal of Earth Sciences ◽

10.1139/e84-079 ◽

1984 ◽

Vol 21 (6) ◽

pp. 731-736 ◽

Cited By ~ 4

Author(s):

Nathan L. Green ◽

Paul Henderson

Keyword(s):

British Columbia ◽

Earth Element ◽

Volcanic Rocks ◽

Crustal Contamination ◽

Lake Area ◽

Calc Alkaline ◽

Lower Light ◽

The Individual ◽

High Level ◽

Ree Patterns

A suite of hy-normative hawaiites, ne-normative mugearite, and calc-alkaline andesitic rocks from the Garibaldi Lake area exhibits fractionated, slightly concave-upward REE patterns (CeN/YbN = 4.5–15), heavy REE contents about 5–10 times the chondritic abundances, and no Eu anomalies. It is unlikely that the REE patterns provide information concerning partial melting conditions beneath southwestern British Columbia because they have probably been modified substantially by upper crustal processes including crustal contamination and (or) crystal fractionation. The REE contents of the Garibaldi Lake lavas are not incompatible with previous interpretations that (1) the hawaiites have undergone considerable fractionation of olivine, plagioclase, and clinopyroxene; and (2) the individual andesitic suites were derived from separate batches of chemically distinct magma that evolved along different high-level crystallization trends. In general, however, the andesites are characterized by lower light REE contents than the basaltic andesites. These differences in LREE abundances may reflect different amounts of LREE-rich accessory phases, such as apatite, sphene, or allanite, assimilated from the underlying quartz diorites.

Download Full-text

Genesis of porphyry and plutonic mineralisation systems in metaluminous granitoids of the Grampian Terrane, Scotland

Transactions of the Royal Society of Edinburgh Earth Sciences ◽

10.1017/s0263593300003618 ◽

1994 ◽

Vol 85 (3) ◽

pp. 221-237 ◽

Cited By ~ 5

Author(s):

David Lowry ◽

Adrian J. Boyce ◽

Anthony E. Fallick ◽

W. Edryd Stephens

Keyword(s):

Source Region ◽

Crustal Contamination ◽

Magma Ascent ◽

Magmatic Fluid ◽

Magmatic System ◽

Low Salinity ◽

Deep Faults ◽

Supergene Enrichment ◽

Propylitic Alteration ◽

O 10

AbstractMineralisation associated with Late Caledonian metaluminous granitoids in the Grampian Terrane has been investigated using stable isotope, fluid inclusion and mineralogical techniques.A porphyry-stock-related style of mineralisation in the Grampian Terrane is characterised by a stockwork of veinlets and disseminations in dacite prophyries, consisting of quartz, dolomite, sulphides and late calcite, and well-developed wallrock alteration dominated by zones of phyllic, sericitic and propylitic alteration. On the basis of δ34S (+0·4±l·0‰), δ13C (−5·7‰ to + l·4‰) and δ18O (+10·8‰ to +19·9‰) it is likely that initial mineralising components were orthomagmatic with an input of external fluids during the later parageneses. Fluids were saline, boiling (up to 560°C), deficient in CO2, and ore deposition took place at depths of less than 3 km.Plutonic-hosted mineralisation in appinites, diorites, tonalites and monzogranites is commonly represented by sporadic disseminations and occasional veins consisting of quartz, calcite and sulphides. Wallrock alteration is generally propylitic with phyllic vein selvages. Deposition from a cooling magma sourced fluid is indicated by δ34S (+2·6±l·5‰), δ13C (−7·2‰ to −4·5‰) and δ18O (+9·5‰ to + ll·8‰) data. Fluids were CO2-rich and of low salinity; inclusions were trapped below ≈460°C, and formed at estimated depths of 3–5 km.Differences between these styles of mineralisation may due to multiple factors, the most important being the nature of the fluid: porphyry systems are dominated by greater volumes and much higher temperatures of hydrothermal fluids. Other controlling factors are likely to be the compositional characteristics of the melt source region, the mechanism of magma ascent, the level of emplacement, and the nature of the host metasediments. Variations in δ34S between the two groups are related, for the most part, to redox processes during magma and fluid genesis and not by crustal contamination.Nolarge porphyry-related mineral deposits have been found in the Grampian Terrane, unlike those in Mesozoic and Tertiary continental margin environments. This is largely due to a combination of detrimental factors which massively reducesthe probability of economic mineralisation. These include the already metamorphosed nature of the host Dalradian, the absence of seawater (which entered many subduction-related magmatic systems), a poorly-developed system of deep faults (most deposits too deep to be influenced by surface-derived fluids), and the absence of supergene enrichment. The main processes which aid the concentration of mineralisation involve encroachment of external fluids (formation, meteoric and seawaters) into the magmatic system, but these fluids were largely absent from the Grampian host block at the time of granitoid intrusion.The results of this study can be used in characterising the sources of fluids in sedimentary-hosted ore veins known (or considered) to be underlain by metaluminous granitoid batholiths, particularly in estimating the degree of magmatic fluid inputs into the vein systems: an example where this interaction has occurred (the Tyndrum Fault Zone) is discussed.

Download Full-text

Petrology, mineral chemistry, and geochemistry of Late Triassic Ni–Cu ore-bearing mafic–ultramafic intrusions, Hongqiling, northeastern China: petrogenesis and tectonic implications

Canadian Journal of Earth Sciences ◽

10.1139/cjes-2018-0014 ◽

2019 ◽

Vol 56 (2) ◽

pp. 111-128

Author(s):

Ai Li ◽

Jian Wang ◽

Yue Song

Keyword(s):

Crustal Contamination ◽

Parental Magma ◽

Mineral Chemistry ◽

Late Triassic ◽

Sulfide Deposit ◽

Chemical Compositions ◽

Tholeiitic Magma ◽

Average Value ◽

Central Asian ◽

History Of

The Hongqiling magmatic Ni–Cu sulfide deposit, situated on the southern margin of the eastern Central Asian Orogenic Belt (CAOB), is composed of over 30 mafic–ultramafic intrusions. These ore-bearing intrusions are composed mainly of harzburgite, lherzolite, websterite, orthopyroxenite, and norite (gabbro). The constituent minerals are olivine, diopside, bronzite, calcic-hornblende, plagioclase, and spinel with orthopyroxene as a dominant mineral in these intrusions. These ore-bearing intrusions are not Alaskan-type complexes. Spinel and clinopyroxene both exhibit different chemical compositions from those in the Alaskan-type complexes. The rocks that make up the intrusions have high contents of MgO (average value = 25.20 wt.%) and low TiO2 (average value = 0.58 wt.%). The high MgO contents of the minerals and the high Mg# (71) of the calculated melt in equilibrium with olivine demonstrate that the parental magma of the Hongqiling mafic–ultramafic intrusions was a high-Mg tholeiitic magma. The Hongqiling ore-bearing mafic–ultramafic intrusions and the calculated “trapped liquids” for the olivine-orthopyroxene cumulate rocks are all enriched in large-ion lithophile elements and depleted in high field strength elements. The Ce/Pb, Ta/La, Th/Yb, and (La/Sm)PM values and the depletion of Nb and Ta suggest that the magma experienced crustal contamination. The Hongqiling ore-bearing intrusions display many similarities with mafic–ultramafic intrusions that formed in a post-collisional extensional environment in the western CAOB (e.g., Huangshanxi). Common features include their whole-rock compositions and mineral chemistry. Combined with the evolutionary history of the eastern segment of the CAOB, we believe that the Late Triassic Hongqiling mafic–ultramafic intrusions formed in a post-collisional extensional environment.

Download Full-text

Mafic and ultramafic amphibolites from the northwestern Pontiac Subprovince: chemical characterization and implications for tectonic setting

Canadian Journal of Earth Sciences ◽

10.1139/e93-094 ◽

1993 ◽

Vol 30 (6) ◽

pp. 1110-1122 ◽

Cited By ~ 14

Author(s):

G. E. Camiré ◽

J. N. Ludden ◽

M. R. La Flèche ◽

J. -P. Burg

Keyword(s):

Magma Mixing ◽

Tectonic Setting ◽

Crustal Contamination ◽

Chemical Characterization ◽

Mantle Metasomatism ◽

Primitive Mantle ◽

Mafic Dykes ◽

Metavolcanic Rocks ◽

Source Mantle ◽

Ree Patterns

In the northwestern Pontiac Subprovince, metavolcanic rocks are exposed within a metagraywacke sequence that is intruded by metamorphosed mafic dykes. The metavolcanics are Al-undepleted komatiites ([La/Sm]N = 0.3, [Tb/Yb]N = 0.9) and tholeiitic Fe-basalts ([La/Sm]N = 0.8 and [Tb/Yb]N = 0.8). The nearly flat chondrite-normalized distributions of high field strength elements (HFSE), Ti and P, the constant Zr/Y, Nb/Th, Ti/Zr, and Ti/P ratios, and the lack of depletion of HFSE relative to rare-earth elements (REE) in both ultramafic and mafic metavolcanics, imply that crustal assimilation and magma mixing with crustal melts were not significant during differentiation and argue against the presence of subduction-related magmatic components. Contemporaneous volcanism and sedimentation in the northwestern Pontiac Subprovince are unlikely. The metavolcanics do not show any evidence of crustal contamination and likely represent a structurally emplaced, disrupted assemblage, chemically similar to early volcanics of the adjacent southern Abitibi Subprovince.Metamorphosed mafic dykes intruding the metagraywackes are not genetically related to the metavolcanics. The dykes have high CaO, P2O5, K2O, Ba, Rb, and Sr, intermediate Cr and Ni contents, and strongly fractionated REE patterns ([La/Yb]N = 10.8). Normalized to the primitive mantle, they display pronounced negative Nb, Ta, Ti, Zr, and Hf anomalies. These amphibolites are metamorphosed equivalents of Mg-rich calc-alkaline lamprophyre dykes, most likely derived from a hybridized mantle source. Mantle metasomatism was probably related to a subduction event prior to the peak of compressional Kenoran deformation in the Pontiac Subprovince.

Download Full-text

Striking differences in lithospheric structure between the north- and south-western Alps: insights from receiver functions along the Cifalps profiles and a new Vs model

10.5194/egusphere-egu21-9391 ◽

2021 ◽

Author(s):

Anne Paul ◽

Ahmed Nouibat ◽

Liang Zhao ◽

Stefano Solarino ◽

Stéphane Schwartz ◽

...

Keyword(s):

Receiver Function ◽

Negative Polarity ◽

Western Alps ◽

Lithospheric Structure ◽

Seismic Stations ◽

Continental Subduction ◽

The North ◽

Ligurian Alps ◽

The Alps ◽

Converted Waves

The CIFALPS receiver-function (RF) profile in the southwestern Alps provided the first seismological evidence of continental subduction in the Alps, with the detection of waves converted on the European Moho at 75-80 km depth beneath the western edge of the Po basin (Zhao et al., 2015). To complement the CIFALPS profile and enhance our knowledge of the lithospheric structure of the Western Alps, we installed CIFALPS2, a temporary network of 55 broadband seismic stations that operated for ~14 months (2018-2019) across the North-Western Alps (Zhao et al., 2018). The CIFALPS2 line runs from the Eastern Massif Central to the Ligurian coast, across the Mont-Blanc and Gran Paradiso massifs and the Ligurian Alps. Seismic stations were installed along a quasi-linear profile with a spacing of 7-10 km.We will show 2 receiver-function CCP (common-conversion point) depth-migrated sections along the CIFALPS2 profile, the first one across the Alps, and the second one across the Ligurian Alps and the Po basin. The time-to-depth migration of RF data is based on the new 3-D Vs model of the Greater Alpine region derived by Nouibat et al. (2021) using transdimensional ambient noise tomography on a large dataset including the AlpArray seismic network. Depth sections across the Vs model are also useful for interpreting the RF CCP sections as they have striking similarities.The images of the lithospheric structure of the NW Alps along CIFALPS2 are surprisingly different from those of the SW Alps along CIFALPS. The deepest P-to-S converted phases on the European Moho are detected at 60-65 km depth beneath the Ivrea-Verbano zone, that is 15 km less than on CIFALPS. The negative polarity converted phase interpreted as the base of the Ivrea body mantle flake on the CIFALPS section is still visible on CIFALPS2, but with a lower amplitude. The RF section confirms the existence of a jump of the European Moho of ~10 km amplitude in less than 10 km distance, which is located within a few km from the western boundary of the Mont Blanc external crystalline massif. All these observations are confirmed by the Vs model that also displays a less deep continental subduction than on CIFALPS, weaker S-wave velocities in the Ivrea body wedge, and the jump of the European Moho.The Moho beneath the Ligurian Alps is detected at 25-30 km depth both on the RF and on the Vs depth sections. Moving northwards, this Ligurian Moho is separated from the Adriatic Moho by a puzzling S-dipping set of P-to-S converted waves with negative polarity. The crust of the Ligurian Alps is characterized by a set of north-dipping negative-polarity converted waves at 10 to 20 km depth beneath the Valosio massif, which is a small internal crystalline massif of (U)HP metamorphic rocks located north of Voltri. The similarity of this set of negative-polarity conversions to the one observed beneath the Dora Maira massif on the CIFALPS profile suggests that it may be a relic of the Alpine structure overprinted by the opening of the Ligurian sea.

Download Full-text

The arc of the Western Alps : understanding its kinematics and formation mechanisms based on new structural and paleomagnetic datas, and thermo-mechanical modelling.

10.5194/egusphere-egu21-16529 ◽

2021 ◽

Author(s):

Quentin Brunsmann ◽

Claudio Rosenberg ◽

Nicolas Bellahsen ◽

Laetitia Le Pourhiet

Keyword(s):

Western Alps ◽

Strike Slip ◽

Rheological Parameters ◽

The South ◽

Adriatic Plate ◽

The North ◽

Field Evidence ◽

Internal Zone ◽

The Alps ◽

East West

The Alps have an overall East-West orientation, which changes radically in their western termination, where they rotate southward into a N-S strike, and then eastward into an E-W strike, forming the arc of the Western Alps. This arc is commonly inferred to have formed during collision, due to indentation of the Adriatic plate into the European continental margin. Several models attempted to provide a kinematic explanation for the formation of this arched, lateral end of the Alps. Indeed, the radial nature of the transport directions observed along the arc of the Western Alps cannot be explained by a classic convergence model. For more than 50 years the formation of this arc was been associated to westward-directed indentation of Adria, accommodated along East-West oriented strike-slip faults, a sinistral one in the South of the arc and a dextral one in the North. The dextral one correspond to the Insubric Fault. The sinistral strike-slip zone, inferred to be localized along the &#171;Stura corridor&#187; (Piedmont, Italy) would correspond to a displacement of 100 to 150 km according to palaeogeographical, and geometric analyses. However, field evidence is scarce and barely documented in the literature. Vertical axis rotations of the Adriatic indenter also inferred to be syn-collisional could have influenced the acquisition of the morphology of the arc. Paleomagnetic analyses carried out in the Internal Zone and in the Po plain suggest a southward increading amount of counter-clockwise rotation of the Adriatic plate and the Internal Zone, varying from 20&#176;-25&#176; in the North to nearly 120&#176; in the South. Dextral shear zones possibly accommodating this rotation in some conceptual models is observed in several places below the Penninic Front and affect the Argentera massif to the south. However, the measured displacement quantities do not appear to be equivalent to those induced by such rotations. The present study aims to constrain the kinematic evolution of the arc of the Western Alps through a multidisciplinary approach. The first aspect of this project is the structural analysis of the area (Stura corridor) inferred to accommodate large sinistral displacements allowing for the westward indentation of the Adriatic indenter. We discuss the general lack of field evidence supporting sinistral strike-slip movements, in contrast to large-scale compilation of structures suggesting the possible occurrence of such displacement. The second part consists of a palaeomagnetic study, in which new data are integred with a compilation of already existing data. This compilation shows that several parts of the arc in the External Zone did not suffer any Cenozoic rotations, hence suggesting that a proto-arc already axisted at the onset collision, as suggested by independent evidence of some paleogeographic reconstruction. Finally, 2D and 3D thermo-mechanical modeling in using the pTatin3D code is used to test which structural (geometrical), and rheological parameters affected the first-order morphology of the Western Alpin arc and its kinematics. The synthesis of these different approaches allows us to propose a new model explaining the kinematics and the mechanisms of formation of the Western Alps arc.

Download Full-text

The Vesuvianite Gems of the Val d’Ala (Piedmont, Italy)

Minerals ◽

10.3390/min10060535 ◽

2020 ◽

Vol 10 (6) ◽

pp. 535

Author(s):

Franca Piera Caucia ◽

Luigi Marinoni ◽

Maurizio Scacchetti ◽

Maria Pia Riccardi ◽

Omar Bartoli

Keyword(s):

Inductively Coupled Plasma ◽

Major Elements ◽

Western Alps ◽

Inductively Coupled ◽

Icp Ms ◽

Plasma Mass Spectrometry ◽

Gran Paradiso ◽

Dark Green ◽

Ree Patterns

In Val d’Ala (Western Alps in Piedmont, Italy), the most interesting rocks for mineralogical research are represented by rodingite (rich in mineralized veins and fractures) associated with serpentinite in the eclogitized oceanic crust of Piedmont Zone, south of Gran Paradiso Massif. Among the vein-filling minerals, vesuvianite is well appreciated for its potential as gem-quality materials, even though it has never been characterized in detail. This study provides a gemological characterization of eleven vesuvianite crystals from different localities of the Val d’Ala. The refractive index (1.717–1.708) and density (1.705–1.709) values of our vesuvianite are in the range of those in the literature. Scanning electron microscopy with energy-dispersive spectroscopy (SEM/EDS) and laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) established that the samples are pretty compositionally homogeneous in terms of major elements, while trace and rare earth elements (REE) contents are more variable. All REE patterns are characterized by pronounced positive Eu anomalies. The variations in color (from olive green to dark green with chocolate (reddish-brown color shades and polychrome bands) are due to the relevant presence of Fe and, to a lesser extent, Ti and Cr. The X-ray powder diffraction (XRPD) analyses and SEM/EDS quantitative study indicate that the other phases associated with vesuvianite are represented by diopside, garnet, clinochlore.

Download Full-text

On the nature of the parental magma of the Palaeogene Staffa Magma sub-type, Isle of Mull, Scotland

Transactions of the Royal Society of Edinburgh Earth Sciences ◽

10.1017/s0263593300007021 ◽

1998 ◽

Vol 89 (2) ◽

pp. 87-93 ◽

Cited By ~ 3

Author(s):

Andrew C. Kerr

Keyword(s):

Crustal Contamination ◽

Parental Magma ◽

Distinct Group ◽

Crystal Fractionation ◽

Distinctive Features ◽

Tholeiitic Magma ◽

Igneous Province ◽

Melt Generation

AbstractThe tholeiitic, columnar (Staffa type) lavas found at, and near, the base of the Tertiary lava succession on the Isle of Mull contrast markedly with overlying transitional tholeiiticalkalic Mull Plateau Group lavas, and as a result previous workers have classed the Staffa type lavas as a distinct group. The Staffa type lavas are among the most contaminated in the British Tertiary Igneous Province and have equilibrated and fractionated at shallow depths within the crust (relative to the overlying Plateau Group lavas), so obscuring the chemical identity of their parental magma. However, Staffa type lavas which are more basic than examples hitherto reported help in the elucidation of the parental magma. It is demonstrated that the Staffa type lavas were derived from a parental magma which was compositionally similar to that of Plateau Group lavas. The primary reasons for the distinctive features of the Staffa type are related to post-mantle melt generation processes, i.e. to extensive crystal fractionation and to crustal contamination at shallow crustal depths. The lavas are compositionally and temporally unrelated to the Hebridean tholeiitic magma types, the Central Mull Tholeiite type and the Skye Preshal More type.

Download Full-text