scholarly journals Geochemical Characteristics and Tectonic Setting of Amphibolites in Ifewara Area, Ife-Ilesha Schist Belt, Southwestern Nigeria

2016 ◽  
Vol 6 (1) ◽  
pp. 43 ◽  
Author(s):  
Anthony Temidayo Bolarinwa ◽  
Adebimpe Atinuke Adepoju
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Major Element ◽  
Tectonic Setting ◽  
Crustal Contamination ◽  
Geochemical Evolution ◽  
Schist Belt ◽  
Southwestern Nigeria ◽  
Eu Anomaly ◽  
Ree Patterns

Trace and Rare Earth Elements (REEs) data are used to constrain the geochemical evolution of the amphibolites from Ifewara in the Ife-Ilesha schist belt of southwestern Nigeria. The amphibolites can be grouped into banded and sheared amphibolites. Major element data show SiO2 (48.34%), Fe2O3 (11.03-17.88%), MgO (5.76-9.90%), CaO (7.76-18.6%) and TiO2 (0.44-1.77%) contents which are similar to amphibolites in other schist belts in Nigeria. The Al2O3 (2.85-15.55%) content is varied, with the higher values suggesting alkali basalt protolith. Trace and rare earth elements composition reveal Sr (160-1077ppm), Rb (0.5-22.9ppm), Ni (4.7-10.2ppm), Co (12.2-50.9 ppm) and Cr (2-7ppm). Chondrite-normalized REE patterns show that the banded amphibolites have HREE depletion and both negative and positive Eu anomalies while the sheared variety showed slight LREE enrichment with no apparent Eu anomaly. The study amphibolites plot in the Mid Oceanic Ridge Basalts (MORB) and within plate basalt fields on the Zr/Y vs Zr discriminatory diagrams. They are further classified as volcanic arc basalt and E-type MORB on the Th- Hf/3- Ta and the Zr-Nb-Y diagrams. The amphibolites precursor is considered a tholeiitic suite that suffered crustal contamination, during emplacement in a rifted crust.

scholarly journals Provenance Studies of Sandstone Facies Exposed Near Igbile Southwestern Nigeria: Petrographic and Geochemical Approach

2014 ◽  
Vol 6 (2) ◽  
pp. 47 ◽  
Author(s):  
Ikhane P. R. ◽  
Akintola A. I. ◽  
Bankole S. I. ◽  
Oyinboade Y. T.
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Inductively Coupled Plasma ◽  
Tectonic Setting ◽  
Source Area ◽  
Rock Fragment ◽  
Petrographic Analysis ◽  
Humid Climate ◽  
Southwestern Nigeria ◽  
Plagioclase Feldspar

The petrography, as well as the major, trace and rare earth element compositions of ten (10) sandstone samples of Maastrichtian Afowo Formation exposed near Igbile, Southwestern Nigeria, have been investigated to determine their provenance, source area weathering conditions, paleoclimate and tectonic setting using petrographic analysis and Inductively Coupled Plasma - Mass Spectrometry (ICP-MS). Results of the petrographic analysis revealed that quartz is the most dominant detrital mineral with (86%) followed by weathered plagioclase feldspar (5.10%) and rock fragments (10.9%). The quartz grain is sub-angular to sub-rounded in shape and the sandstones were classified as quartz arenites, sublitharenites and subarkoses based on framework composition of quartz, feldspar and rock fragment plots. This suggests a recycled orogen source for the sandstones and deposition in a humid climate, evidenced by the weathered feldspars. Eleven (11) major, seventeen (17) trace and fourteen (14) rare earth elements were obtained from the geochemical analysis. The major elements values range in concentration from 0.01%–81.39% with SiO2 being the dominant oxide followed by Al2O3 and Fe2O3 constituting over 95% of the major oxides; K2O, TiO2, Na2O, CaO, MgO and P2O5 made up the remaining 5%. The average ratio of SiO2/Al2O3 valued 4.31 for the sandstone is appreciably high indicating that it has been heavily weathered. The trace elements range in concentration from 0.2 ppm–1651.2 ppm with Zr being the most dominant element an indication of orogenic recycling. The rare earth elements range in concentration from 0.01 ppm–163.7 ppm with Ce having the highest concentration, depicting that the sandstones were deposited in an oxidizing environment. Also, the trace element relationship illustrated from the spider plot shows chemical coherence and uniformity of the sandstones. The chondrite normalized rare earth elements (REE) plot shows enrichment in the Light REE over the heavy REE for the sediment with strong negative Eu anomaly values between (0.57–0.69) suggesting a felsic provenance derived from upper continental crust for the sandstones.

Geochemical evolution of the Chatham–Grenville stock, Quebec

1985 ◽  
Vol 22 (6) ◽  
pp. 872-880 ◽  
Author(s):  
Michael Denis Higgins
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Mass Balance ◽  
Major Element ◽  
Parental Magma ◽  
Alkali Feldspar ◽  
Geochemical Evolution ◽  
Wide Range ◽  
The Mean

The Chatham–Grenville stock is an anorogenic multiple intrusion that shows a complete gradation from early cumulate and noncumulate syenites to slightly peralkaline granites. It can be divided into four units. Unit 1, the first unit, is a noncumulate syenite with modal quartz less than 5%. Unit 2 has a wide range in composition from cumulate syenites (no modal quartz) to noncumulate syenites and quartz syenites (modal quartz = 20%). Units 3 and 4 are granites with modal quartz up to 25 and 30%, respectively. The parental magma of the whole complex was syenitic. Differentiation occurred as a result of crystal fractionation by filter pressing both at depth and in situ. Ba, Sr, Rb, and Eu abundances and major-element mass-balance calculations show that alkali feldspar, mafic minerals, and apatite were fractionated. At least 79% fractionation is necessary to transform the mean composition of the first unit (1) into the mean composition of the last unit (4). The rare-earth elements, Th, Ta, Hf, and Zr, did not behave in a residual fashion but may have been fractionated in minor accessory phases such as apatite, zircon, monazite, allanite, and xenotime.

scholarly journals Contribution to the Mineral Chemistry of the Proterozoic Aravalli Mafic Meta-Volcanic Rocks from Rajasthan, NW India

Minerals ◽  
2020 ◽  
Vol 10 (7) ◽  
pp. 638
Author(s):  
Janina Wiszniewska ◽  
Anna Grabarczyk ◽  
Ewa Krzemińska ◽  
Talat Ahmad
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Volcanic Rocks ◽  
Crustal Contamination ◽  
Pillow Lava ◽  
Mineral Chemistry ◽  
Field Evidence ◽  
Tectonic Environment ◽  
Ree Patterns ◽  
Aravalli Craton

Field, petrological and mineral chemistry for meta-volcanic rocks from the Aravalli sequence (Aravalli Craton, India) are presented. Field evidence such as volcanic flows and suspect pillow lava structures, dominant Fe-tholeiite lava flows intercalated with quartzites and argillaceous sediments, indicate rift tectonic environment. Primary mineralogy was obliterated during post-magmatic processes such as metamorphism corresponding to the greenschist to lower amphibolite facies conditions. The rock’s mineral composition was overprinted by plagioclase–chlorite–amphibole–epidote assemblage. The relicts of clinopyroxene were observed. The P-T estimation indicates a temperature of 550–600 °C for the pressure ranging from 3.0 to 7.0 kbar for the majority of amphiboles and 8.0–10.7 kbar for the minority. Geochemically, these rocks are komatiitic (picritic) and high-Fe tholeiitic basalts with 45.06−59.2 wt.% SiO2 and MgO content from 5 to 22.4 wt.% and Mg# of 17 to 71. They show large-ion lithophile elements (LILE) and light rare-earth elements (LREE) enrichment. Chondrite normalized rare-earth elements (REE) patterns for the Aravalli lava are moderately enriched with (La/Sm)N = 1.1−3.85, (La/Yb)N from 1.49 (komatiites) to 14.91 (komatiitic basalts). The trace element systematics with the negative Nb, P and Zr anomalies reflect their derivation from enriched sub-continental lithospheric sources, although minor crustal contamination cannot be ruled out. Aravalli rocks are considered to represent the transition from continental rift magmatism to shallow submarine eruption.

scholarly journals Peculiarities of the distribution of rare-earth elements in the ores of some gold deposits of Eastern Transbaikalia

2018 ◽  
pp. 48-58
Author(s):  
B. N. Abramov
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Gold Deposits ◽  
Volatile Components ◽  
Magma Chambers ◽  
Eastern Transbaikalia ◽  
Different Depths ◽  
Degree Of Differentiation ◽  
Gold Sulfide ◽  
Ree Patterns

The distribution of rare-earth elements (REE) in ores of gold deposits of East Transbaikalia has shown that the ore-bearing magma chambers have different depths and degrees of differentiation. The greatest degree of differentiation was within the magmatic foci (Eu/Eu* — 0,29—0,32; Rb/Sr — 0,98—1,40), which are the sources of gold-quartz-arsenopyrite ores, the magmatic sources of the gold-quartz and gold-sulfide-quartz ores (Eu/Eu* — 0,53—0,72; Rb/Sr of 0,10 to 0,54) had lesser degree of differentiation. Magma chambers that are sources for the gold-quartz-arsenopyrite ores (Eu/Sm — 0,08—0,14), were at shallower depths than those for gold-quartz and gold-sulfide-quartz ores (Eu/Sm — 0,11—0,19). The formation of gold-quartz-arsenopyrite ores took place at the magma chambers, largely enriched in volatile components, it is indicated by the existence of a significant tetrad effects in REE patterns of (T1-4 - 0,80; 1,15; 1,16).

Analysis of ultra-low level rare earth elements in magnetite samples from banded iron formations using HR-ICP-MS after chemical separation

2014 ◽  
Vol 6 (15) ◽  
pp. 6125-6132 ◽  
Author(s):  
Wenjun Li ◽  
Xindi Jin ◽  
Bingyu Gao ◽  
Changle Wang ◽  
Lianchang Zhang
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Reference Materials ◽  
Chemical Separation ◽  
Banded Iron Formations ◽  
Low Level ◽  
Icp Ms ◽  
Ree Patterns ◽  
Iron Formations

Comparison between the REE data of this work and literature values by Z. S. Yu et al., Sampaio et al., Dulski et al., and Bau et al. in reference materials FER-2 (a) and FER-3 (b) using PAAS-normalized REE patterns.

Mafic and ultramafic amphibolites from the northwestern Pontiac Subprovince: chemical characterization and implications for tectonic setting

1993 ◽  
Vol 30 (6) ◽  
pp. 1110-1122 ◽  
Author(s):  
G. E. Camiré ◽  
J. N. Ludden ◽  
M. R. La Flèche ◽  
J. -P. Burg
Keyword(s):  
Magma Mixing ◽  
Tectonic Setting ◽  
Crustal Contamination ◽  
Chemical Characterization ◽  
Mantle Metasomatism ◽  
Primitive Mantle ◽  
Mafic Dykes ◽  
Metavolcanic Rocks ◽  
Source Mantle ◽  
Ree Patterns

In the northwestern Pontiac Subprovince, metavolcanic rocks are exposed within a metagraywacke sequence that is intruded by metamorphosed mafic dykes. The metavolcanics are Al-undepleted komatiites ([La/Sm]N = 0.3, [Tb/Yb]N = 0.9) and tholeiitic Fe-basalts ([La/Sm]N = 0.8 and [Tb/Yb]N = 0.8). The nearly flat chondrite-normalized distributions of high field strength elements (HFSE), Ti and P, the constant Zr/Y, Nb/Th, Ti/Zr, and Ti/P ratios, and the lack of depletion of HFSE relative to rare-earth elements (REE) in both ultramafic and mafic metavolcanics, imply that crustal assimilation and magma mixing with crustal melts were not significant during differentiation and argue against the presence of subduction-related magmatic components. Contemporaneous volcanism and sedimentation in the northwestern Pontiac Subprovince are unlikely. The metavolcanics do not show any evidence of crustal contamination and likely represent a structurally emplaced, disrupted assemblage, chemically similar to early volcanics of the adjacent southern Abitibi Subprovince.Metamorphosed mafic dykes intruding the metagraywackes are not genetically related to the metavolcanics. The dykes have high CaO, P2O5, K2O, Ba, Rb, and Sr, intermediate Cr and Ni contents, and strongly fractionated REE patterns ([La/Yb]N = 10.8). Normalized to the primitive mantle, they display pronounced negative Nb, Ta, Ti, Zr, and Hf anomalies. These amphibolites are metamorphosed equivalents of Mg-rich calc-alkaline lamprophyre dykes, most likely derived from a hybridized mantle source. Mantle metasomatism was probably related to a subduction event prior to the peak of compressional Kenoran deformation in the Pontiac Subprovince.

Deformation-driven emplacement-differentiation in the Closepet pluton, Dharwar Craton, South India: an alternate view

2019 ◽  
Vol 489 (1) ◽  
pp. 261-274 ◽  
Author(s):  
Abhijit Bhattacharya
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
South India ◽  
Major Element ◽  
Volume Fraction ◽  
Dharwar Craton ◽  
The North ◽  
Magmatic Fabric ◽  
Melt Composition ◽  
Crystal Content

AbstractIn the Late Archean north-trending Closepet pluton, trains of euhedral K-feldspar phenocrysts and matrix-supported idiomorphic K-feldspar crystals in the central part of the pluton define oblique-to-pluton margin steep-dipping east/ENE-trending magmatic fabrics. The magmatic fabric is defined by phenocryst-rich and phenocryst-poor layers, with the euhedral porphyries continuous across the layers. The fabrics are near-orthogonal to the gently-dipping gneissic layers in the host gneisses. The fabrics curve adjacent to locally-developed north/NNE-trending melt-hosted dislocations parallel to the axial planes of horizontal/gently-plunging north-trending upright folds in the host gneisses. In the pluton interior, both fabrics in the intrusives formed at supra-solidus conditions, although the volume fraction of melts diminished drastically due to cooling/melt expulsion. At the pluton margin, the north-trending fabric is penetrative and post-dates magma solidification. Within the pluton, the major element oxides, rare earth elements, anorthite contents in plagioclase, and (Mg/Fe + Mg) ratios in biotite decrease with increasing SiO2 from phenocryst-rich (up to 75% by volume) granodiorite to phenocryst-poor (<15 vol%) granite that broadly correspond to minimum melt composition. The chemical-mineralogical variations in the pluton is attributed to deformation-driven ascent of magma with heterogeneous crystal content, ascending at variable velocities (highest in crystal-poor magma) along oblique-to-pluton margin east/ENE-trending extensional fractures induced by dextral shearing.

scholarly journals Allanite Geochemical Response to Hydrothermal Alteration by Alkaline, Low-Temperature Fluids

Minerals ◽  
2020 ◽  
Vol 10 (5) ◽  
pp. 392 ◽  
Author(s):  
Katarzyna Gros ◽  
Ewa Słaby ◽  
Petras Jokubauskas ◽  
Jiří Sláma ◽  
Gabriela Kozub-Budzyń
Keyword(s):  
Rare Earth ◽  
Low Temperature ◽  
Rare Earth Elements ◽  
Geochemical Evolution ◽  
Additional Component ◽  
Second Stage ◽  
Ce Anomaly ◽  
Hydrothermal Processes ◽  
Fluid Infiltration ◽  
Two Stages

Allanite is one of the main rare earth elements (REE)-rich accessory minerals in composite dykes from the granitoid pluton of Karkonosze. These dykes differ in composition from the bulk of the pluton by elevated rare earth elements (REE), Y, Zr, and alkali contents, suggesting contribution of an additional component. Allanite exhibits complex alteration textures, which can be divided into two stages. The first stage is represented by allanite mantles, formed by fluid infiltration into previously crystallized magmatic allanite. These zones have low totals, are Ca-, Al-, Mg-, and light REE (LREE)-depleted, and Y-, heavy REE (HREE)-, Th-, Ti-, and alkali-enriched. The fractionation between LREE and HREE was caused by different mobility of complexes formed by these elements in aqueous fluids. The second stage includes recrystallized LREE-poor, Y-HREE-rich allanite with variable Ca, Al, Mg, and REE-fluorocarbonates. The alteration products from both stages demonstrate higher Fe3+/(Fe2+ + Fe3+) ratios and a negative Ce anomaly. These features point to the alkaline, low-temperature, and oxidized nature of the fluids. The differences in mobility and solubility of respective ligands show that the fluids from the first stage may have been dominated by Cl, whereas those of the second stage may have been dominated by F and CO2 (and PO4 in case of one sample). The inferred chemistry of the fluids resembles the overall geochemical signature of the composite dykes, indicating a major contribution of the hydrothermal processes to their geochemical evolution.

Petrology, age, and tectonic setting of the rapakivi-bearing Margaree pluton, Cape Breton Island, Canada: evidence for a Late Devonian posttectonic cryptic silicic-mafic magma chamber

2020 ◽  
Vol 57 (9) ◽  
pp. 1011-1029
Author(s):  
Gabriel Sombini dos Santos ◽  
Sandra M. Barr ◽  
Chris E. White ◽  
Deanne van Rooyen
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Magma Chamber ◽  
Magma Mixing ◽  
Tectonic Setting ◽  
Mafic Magma ◽  
Coarse Grained ◽  
Late Devonian ◽  
Cape Breton Island ◽  
Cape Breton

The Margaree pluton extends for >40 km along the axis of the Ganderian Aspy terrane of northern Cape Breton Island, Nova Scotia. The pluton consists mainly of coarse-grained megacrystic syenogranite, intruded by small bodies of medium-grained equigranular syenogranite and microgranite porphyry, all locally displaying rapakivi texture. The three rock types have similar U–Pb (zircon) ages of 363 ± 1.6, 364.8 ± 1.6, and 365.5 ± 3.3 Ma, respectively, consistent with field and petrological evidence that they are coeval and comagmatic. The rare earth elements display parallel trends characterized by enrichment in the light rare earth elements, flat heavy rare earth elements, moderate negative Eu anomalies, and, in some cases, positive Ce anomalies. The megacrystic and rapakivi textures are attributed to thermal perturbation in the magma chamber caused by the mixing of mafic and felsic magma, even though direct evidence of the mafic magma is mainly lacking at the current level of exposure. Magma evolution was controlled by fractionation of quartz, K-feldspar, and Na-rich plagioclase in molar proportions of 0.75:0.12:0.13. The chemical and isotopic (Sm–Nd) signature of the Margaree pluton is consistent with the melting of preexisting continental crust that was enriched in heat-producing elements, likely assisted by intrusion of mantle-derived mafic magma during Late Devonian regional extension. The proposed model involving magma mixing at shallow crustal levels in a cryptic silicic-mafic magma chamber during post-Acadian extension is consistent with models for other, better exposed occurrences of rapakivi granite in the northern Appalachian orogen.

Rare Earth Elements: A Tool for Understanding the Behaviour of Trivalent Actinides in the Geosphere

2006 ◽  
Vol 985 ◽  
Author(s):  
Belen Buil ◽  
Paloma Gómez ◽  
Antonio Garralón ◽  
M. Jesús Turrero
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Source Rocks ◽  
Uranium Mine ◽  
Colloidal Transport ◽  
Trivalent Actinides ◽  
Aqueous Complexes ◽  
Ree Patterns

AbstractREE concentrations have been determined in groundwaters, granite and fracture fillings in a restored uranium mine.The granitoids normalized REE patterns of groundwaters show HREE-enrichment and positive Eu anomalies. This suggests that the REE are fractionated during leaching from the source rocks by groundwaters. Preferential leaching of HREE would be consistent with the greater stability of their aqueous complexes compared to those of the LREE, together with the dissolution of certain fracture filling minerals, dissolution/alteration of phyllosilicates and colloidal transport.

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